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US4638485A
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Solid state vibrational lasers using F-center/molecular-defect pairs in alkali halides
Assignee: University of Utah
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Filing: 1985-10-03
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Granted: 1987-01-20
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Expires: 2005-10-03
Abstract
Abstract Vibrational emission from molecular defects in ionic crystals can be realized by dilute diatomic molecular defects such as, e.g., CN - molecules in alkali halide crystals. After association of F-centers to the CN - molecules, forming a new F-center/molecular defect pair, the emission can be pumped by optical F-center excitation through electronic-vibrational coupling. Using this coupling mechanism, laser action in the near infrared wavelength region is obtained between vibrational energy levels of the molecules while pumping the F-center/molecule defect in the visible wavelength range. The laser crystals are prepared by additively coloring a CN - doped alkali halide crystal and exposing the colored crystal to light having a wavelength capable of being absorbed by the electronic F-center/molecule defect transition.
Inventors
- 👤 Werner Gellermann
- 👤 Yihong Yang
- 👤 Fritz Luty
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 19:43
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/14; H01S3/16; H01S3/1681; H01S3/05; H01S3/08; H01S3/081; H01S3/0811
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
56 words
A laser having a laser action in the infrared wavelength region comprising: an alkali halide crystal having dilute diatomic molecular defects; F-center defects in said alkali halide crystal associated with said molecular defects; cooling means for cooling said crystal below about 77K; optical pumping means for pumping the F-center/molecular defect pairs in the visible wavelength range.
Claim 2
Dependent Claim
56 words
A laser having a laser action in the infrared wavelength region comprising: an alkali halide crystal having dilute diatomic molecular defects; F-center defects in said alkali halide crystal associated with said molecular defects; cooling means for cooling said crystal below about 77K; optical pumping means for pumping the F-center/molecular defect pairs in the visible wavelength range.
Claim 3
Dependent Claim
30 words
The laser defined in claim 1 wherein the alkali halide is selected from the group consisting of NaCl, NaBr, NaI, KCl, KBr, KI, RbCl, RbBr, RbI, CsCI, CsBr, and CsI.
Claim 4
Dependent Claim
36 words
The laser defined in claim 1 wherein the diatomic molecules are selected from the group consisting of CN - , OH - , OD - , SH - , TeH - or any other diatomic molecule.
Claim 5
Dependent Claim
65 words
A laser having laser action in the infrared wavelength region comprising: an alkali halide crystal doped with diatomic molecular defects: F-center defects formed in said alkali halide crystals in association with said CN - molecular defects; cooling means for cooling said crystal below about 77K; and optical pumping means for optically pumping said F-center/molecular defects in the visible wavelength region to produce infrared laser action.
Claim 6
Dependent Claim
65 words
A laser having laser action in the infrared wavelength region comprising: an alkali halide crystal doped with diatomic molecular defects: F-center defects formed in said alkali halide crystals in association with said CN - molecular defects; cooling means for cooling said crystal below about 77K; and optical pumping means for optically pumping said F-center/molecular defects in the visible wavelength region to produce infrared laser action.
Claim 7
Dependent Claim
30 words
The laser defined in claim 4 wherein the alkali halide is selected from the group consisting of NaCl, NaBr, NaI, KCl, KBr, KI, RbCl, RbBr, RbI, CsCl, CsBr, and CsI.
Claim 8
Dependent Claim
36 words
The laser defined in claim 4 wherein the diatomic molecules are selected from the group consisting of CN - , OH - , OD - , SH - , TeH - or any other diatomic molecule.
Claim 9
Independent Claim
70 words
A method for producing laser action in the infrared wavelength region comprising: obtaining an alkali halide crystal; producing molecular defects in the alkali halide crystal by doping said crystal with dilute diatomic molecules; creating F-center defects in the alkali halide crystal adjacent the molecular defects; cooling the crystal below about 77K; and pumping the F-center/molecular defect in the visible wavelength range thereby producing laser action in the infrared wavelength region.
Claim 10
Independent Claim
70 words
A method for producing laser action in the infrared wavelength region comprising: obtaining an alkali halide crystal; producing molecular defects in the alkali halide crystal by doping said crystal with dilute diatomic molecules; creating F-center defects in the alkali halide crystal adjacent the molecular defects; cooling the crystal below about 77K; and pumping the F-center/molecular defect in the visible wavelength range thereby producing laser action in the infrared wavelength region.
Claim 11
Dependent Claim
33 words
The method defined in claim 7 wherein the obtaining step comprises selecting the alkali halide from the group consisting of NaCl, NaBr, NaI, KCl, KBr, KI, RbCl, RbBr, RbI, CsCI, CsBr, and CsI.
Claim 12
Dependent Claim
39 words
The method defined in claim 7 wherein the producing step comprises selecting the diatomic molecules from the group consisting of CN - , OH - , OD - , SH - , TeH - or any other diatomic molecule.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-01-19 | 1990-07-21 | 1991-01-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-01-19 | 1994-07-21 | 1995-01-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-01-19 | 1998-07-21 | 1999-01-20 | $7700.00 | Window Closed / Lapsed |