Patent US4631084A successfully refreshed from Google Patents.
US4631084A
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Heat-sensitive composition and imaging sheet incorporating same
Assignee: 3M Co
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Filing: 1985-05-08
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Granted: 1986-12-23
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Expires: 2005-05-08
Abstract
Abstract Heat-sensitive composition containing (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical change which results in change of color, and (2) a non-complexing phenolic compound which enhances the color forming reaction. This composition can be applied to a substrate, such as, for example, paper or film, in order to form a heat-sensitive imaging sheet.
Inventors
- 👤 Burt K. Sagawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 17:31
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/333; B41M5/3333; B41M5/3335; B41M5/32; B41M5/337; B41M5/3375; B41M5/3377; Y; Y10; Y10S; Y10S428/00; Y10S428/913
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
186 words
Heat-sensitive composition comprising: A. at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said at least two reactants comprising either (1) a ferric salt of an organic acid and (2) a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy or (1a) at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and (2a) at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change, and B. a non-complexing phenolic compound wherein said non-complexing phenolic compound does not have hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 2
Dependent Claim
186 words
Heat-sensitive composition comprising: A. at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said at least two reactants comprising either (1) a ferric salt of an organic acid and (2) a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy or (1a) at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and (2a) at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change, and B. a non-complexing phenolic compound wherein said non-complexing phenolic compound does not have hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 3
Dependent Claim
39 words
The composition of claim 1 wherein the reactants comprise (a) a ferric salt of an organic acid and (b) a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy.
Claim 4
Dependent Claim
43 words
The composition of claim 2 wherein said phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy has hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 5
Dependent Claim
91 words
The composition of claim 1 wherein the reactants comprise a uniformly dispersed mixture of at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change.
Claim 6
Dependent Claim
13 words
The composition of claim 1 wherein the non-complexing phenolic compound is a bisphenol.
Claim 7
Dependent Claim
12 words
The composition of claim 5 wherein the non-complexing phenolic compound is 4,4'-isopropylidenediphenol.
References Cited (Backward Citations)
US2663654A
Cited
US3157526A
Cited
US3846153A
Cited
US3829401A
Cited
DE2344562A1
Cited
US3937864A
Cited
US3953659A
Cited
JPS5714096A
Cited
JPS57116689A
Cited
US4372582A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-12-22 | 1990-06-23 | 1990-12-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-12-22 | 1994-06-23 | 1994-12-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-12-22 | 1998-06-23 | 1998-12-23 | $7700.00 | Window Closed / Lapsed |