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US4631084A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-sensitive composition and imaging sheet incorporating same

Assignee: 3M Co
•
Filing: 1985-05-08
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Granted: 1986-12-23
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Expires: 2005-05-08
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Abstract

Abstract Heat-sensitive composition containing (1) at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical change which results in change of color, and (2) a non-complexing phenolic compound which enhances the color forming reaction. This composition can be applied to a substrate, such as, for example, paper or film, in order to form a heat-sensitive imaging sheet.

Inventors

  • 👤 Burt K. Sagawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 03:56
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/333; B41M5/3333; B41M5/3335; B41M5/32; B41M5/337; B41M5/3375; B41M5/3377; Y; Y10; Y10S; Y10S428/00; Y10S428/913

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 186 words
Heat-sensitive composition comprising: A. at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said at least two reactants comprising either (1) a ferric salt of an organic acid and (2) a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy or (1a) at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and (2a) at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change, and B. a non-complexing phenolic compound wherein said non-complexing phenolic compound does not have hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 2
Dependent Claim 186 words
Heat-sensitive composition comprising: A. at least two reactants which at normal room temperature do not react with each other, but which, upon application of thermal energy, undergo a chemical reaction with each other which results in change of color, said at least two reactants comprising either (1) a ferric salt of an organic acid and (2) a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy or (1a) at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and (2a) at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change, and B. a non-complexing phenolic compound wherein said non-complexing phenolic compound does not have hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 3
Dependent Claim 39 words
The composition of claim 1 wherein the reactants comprise (a) a ferric salt of an organic acid and (b) a phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy.
Claim 4
Dependent Claim 43 words
The composition of claim 2 wherein said phenolic compound which forms a complex with the ferric ion of said ferric salt upon application of thermal energy has hydroxyl groups in adjacent positions on any aromatic ring of a monocyclic or polycyclic aromatic compound.
Claim 5
Dependent Claim 91 words
The composition of claim 1 wherein the reactants comprise a uniformly dispersed mixture of at least one zinc salt selected from the class consisting of zinc lower alkyl di-substituted di-thiocarbamates, the substituted radicals of which have from one to five carbon atoms, and zinc aryl di-substituted di-thiocarbamates, and at least one heavy metal salt of a higher fatty acid which is non-reactive with said zinc salt at normal room and storage temperature and is reactive therewith at temperatures above the melting point of said zinc salt to produce a color change.
Claim 6
Dependent Claim 13 words
The composition of claim 1 wherein the non-complexing phenolic compound is a bisphenol.
Claim 7
Dependent Claim 12 words
The composition of claim 5 wherein the non-complexing phenolic compound is 4,4'-isopropylidenediphenol.

References Cited (Backward Citations)

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US3829401A Cited
DE2344562A1 Cited
US3937864A Cited
US3953659A Cited
JPS5714096A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-22 1990-06-23 1990-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-22 1994-06-23 1994-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-22 1998-06-23 1998-12-23 $7700.00 Window Closed / Lapsed

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