Thermally stable capped thermoplastic phenolic resin

Claim 2

A thermally stable, thermoplastic phenolic resin prepared by reacting (I) (A) the reaction product of (1) at least one epox average of more than one vicinal epoxy group per molecule with (2) one or more polyhydric phenols; and optionally (B) one or more polyhydric phenols; with (II) a material having only one vicinal epoxy group per molecule or mixture of such materials; in the presence of an effective quantity of a suitable catalyst and wherein the components are present in quantities which provide an equivalent ratio of component (I-A-1) to component (I-A-2) of from about 0.7:1 to about 0.95:1, the ratio of phenolic hydroxyl equivalents of component (I-B) to the phenolic hydroxyl equivalents of component (I-A) is from about 0:1 to about 20:1, and the ratio of epoxy equivalents from component (II) to phenolic hydroxyl equivalents in component (I) is from about 0.9:1 to about 1.1:1.

Claim 3

A thermally stable, thermoplastic phenolic resin of claim 1 wherein (i) the epoxy groups contained in components (I-A-1) and (II) are glycidyl ether groups; (ii) the equivalent ratio of component (I-A-1) to component (I-A-2) is from about 0.8:1 to about 0.92:1; (iii) the ratio of phenolic hydroxyl equivalents from component (I-B) to the phenolic hydroxyl equivalents from component (I-A) is from about 1:1 to about 10:1; and (iv) the ratio of epoxy equivalents from component (II) to phenolic hydroxyl equivalents from component (I) is from about 0.95:1 to about 1.05:1.

Claim 4

A thermally stable, thermoplastic phenolic resin of claim 2 wherein (i) the equivalent ratio of component (I-A-1) to component (I-A-2) is from about 0.85:1 to about 0.9:1; (ii) the ratio of phenolic hydroxyl equivalents from component (I-B) to the phenolic hydroxyl equivalents from component (I-A) is from about 2:1 to about 5:1; and (iii) the ratio of epoxy equivalents from component (II) to phenolic hydroxyl equivalents from component (I) is from about 0.97:1 to about 1.02:1.

Claim 5

A thermally stable, thermoplastic phenolic resin of claim 3 wherein (i) component (I-A-1) is an epoxy resin or a mixture of epoxy resins represented by formulas (I), (II), (III) or (IV) in the specification wherein each A is independently a divalent hydrocarbyl group having from 1 to about 10 carbon atoms, ##STR5## each A' is independently a divalent hydrocarbyl group having from 1 to about 10 carbon atoms; each R is independently hydrogen or a hydrocarbyl group having from 1 to about 4 carbon atoms; R' is hydrogen or a hydrocarbyl group having from 1 to about 10 carbon atoms; each X is independently hydrogen, a halogen, or a hydrocarbyl group having from 1 to about 12 carbon atoms; n has a value of zero or 1; n' has an average value of from about zero to about 40; m has an average value of from about 0.001 to about 6; and m' has an average value from 0 to about 4; (ii) components (I-A-2) and (B) are independently a polyhydric phenolic compound or mixture of such compounds represented by formulas (V), (VI), (VII) or (VIII) in the specification wherein A, A', R', X, n and m are as defined above; and (iii) component (II) is selected from monoepoxy compounds represented by formulas (IX), (X) or (XI) in the specification wherein each R, R' and X are as defined above.

Claim 6

A thermally stable, thermoplastic phenolic resin of claim 4 wherein (i) component (I-A-1) is one or more epoxy resins represented by the formula (II) wherein A is a divalent hydrocarbyl group having from 1 to about 10 carbon atoms, each X is independently hydrogen, an alkyl group having from 1 to about 4 carbon atoms or bromine, n has a value of 1 and n' has an average value of from about 0.035 to about 2; and (ii) components (I-A-2) and (I-B) are independently one or more phenolic compounds represented by formula (VI).

Claim 7

A thermally stable, thermoplastic phenolic resin of claim 5 wherein (i) component (I-A-1) is a diglycidyl ether of bisphenol A having an EEW of from about 1500 to about 3500; (ii) components (I-A-2) and (I-B) are bisphenol A; and (iii) component (II) is the glycidyl ether of t-butyl phenol, the glycidyl ether of cresol, propylene oxide or a mixture thereof.