Patent US1411150A successfully refreshed from Google Patents.
Patent US4636434A successfully refreshed from Google Patents.
US4636434A
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Ceramic composite article
Assignee: Hitachi Ltd
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Filing: 1984-12-07
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Granted: 1987-01-13
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Expires: 2004-12-07
Abstract
Abstract A carbon film is formed on a ceramic element, or a metal film is formed on the carbon film, and subsequently the ceramic element is bonded to another ceramic or metal element, thereby forming a composite article. The composite article has a high bonding strength and is hardly fractured at joint. Ceramic articles having a surface coating of a hard carbon film or a hard carbon film containing metal grains can also be formed by this process.
Inventors
- 👤 Hisanori Okamura
- 👤 Hirosi Akiyama
- 👤 Mutuo Kamoshita
- 👤 Kunio Miyazaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 07:01
CPC Classifications
C; C04; C04B; C04B37/00; C04B37/008; C04B37/003; C04B37/005; C04B37/006; C04B37/02; C04B37/023; C04B37/025; C04B37/026; C04B41/00; C04B41/009; C04B41/45; C04B41/50; C04B41/5001; C04B41/80; C04B41/81; C04B41/85; C04B2235/00; C04B2235/65; C04B2235/656; C04B2235/6562; C04B2235/70; C04B2235/96; C04B2235/963; C04B2237/00; C04B2237/02; C04B2237/04; C04B2237/08; C04B2237/086; C04B2237/12; C04B2237/123; C04B2237/124; C04B2237/125; C04B2237/30; C04B2237/32; C04B2237/34; C04B2237/343; C04B2237/36; C04B2237/365; C04B2237/368; C04B2237/40; C04B2237/405; C04B2237/406; C04B2237/50; C04B2237/60; C04B2237/70; C04B2237/708; C04B2237/72; C04B2237/76; C04B2237/78; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/256; Y10T428/26; Y10T428/30; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31652; Y10T428/31667; Y10T428/31786; Y10T428/31855; Y10T428/31935
Claims Analysis
Total Claims: 45
Claim 1
Independent Claim
94 words
A ceramic composite article which comprises ceramic elements joined together with carbon which has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance applied to at least one joining surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, Polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of any carbon film at an interface between the joining surfaces is not more than 10 μm.
Claim 2
Dependent Claim
94 words
A ceramic composite article which comprises ceramic elements joined together with carbon which has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance applied to at least one joining surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, Polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of any carbon film at an interface between the joining surfaces is not more than 10 μm.
Claim 3
Dependent Claim
25 words
A ceramic composite article according to claim 1, wherein a hard carbon film is present on at least one joining surface of said ceramic elements.
Claim 4
Dependent Claim
21 words
A ceramic composite article according to claim 1, wherein said carbon is diffused into the joining surfaces of said ceramic elements.
Claim 5
Dependent Claim
29 words
A ceramic composite article according to claim 1, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 6
Dependent Claim
108 words
A ceramic composite article which comprises ceramic elements joined together with a metal via hard carbon films each formed on joining surfaces of said ceramic elements wherein carbon from the carbon films has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance applied to the joining surfaces of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvivyl chloride resin, and the thickness of a carbon film on the joining surfaces is not more that 10 μm.
Claim 7
Dependent Claim
108 words
A ceramic composite article which comprises ceramic elements joined together with a metal via hard carbon films each formed on joining surfaces of said ceramic elements wherein carbon from the carbon films has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance applied to the joining surfaces of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvivyl chloride resin, and the thickness of a carbon film on the joining surfaces is not more that 10 μm.
Claim 8
Dependent Claim
21 words
A ceramic composite article according to claim 1, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 9
Dependent Claim
20 words
A ceramic composite article according to claim 1, wherein the thickness of the carbon film is 0.1 to 10 μm.
Claim 10
Dependent Claim
24 words
A ceramic composite article according to claim 5, wherein said carbon film has an electric resistivity of 10 Ω.cm or less at room temperature.
Claim 11
Dependent Claim
14 words
A ceramic composite article according to claim 5, wherein said metal is a solder.
Claim 12
Dependent Claim
29 words
A ceramic composite article according to claim 5, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 13
Dependent Claim
21 words
A ceramic composite article according to claim 5, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 14
Dependent Claim
20 words
A ceramic composite article according to claim 5, wherein the thickness of the carbon film is 0.1 to 10 μm.
Claim 15
Dependent Claim
115 words
A ceramic composite article which comprises ceramic elements joined together via a solder between metal films located between hard carbon films, each carbon film being formed on joining surfaces of said ceramic elements wherein carbon from the carbon films has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance applied to the joining surfaces of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of a carbon film on the joining surfaces is not more than 10 μm.
Claim 16
Dependent Claim
115 words
A ceramic composite article which comprises ceramic elements joined together via a solder between metal films located between hard carbon films, each carbon film being formed on joining surfaces of said ceramic elements wherein carbon from the carbon films has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance applied to the joining surfaces of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of a carbon film on the joining surfaces is not more than 10 μm.
Claim 17
Dependent Claim
32 words
A ceramic composite article according to claim 13, wherein said metal films and carbon are reacted to form a carbide on the surfaces of said metal films joined to said carbon films.
Claim 18
Dependent Claim
29 words
A ceramic composite article according to claim 13, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 19
Dependent Claim
21 words
A ceramic composite article according to claim 13, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 20
Dependent Claim
20 words
A ceramic composite article according to claim 13, wherein the thickness of the carbon film is 0.1 to 10 μm.
Claim 21
Dependent Claim
118 words
A ceramic composite article which comprises a ceramic element and a metal element joined together with a metal via a hard carbon film formed on a joining surface of said ceramic element wherein carbon from the carbon film has been diffused and penetrated into the ceramic element from the decomposition of an organic substance applied to the joining surface of the ceramic element, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of any carbon film on the joining surface of the ceramic element is not more than 10 μm.
Claim 22
Dependent Claim
118 words
A ceramic composite article which comprises a ceramic element and a metal element joined together with a metal via a hard carbon film formed on a joining surface of said ceramic element wherein carbon from the carbon film has been diffused and penetrated into the ceramic element from the decomposition of an organic substance applied to the joining surface of the ceramic element, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of any carbon film on the joining surface of the ceramic element is not more than 10 μm.
Claim 23
Dependent Claim
22 words
A ceramic composite article according to claim 18, wherein said carbon film has an electric resistivity of 10 Ω.cm at room temperature.
Claim 24
Dependent Claim
14 words
A ceramic composite article according to claim 18, wherein said metal is a solder.
Claim 25
Dependent Claim
29 words
A ceramic composite article according to claim 18, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 26
Dependent Claim
21 words
A ceramic composite article according to claim 18, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 27
Dependent Claim
20 words
A ceramic composite article according to claim 18, wherein the thickness of the carbon film is 0.1 to 10 μm.
Claim 28
Dependent Claim
109 words
A ceramic composite article which comprises ceramic elements joined with a hard carbon film containing metal grains wherein carbon from the carbon film has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance containing metal grains applied to at least one joining surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of a carbon film containing metal grains at an interface between joining surfaces is not more than 10 μm.
Claim 29
Dependent Claim
109 words
A ceramic composite article which comprises ceramic elements joined with a hard carbon film containing metal grains wherein carbon from the carbon film has been diffused and penetrated into the ceramic elements from the decomposition of an organic substance containing metal grains applied to at least one joining surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of a carbon film containing metal grains at an interface between joining surfaces is not more than 10 μm.
Claim 30
Dependent Claim
29 words
A ceramic composite article according to claim 24, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 31
Dependent Claim
21 words
A ceramic composite article according to claim 24, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 32
Dependent Claim
20 words
A ceramic composite article according to claim 24, wherein the thickness of the carbon film is 0.1 to 10 μm.
Claim 33
Dependent Claim
111 words
A ceramic composite article which comprises a ceramic element and a metal element joined with a hard carbon film containing metal grains wherein carbon from the hard carbon film containing metal grains has been diffused and penetrated into the ceramic element from the decomposition of an organic substance containing metal grains applied to a joining surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of a carbon film on the joining surface is not more than 10 μm.
Claim 34
Dependent Claim
111 words
A ceramic composite article which comprises a ceramic element and a metal element joined with a hard carbon film containing metal grains wherein carbon from the hard carbon film containing metal grains has been diffused and penetrated into the ceramic element from the decomposition of an organic substance containing metal grains applied to a joining surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, and the thickness of a carbon film on the joining surface is not more than 10 μm.
Claim 35
Dependent Claim
29 words
A ceramic composite article according to claim 28, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 36
Dependent Claim
21 words
A ceramic composite article according to claim 28, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 37
Dependent Claim
20 words
A ceramic composite article according to claim 28, wherein the thickness of the carbon film is 0.1 to 10 μm.
Claim 38
Dependent Claim
88 words
A ceramic composite article which comprises ceramic elements each having a hard carbon film formed on the surface thereof resulting from the decomposition of an organic substance applied to the surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, wherein a portion of the carbon from the hard carbon film is diffused and penetrated into the ceramic elements.
Claim 39
Dependent Claim
88 words
A ceramic composite article which comprises ceramic elements each having a hard carbon film formed on the surface thereof resulting from the decomposition of an organic substance applied to the surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, wherein a portion of the carbon from the hard carbon film is diffused and penetrated into the ceramic elements.
Claim 40
Dependent Claim
29 words
A ceramic composite article according to claim 32, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 41
Dependent Claim
21 words
A ceramic composite article according to claim 32, wherein the decomposition is performed at a temperature of at least 800° C.
Claim 42
Dependent Claim
101 words
A ceramic composite article which comprises ceramic elements each having a hard carbon film containing metal grains formed on the surface thereof resulting from the decomposition of an organic substance containing metal grains applied to the surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, containing metal grains, wherein a portion of the carbon of the hard carbon film containing metal grains has been diffused and penetrated into the ceramic elements.
Claim 43
Dependent Claim
101 words
A ceramic composite article which comprises ceramic elements each having a hard carbon film containing metal grains formed on the surface thereof resulting from the decomposition of an organic substance containing metal grains applied to the surface of the ceramic elements, the organic substance being selected from the group consisting of phenol resin, polyimide resin, polyvinylidine fluoride resin, cellulose acetate resin, epoxy resin, polyester resin, polybutyl acrylate resin, vinyl acetate resin and polyvinyl chloride resin, containing metal grains, wherein a portion of the carbon of the hard carbon film containing metal grains has been diffused and penetrated into the ceramic elements.
Claim 44
Dependent Claim
29 words
A ceramic composite article according to claim 35, wherein the organic substance is a resin selected from the group consisting of epoxy resin, polybutyl acrylate resin and polyester resin.
Claim 45
Dependent Claim
21 words
A ceramic composite article according to claim 35, wherein the decompostion is performed at a temperature of at least 800° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-01-12 | 1990-07-14 | 1991-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-01-12 | 1994-07-14 | 1995-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-01-12 | 1998-07-14 | 1999-01-13 | $7700.00 | Window Closed / Lapsed |