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US4629540A
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Process for the preparation of polyanilines, polyanilines obtained according to this process and their uses in the production of electrochemical generators
Assignee: Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
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Filing: 1984-05-04
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Granted: 1986-12-16
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Expires: 2004-05-04
Abstract
Abstract Process for the preparation of polyanilines, polyanilines obtained according to this process and their uses in the production of electrochemical generators. This process consists of oxidizing a compound chosen from among aniline, para-aminodiphenylamine and their derivatives in a super acid in the liquid phase, having fluoride ions, e.g. in the eutectic NH 3 , HF, either chemically using an oxidizing agent, or electrochemically. The polyanilines obtained can be used as a positive electrode material (5) in an electrochemical generator having two current collectors (3) and (7) and a negative electrode material (9), e.g. constituted by lithium or a lithium-aluminum alloy.
Inventors
- 👤 Eugene Geniees
- 👤 Gerard Pierre
- 👤 Christian Santier
- 👤 Constantin Tsintavis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 12:34
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/02; C08G73/026; C08G73/0266; H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/60; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
38 words
A process for the synthesis of a polyaniline, comprising: (a) mixing aniline, p-aminodiphenylamine or derivative thereof and a super acid in the liquid phase containing fluoride ions; and (b) electrochemically oxidizing the reaction mixture, thereby preparing said polyaniline.
Claim 2
Dependent Claim
38 words
A process for the synthesis of a polyaniline, comprising: (a) mixing aniline, p-aminodiphenylamine or derivative thereof and a super acid in the liquid phase containing fluoride ions; and (b) electrochemically oxidizing the reaction mixture, thereby preparing said polyaniline.
Claim 3
Dependent Claim
142 words
The process of claim 1, wherein said aniline, p-aminodiphenylamine or derivative thereof is a compound of the formula: ##STR4## wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 , each of which can be the same or different, are hydrogen, aryl or alkyl or a substituent selected from the group consisting of NO 2 , NH 2 , CF 3 , SO 2 , CN, OCH 3 , Cl, F, ##STR5## and SR, wherein R is aryl or alkyl, or alkyl or aryl each substituted by at least one substituent selected from the group consisting of NO 2 , NH 2 , CF 3 , SO 2 , CN, OCH 3 , Cl, F, SCN, OCN, ##STR6## SR, wherein R is as defined above.
Claim 4
Dependent Claim
20 words
The process of claim 1, wherein said fluoride ion concentration in the liquid phase ranges from 0.5 to 10 ions.g/l.
Claim 5
Dependent Claim
27 words
The process of claim 1, wherein the concentration of said aniline, p-aminodiphenylamine or derivative thereof in the said liquid phase ranges from 10 -3 to 4 mole/l.
Claim 6
Dependent Claim
25 words
The process of claim 1, wherein said liquid phase containing said super acid and the fluoride ions is the eutectic of NH 3 and HF.
Claim 7
Dependent Claim
27 words
The process of claim 1, wherein the electrochemical oxidation of said reaction mixture is conducted at a current density varying between 0.05 and 100 mA/cm 2 .
Claim 8
Dependent Claim
9 words
A polyaniline prepared by the process of claim 1.
References Cited (Backward Citations)
US4488943A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-12-15 | 1990-06-16 | 1990-12-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-12-15 | 1994-06-16 | 1994-12-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-12-15 | 1998-06-16 | 1998-12-16 | $7700.00 | Window Closed / Lapsed |