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US4631143A Expired / Lapsed US ⏱️ 0.0 years remaining

Triphenylene derivatives

Assignee: Merck Patent GmbH
•
Filing: 1984-12-21
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Granted: 1986-12-23
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Expires: 2004-12-21
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Abstract

Abstract Triphenylene derivatives of the formula I ##STR1## wherein X 1 to X 6 are each, independently of one another, --SH, --SR, --SOR, --SO 2 R or --S--COR, and each R is an alkyl group with up to 20 C atoms, it being possible for one or two CH 2 groups to be replaced by O atoms and/or by unsubstituted or substituted vinylene or vinylidene groups, may be used as components of discotic liquid-crystalline phases.

Inventors

  • 👤 Klaus Praefcke
  • 👤 Bernd Kohne
  • 👤 Wadi Poules
  • 👤 Eike Poetsch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:12
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/32; C09K2019/328

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 104 words
A triphenylene of the formula ##STR3## wherein X 1 to X 6 are each --SH, --SR, --SOR, --SO 2 R or --S--COR, and each R is alkyl of up to 20 C atoms, or such an alkyl group wherein one or two CH 2 groups not bound to S are replaced by O atoms and/or vinylene or vinylidene groups or vinylene or vinylidene groups substituted by F, Cl or CN, the total number of C atoms being up to 20 in all cases, and O atoms being non-adjacent the X-substitution being hexakis and saturated, or pentakis and saturated with the sixth X being unsaturated.
Claim 2
Dependent Claim 104 words
A triphenylene of the formula ##STR3## wherein X 1 to X 6 are each --SH, --SR, --SOR, --SO 2 R or --S--COR, and each R is alkyl of up to 20 C atoms, or such an alkyl group wherein one or two CH 2 groups not bound to S are replaced by O atoms and/or vinylene or vinylidene groups or vinylene or vinylidene groups substituted by F, Cl or CN, the total number of C atoms being up to 20 in all cases, and O atoms being non-adjacent the X-substitution being hexakis and saturated, or pentakis and saturated with the sixth X being unsaturated.
Claim 3
Dependent Claim 12 words
A compound of claim 1 wherein X 1 -X 6 are identical.
Claim 4
Dependent Claim 27 words
A compound of claim 1 wherein X 1 -X 6 contains alkyl of 3-20 C atoms having one or two O atoms or vinylene or vinylidene groups.
Claim 5
Dependent Claim 21 words
A compound of claim 3 wherein X 1 -X 6 contain a group which is ω-hydroxy-alkyl, (ω-1)-alkenyl, (ω-2)-alkenyl, (ω-3)-alkenyl or (ω-1)-methyl-(ω-1)-alkenyl.
Claim 6
Dependent Claim 9 words
A compound of claim 1 wherein R is linear.
Claim 7
Dependent Claim 16 words
A compound of claim 1 wherein at least one of X 1 -X 6 is --SH.
Claim 8
Dependent Claim 16 words
A compound of claim 1 wherein at least one of X 1 -X 6 is --SR.
Claim 9
Dependent Claim 16 words
A compound of claim 1 wherein at least one of X 1 -X 6 is --SOR.
Claim 10
Dependent Claim 18 words
A compound of claim 1 wherein at least one of X 1 -X 6 is --SO 2 R.
Claim 11
Dependent Claim 16 words
A compound of claim 1 wherein at least one of X 1 -X 6 is --S--COR.
Claim 12
Dependent Claim 10 words
A compound of claim 2 wherein the X's are --SH.
Claim 13
Dependent Claim 10 words
A compound of claim 2 wherein the X's are --SR.
Claim 14
Dependent Claim 10 words
A compound of claim 2 wherein the X's are --SOR.
Claim 15
Dependent Claim 12 words
A compound of claim 2 wherein the X's are --SO 2 R.
Claim 16
Dependent Claim 10 words
A compound of claim 2 wherein the X's are --S--COR.
Claim 17
Dependent Claim 22 words
A discotic liquid-crystalline phase comprising at least two liquid-crystalline components, wherein at least one component is a triphenylene derivative of claim 1.
Claim 18
Dependent Claim 22 words
A discotic liquid-crystalline phase comprising at least two liquid-crystalline components, wherein at least one component is a triphenylene derivative of claim 2.
Claim 19
Dependent Claim 20 words
In a liquid crystal display element comprising a liquid-crystalline phase, the improvement wherein the phase is one of claim 16.
Claim 20
Dependent Claim 20 words
In a liquid crystal display element comprising a liquid-crystalline phase, the improvement wherein the phase is one of claim 17.

References Cited (Backward Citations)

US4333709A Cited
US4430650A Cited
EP0134576A2 Cited
US4578210A Cited
EP0149209A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-22 1990-06-23 1990-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-22 1994-06-23 1994-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-22 1998-06-23 1998-12-23 $7700.00 Window Closed / Lapsed

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