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US4627458A Expired / Lapsed US ⏱️ 0.0 years remaining

One-step process for transforming a water-in-oil emulsion into an oil-in-water emulsion

Assignee: Nexen Inc
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Filing: 1985-11-27
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Granted: 1986-12-09
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Expires: 2005-11-27
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Abstract

Abstract There is provided a process for the formulation of an oil-in-water emulsion from a produced hydrocarbon crude which includes a water-in-oil emulsion. A surface-active chemical system is added with agitation to the crude when such crude is at a temperature of from about 100° to about 200° F., in a quantity sufficient to formulate and then sustain an oil-in-water emulsion at pipeline conditions of temperature and shear. Water-content is from about 15 percent to about 35 percent by weight. Viscosity is sufficiently low for pipeline transportation. Any excess water is separated from the formed oil-in-water emulsion prior to pipelining. The oil-in-water emulsion is one that can easily be dewatered and desalted to the necessary marketing specifications at the downsteam end of the pipeline, using known technology.

Inventors

  • 👤 Rama R. S. Prasad

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:35
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/32; C10L1/328; F; F17; F17D; F17D1/00; F17D1/08; F17D1/16; F17D1/17; Y; Y10; Y10T; Y10T137/00; Y10T137/0318; Y10T137/0391

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 134 words
A process for the production of an oil-in-water emulsion for pipeline transmission which comprises: (a) producing a hydrocarbon crude including a water-in-oil emulsion; (b) adding to said hydrocarbon crude when said crude is at a temperature of from about 100° to about 200° F., an emulsifier system capable of forming and sustaining an oil-in-water emulsion at said temperature and at ambient pipeline transmission temperatures, the amount of emulsifier system added being sufficient to form and sustain an oil-in-water emulsion having a selected water content of from about 15 percent to about 35 percent by weight water and a viscosity sufficiently low for pipeline transmission; (c) agitating the hydrocarbon crude including a water-in-oil emulsion and the added emulsifier system, to form an oil-in-water emulsion; and (d) separating any excess water from the formed oil-in-water emulsion.
Claim 2
Dependent Claim 134 words
A process for the production of an oil-in-water emulsion for pipeline transmission which comprises: (a) producing a hydrocarbon crude including a water-in-oil emulsion; (b) adding to said hydrocarbon crude when said crude is at a temperature of from about 100° to about 200° F., an emulsifier system capable of forming and sustaining an oil-in-water emulsion at said temperature and at ambient pipeline transmission temperatures, the amount of emulsifier system added being sufficient to form and sustain an oil-in-water emulsion having a selected water content of from about 15 percent to about 35 percent by weight water and a viscosity sufficiently low for pipeline transmission; (c) agitating the hydrocarbon crude including a water-in-oil emulsion and the added emulsifier system, to form an oil-in-water emulsion; and (d) separating any excess water from the formed oil-in-water emulsion.
Claim 3
Dependent Claim 33 words
A process as claimed in claim 1 in which the temperature of the hydrocarbon crude including a water-in-oil emulsion, is from about 130° to about 170° F. during formation of the oil-in-water emulsion.
Claim 4
Dependent Claim 45 words
A process as claimed in claim 1 in which the emulsifier system contains at least one emulsifier capable of sustaining the oil-in-water emulsion at the elevated temperature and at least one emulsifier capable of sustaining the formed oil-in-water emulsion at ambient temperatures of pipeline transmission.
Claim 5
Dependent Claim 31 words
A process as claimed in claim 1 in which the emulsifier system is provided in a concentration of from about 100 to about 5000 ppm by weight of the hydrocarbon crude.
Claim 6
Dependent Claim 31 words
A process as claimed in claim 1 in which the emulsifier system is provided in a concentration of from about 500 to about 2500 ppm by weight of the hydrocarbon crude.
Claim 7
Dependent Claim 34 words
A process as claimed in claim 1 in which the hydrocarbon crude including a water-in-oil emulsion, contains less than 15 percent by weight water, and water is added for formation of the oil-in-water emulsion.
Claim 8
Dependent Claim 38 words
A process as claimed in claim 1 in which the hydrocarbon crude contains "bound" and "free" water, and at least a portion of the "free" water is separated from the hydrocarbon crude prior to forming the oil-in-water emulsion.
Claim 9
Dependent Claim 146 words
A process for the production of an oil-in-water emulsion for pipeline transmission which comprises: (a) producing a hydrocarbon crude including a water-in-oil emulsion and containing in excess of 35 percent by weight water; (b) elevating the temperature of the hydrocarbon crude including a water-in-oil emulsion to a temperature of about 100° to about 200° F., and adding an emulsifier system capable of forming and then sustaining an oil-in-water emulsion at said temperature and at ambient pipeline transmission temperatures, the amount of emulsifier system added being sufficient to form and sustain an oil-in-water emulsion having a selected water content of from about 15 percent to about 35 percent by weight and a viscosity sufficiently low for pipeline transportation; (c) agitating the hydrocarbon crude including a water-in-oil emulsion and the added emulsifier system, to form an oil-in-water emulsion; and (d) separating excess water from the formed oil-in-water emulsion.
Claim 10
Dependent Claim 146 words
A process for the production of an oil-in-water emulsion for pipeline transmission which comprises: (a) producing a hydrocarbon crude including a water-in-oil emulsion and containing in excess of 35 percent by weight water; (b) elevating the temperature of the hydrocarbon crude including a water-in-oil emulsion to a temperature of about 100° to about 200° F., and adding an emulsifier system capable of forming and then sustaining an oil-in-water emulsion at said temperature and at ambient pipeline transmission temperatures, the amount of emulsifier system added being sufficient to form and sustain an oil-in-water emulsion having a selected water content of from about 15 percent to about 35 percent by weight and a viscosity sufficiently low for pipeline transportation; (c) agitating the hydrocarbon crude including a water-in-oil emulsion and the added emulsifier system, to form an oil-in-water emulsion; and (d) separating excess water from the formed oil-in-water emulsion.
Claim 11
Dependent Claim 32 words
A process as claimed in claim 8 in which the temperature of the hydrocarbon crude including a water-in-oil is from about 130° to about 170° F. during formation of the oil-in-water emulsion.
Claim 12
Dependent Claim 35 words
A process as claimed in claim 8 in which the emulsifier system contains at least one emulsifier capable of sustaining the oil-in-water emulsion at the temperature of formation and at ambient temperatures of pipeline transmission.
Claim 13
Dependent Claim 31 words
A process as claimed in claim 8 in which the emulsifier system is provided in a concentration of from about 100 to about 5000 ppm by weight of the hydrocarbon crude.
Claim 14
Dependent Claim 31 words
A process as claimed in claim 8 in which the emulsifier system is provided in a concentration of from about 500 to about 5000 ppm by weight of the hydrocarbon crude.
Claim 15
Dependent Claim 24 words
A process as claimed in claim 8 in which the hydrocarbon crude including a water-in-oil emulsion contains up to 95 percent by weight water.
Claim 16
Dependent Claim 24 words
A process as claimed in claim 10 in which the hydrocarbon crude including a water-in-oil emulsion contains up to 95 percent by weight water.
Claim 17
Dependent Claim 169 words
A process for the production of an oil-in-water emulsion for pipeline transmission which comprises: (a) producing a hydrocarbon crude including a water-in-oil emulsion and containing more than 35 percent by weight water in the form of "bound" and "free" water; (b) separating at least a portion of the "free" water from the hydrocarbon crude; (c) elevating the temperature of the hydrocarbon crude including a water-in-oil emulsion to a temperature of from about 100° to about 200° F., and adding an emulsifier system capable of forming then sustaining an oil-in-water emulsion at said temperature and at ambient pipeline transmission temperatures, the amount of emulsifier system added being sufficient to form and sustain an oil-in-water emulsion having a selected water content of from about 15 percent to about 35 percent by weight water and a viscosity sufficiently low for pipeline transportation; (d) agitating the hydrocarbon crude including a water-in-oil emulsion and the added emulsifier system, to form an oil-in-water emulsion; and (e) separating any excess water from the formed water-in-oil emulsion.
Claim 18
Dependent Claim 169 words
A process for the production of an oil-in-water emulsion for pipeline transmission which comprises: (a) producing a hydrocarbon crude including a water-in-oil emulsion and containing more than 35 percent by weight water in the form of "bound" and "free" water; (b) separating at least a portion of the "free" water from the hydrocarbon crude; (c) elevating the temperature of the hydrocarbon crude including a water-in-oil emulsion to a temperature of from about 100° to about 200° F., and adding an emulsifier system capable of forming then sustaining an oil-in-water emulsion at said temperature and at ambient pipeline transmission temperatures, the amount of emulsifier system added being sufficient to form and sustain an oil-in-water emulsion having a selected water content of from about 15 percent to about 35 percent by weight water and a viscosity sufficiently low for pipeline transportation; (d) agitating the hydrocarbon crude including a water-in-oil emulsion and the added emulsifier system, to form an oil-in-water emulsion; and (e) separating any excess water from the formed water-in-oil emulsion.
Claim 19
Dependent Claim 28 words
A process as claimed in claim 15 in which the temperature of the crude is from about 130° to about 170° F. during formation of the oil-in-water emulsion.
Claim 20
Dependent Claim 46 words
A process as claimed in claim 15 in which the emulsifier system contains at least one emulsifier capable of sustaining the oil-in-water emulsion at the temperature of formation and at least one emulsifier capable of sustaining the formed oil-in-water emulsion at ambient temperatures of pipeline transmission.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-08 1990-06-09 1990-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-08 1994-06-09 1994-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-08 1998-06-09 1998-12-09 $7700.00 Window Closed / Lapsed

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