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US4568735A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing polyepoxides (II)

Assignee: Resolution Performance Products LLC
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Filing: 1985-06-11
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Granted: 1986-02-04
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Expires: 2005-06-11
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Abstract

Abstract A process for preparing polyepoxides having a wide molecular weight distribution comprises reacting a liquid polyepoxide and polyhydric phenol in a first step, and reacting the resulting intermediate with additional polyhydric phenol and polyepoxide in one or more additional steps.

Inventors

  • 👤 Simon M. K. Li

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 23:44
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/02; C08G59/04; C08G59/06; C08G59/066

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 157 words
A process for producing polyepoxide resins having a relatively wide molecular weight distribution per epoxide equivalent weight, which process comprises: (a) reacting a polyepoxide having more than one 1,2-epoxide group with a polyhydric phenol in a first step in the presence of an effective amount of a fusion catalyst to form an intermediate product; and (b) reacting said intermediate product with additional amounts of polyhydric phenol, polyepoxide and effective amounts of fusion catalyst in one or more additional steps where (i) the amount of polyhydric phenol used in each of the steps is about 10 to about 90 percent by weight of the total amount of polyhydric phenol used; (ii) the amount of polyepoxide used in each of the steps is about 10 to 90 percent by weight of the total amount of polyepoxide used; and (iii) the weight ratio of said polyhydric phenol to said polyepoxide employed in each step is about 0.3 to about 0.6.
Claim 2
Dependent Claim 157 words
A process for producing polyepoxide resins having a relatively wide molecular weight distribution per epoxide equivalent weight, which process comprises: (a) reacting a polyepoxide having more than one 1,2-epoxide group with a polyhydric phenol in a first step in the presence of an effective amount of a fusion catalyst to form an intermediate product; and (b) reacting said intermediate product with additional amounts of polyhydric phenol, polyepoxide and effective amounts of fusion catalyst in one or more additional steps where (i) the amount of polyhydric phenol used in each of the steps is about 10 to about 90 percent by weight of the total amount of polyhydric phenol used; (ii) the amount of polyepoxide used in each of the steps is about 10 to 90 percent by weight of the total amount of polyepoxide used; and (iii) the weight ratio of said polyhydric phenol to said polyepoxide employed in each step is about 0.3 to about 0.6.
Claim 3
Dependent Claim 24 words
The process according to claim 1 wherein said polyepoxide having more than one 1,2-epoxide group is a liquid glycidyl polyether of a polyhydric phenol.
Claim 4
Dependent Claim 12 words
The process according to claim 2 wherein said polyhydric phenol is 2,2-bis(4-hydroxyphenyl)propane.
Claim 5
Dependent Claim 12 words
The process according to claim 1 wherein said polyhydric phenol is 2,2-bis(4-hydroxyphenyl)propane.
Claim 6
Dependent Claim 14 words
The process according to claim 1 wherein said fusion catalyst is a phosphonium halide.
Claim 7
Dependent Claim 20 words
The process according to claim 1 wherein the number of steps employed in part (b) is one to nine steps.
Claim 8
Dependent Claim 38 words
The process according to claim 6 where the amounts of polyhydric phenol and polyepoxide used in each step are about 10 to about 60 percent by weight of the respective total amount of polyhydric phenol and polyepoxide used.
Claim 9
Dependent Claim 19 words
The process according to claim 1 where the weight ratio of phenol to polyepoxide is different in each step.

References Cited (Backward Citations)

US3547881A Cited
US3477990A Cited
US3948855A Cited
US3824212A Cited
US3843605A Cited
US3978027A Cited
US4105634A Cited
US4320222A Cited
US4438254A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-02-03 1989-08-05 1990-02-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-02-03 1993-08-05 1994-02-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-02-03 1997-08-05 1998-02-04 $7700.00 Window Closed / Lapsed

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