Recording material for color photography

Claim 1

A recording material for colour photography, which contains in at least one photosensitive silver halide emulsion layer, one intermediate layer and/or one protective layer, a light stabilising amount of at least one polyalkylpiperidine compound as a stabiliser, wherein the polyalkylpiperidine compound is of the formula I ##STR50## in which n is 0 or 1, R 1 is hydrogen, C 1 -C 8 -alkyl, C 5 -C 8 -cycloalkyl, phenyl, C 7 -C 14 -aralkyl, C 7 -C 14 -alkaryl or a group ##STR51## R 2 is C 1 -C 8 -alkyl, C 5 -C 8 -cycloalkyl, phenyl, C 7 -C 14 -aralkyl, C 7 -C 14 -alkaryl and R 3 is hydrogen or methyl, M is a direct bond, --S--, --S--S--, --S(O)--, --S(O) 2 -- or --CH(R 4 )--, in which R 4 is hydrogen or C 1 -C 8 -alkyl, A is a group --CH 2 --, --CH 2 --CH(R 5 )--, ##STR52## in which R 5 is hydrogen, methyl, ethyl, phenoxymethyl or phenyl, R 6 is hydrogen, C 1 -C 12 -alkyl, C 5 -C 8 -cycloalkyl, phenyl or benzyl, E is --CN or a group --COOR 7 , --COR 8 , --SO 2 R 8 , --P(O)(OR 9 ) 2 or --CHO, in which R 7 is C 1 -C 4 -alkyl, R 8 is C 1 -C 12 -alkyl, C 7 -C 14 -alkaryl or phenyl and R 9 is C 1 -C 18 -alkyl, phenyl or allyl, G is hydrogen, C 1 -C 18 -alkyl, C 3 -C 12 -alkenyl, C 3 -C 4 -alkinyl, C 3 -C 12 -cycloalkyl, C 6 -C 18 -alkylcycloalkyl, C 6 -C 14 -cycloalkylalkyl, C 7 -C 14 -aralkyl, C 7 -C 14 -alkaryl or phenyl or C 1 -C 18 -alkyl which is substituted by phenoxy, C 7 -C 10 -alkylphenoxy, benzyloxy, cyclohexyloxy, cyano, --COOR 10 , --OCOR 11 or --P(O)(OR 12 ) 2 , in which R 10 is C 1 -C 18 -alkyl, C 3 -C 12 -cycloalkyl or a group of the formula II --C.sub.a H.sub.2a --CO--X (II) in which a is an integer of from 1 to 6, R 11 is C 1 -C 18 -alkyl, C 3 -C 12 -cycloalkyl, phenyl, C 7 -C 9 -phenylalkyl or a group of the formula III ##STR53## in which s is 0, 1 or 2, and R 12 is C 1 -C 8 -alkyl, allyl or phenyl, or G is C 2 -C 18 -alkyl which is interrupted by --O--, --S--, --SO-- or --SO 2 --, or is a group of the formula III, or, if E is a group --COR 8 , G and R 8 together are tri- or tetra-methylene which is unsubstituted or substituted by hydroxyl or oxo, D is a group ##STR54## in which r is 0 or an integer of from 1 to 12, T is hydrogen, C 1 -C 18 -alkyl, C 3 -C 12 -alkenyl, C 3 -C 4 -alkinyl, C 3 -C 12 -cycloalkyl, C 6 -C 18 -alkylcycloalkyl, C 6 -C 14 -cycloalkylalkyl, C 7 -C 14 -aralkyl, C 7 -C 14 -alkaryl, phenyl, cyano or a group --COR 8 , --SO 2 R 8 or --P(O)(OR 9 ) 2 , a group of the formula III or a group of the formula ##STR55## or T is C 1 -C 18 -alkyl which is interrupted by --O--, --S--, --SO-- or --SO 2 --, X is a group of the formula ##STR56## or of the formula ##STR57## in which e is an integer of from 1 to 5, m is 0 or 1, R is hydrogen or methyl, R 13 is hydroxyl, C 1 -C 12 -alkyl, C 3 -C 6 -alkenylmethyl, C 3 -C 4 -alkinylmethyl, C 7 -C 14 -aralkyl or glycidyl, or C 1 -C 4 -alkyl which is substituted by halogen, cyano, --COOR 18 or --CON(R 19 )(R 20 ), or a group --COR 21 , --COOR 18 or --CON(R 19 )--(R 20 ), a group --CH 2 --CH(R 22 )--OR 23 , --SOR 24 , --SO 2 R 24 , --OR 18 or --OCOR 21 , in which R 18 is C 1 -C 12 -alkyl, allyl, cyclohexyl or benzyl, R 19 is C 1 -C 12 -alkyl, allyl, cyclohexyl, benzyl, phenyl or C 7 -C 10 -alkylphenyl and R 20 is hydrogen, C 1 -C 12 -alkyl, allyl, cyclohexyl or benzyl, or R 19 and R 20 , together with the N atom to which they are bonded, are a 5-membered or 6-membered heterocyclic ring, R 21 is hydrogen, C 1 -C 12 -alkyl, C 2 -C 6 -alkenyl, chloromethyl, C 5 -C 8 -cycloalkyl, C 7 -C 14 -aralkyl, phenyl or C 7 -C 10 -alkylphenyl, or phenyl, phenylmethyl or phenylethyl which is substituted by 1 or 2 C 1 -C 4 -alkyl groups and 1 hydroxyl group, R 22 is hydrogen, C 1 -C 4 -alkyl, C 3 -C 4 -alkoxyalkyl, phenyl or phenoxymethyl, R 23 is hydrogen, C 1 -C 12 -alkyl or a group --COR 21 or --CON(R 19 )(R 20 ) and R 24 is C 1 -C 12 -alkyl, phenyl or C 7 -C 10 -alkylphenyl, Y is --O-- or --N(R 25 )--, in which R 25 is hydrogen, C 1 -C 18 -alkyl, C 3 -C 12 -alkenyl, C 3 -C 12 -cycloalkyl, phenyl, C 7 -C 14 -aralkyl, C 7 -C 14 -alkaryl, C 2 -C 11 -alkoxyalkyl or a group of the formula IV, Z is --O-- or --N(R 26 )--, in which R 26 is hydrogen, C 1 -C 18 -alkyl, C 3 -C 12 -alkenyl, C 3 -C 12 -cycloalkyl, phenyl, C 7 -C 14 -alkaryl, C 7 -C 14 -aralkyl, C 2 -C.sub. 11 -alkoxyalkyl or a group --COR 27 , --COOR 28 , --CON(R 29 )(R 30 ), --CH 2 --CH(R 31 )--OR 32 , --SOR 33 or --SO 2 R 33 , in which R 27 has one of the meanings given for R 21 or is a heterocyclic ring, R 28 has one of the meanings given for R 18 , R 29 has one of the meanings given for R 19 , R 30 has one of the meanings given for R 20 , R 31 has one of the meanings given for R 22 , R 32 has one of the meanings given for R 23 and R 33 has one of the meanings given for R 24 , or R 26 is one of the groups ##STR58## Q is a group --C b H 2b --, in which b is an integer of from 2 to 12, C 4 -C 8 -alkenylene, C 5 -C 12 -cycloalkylene, phenylene, xylylene bitolylene, a group --CO--C r H 2r --CO--, ##STR59## in which t is 0 or an integer of from 1 to 5, or R 13 is a group of the formula ##STR60## and R 14 is hydrogen, C 1 -C 18 -alkyl, C 7 -C 23 -phenoxyalkyl, phenyl, C 7 -C 14 -aralkyl or C 2 -C 11 -alkoxyalkyl, R 15 is hydrogen, methyl, ethyl, phenyl or phenoxymethyl, R 16 is hydrogen, --OR 34 , --OCOR 35 , --N(R 36 )--COR 35 , --OSO 2 R 35 or --N(R 36 )--SO 2 R 35 , in which R 34 is hydrogen, C 1 -C 12 -alkyl, allyl, or benzyl, R 35 is hydrogen, C 1 -C 12 -alkyl, C 2 -C 6 -alkenyl, chloromethyl, C 5 -C 8 -cycloalkyl, C 7 -C 9 -phenylalkyl, C 7 -C 10 -alkylphenyl, phenyl or a group ##STR61## in which Y 1 has one of the meanings given for Y, Q 1 is a group --C r H 2r --, C 2 -C 8 -alkenylene, C 5 -C 12 -cycloalkylene, phenylene, xylylene, bitolylene or a group ##STR62## and R 36 is hydrogen, C 1 -C 12 -alkyl, C 5 -C 8 -cycloalkyl or benzyl, and R 17 is hydrogen, cyano, --COOR 18 , --CONH 2 , --CON--(R 19 )(R 20 ) or --CH 2 NHR 37 , in which R 37 is a group --COR 21 --COOR 18 , --CON(R 19 )(R 20 ), --CH 2 --CH(R 22 )--OR 23 , --SOR 24 or --SO 2 R 24 , the radicals and symbols mentioned repeatedly always being as first defined.