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US4626557A Expired / Lapsed US ⏱️ 0.0 years remaining

Plastic ovenware containing talc

Assignee: Syensqo Specialty Polymers USA LLC
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Filing: 1985-04-24
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Granted: 1986-12-02
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Expires: 2005-04-24
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Abstract

Abstract Permanent ovenware capable of repeated use in both conventional thermal and microwave ovens fabricated from wholly aromatic polyester compositions and, more particularly, from oxybenzoyl polyester compositions containing up to about 60% of talc having present a minimum content of material decomposable at elevated temperatures.

Inventors

  • 👤 Joseph J. Duska
  • 👤 Arnold B. Finestone
  • 👤 John B. Maher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:53
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 96 words
A molded article of permanent ovenware, comprising at least about 35% by weight of a wholly aromatic polyester and about 1 to 60% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950° C. and 2% by weight at 800° C. and having an iron content of not more than about 1.0% by weight analyzed as iron oxide, such that the ovenware is not blistered or bubbled or cracked during molding or oven use.
Claim 2
Dependent Claim 96 words
A molded article of permanent ovenware, comprising at least about 35% by weight of a wholly aromatic polyester and about 1 to 60% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950° C. and 2% by weight at 800° C. and having an iron content of not more than about 1.0% by weight analyzed as iron oxide, such that the ovenware is not blistered or bubbled or cracked during molding or oven use.
Claim 3
Dependent Claim 26 words
The article of claim 1 wherein the talc is selected from the group consisting of high purity talc, highly refined talc, calcined talc and acid-treated talc.
Claim 4
Dependent Claim 15 words
The article of claim 1 comprising about 35 to 55% by weight of said talc.
Claim 5
Dependent Claim 27 words
The article of claim 1 wherein said talc comprises a particle size distribution in which at least about 95% of the particles are less than about 40μ.
Claim 6
Dependent Claim 15 words
The article of claim 1 comprising about 2 to 20% by weight of titanium dioxide.
Claim 7
Dependent Claim 15 words
The article of claim 5 comprising about 5 to 15% by weight of titanium dioxide.
Claim 8
Dependent Claim 13 words
The article of claim 1 wherein the aromatic polyester is an oxybenzoyl polyester.
Claim 9
Dependent Claim 41 words
The article of claim 7 wherein the oxybenzoyl polyester comprises recurrent moieties selected from the following formulas: ##STR5## where X is O, S, CO, NH, or SO 2 ; n is zero or one; and p+q+r+s+t+u is about 3 to 800.
Claim 10
Dependent Claim 26 words
The article of claim 8 wherein each of the ratios q:r, q:u, t:r, t:u, (q+t):(r+u), and t:(r+u) of the moieties present is about 10:10 to 11:10.
Claim 11
Dependent Claim 13 words
The article of claim 9 wherein each of said ratios is about 10:10.
Claim 12
Dependent Claim 9 words
The article of claim 8 wherein n is zero.
Claim 13
Dependent Claim 104 words
The article of claim 7 wherein the oxybenzoyl polyester comprises recurrent moieties selected from the following formulas: ##STR6## where X is O or SO 2 ; m is zero or one; n is zero or one; q:r is about 10:15 to 15:10; p:q is about 1:100 to 100:1; p+q+r is about 3 to 600; the carbonyl groups of the moiety of formula VII or VIII are linked to the oxy groups of the moiety formula VII or IX; and the oxy groups of the moiety of formula VII or IX are linked to the carbonyl groups of the moiety of formula VII or VIII.
Claim 14
Dependent Claim 17 words
The article of claim 7 wherein the oxybenzoyl polyester comprises recurrent units of the following formula: ##STR7##
Claim 15
Dependent Claim 96 words
A molding composition for permanent ovenware, comprising at least about 35% by weight of a wholly aromatic polyester and about 1 to 60% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950° C. and 2% by weight at 800° C. and having an iron content of not more than about 1.0% by weight analyzed as iron oxide, such that during molding at elevated temperatures said composition is not blistered or bubbled or cracked.
Claim 16
Dependent Claim 96 words
A molding composition for permanent ovenware, comprising at least about 35% by weight of a wholly aromatic polyester and about 1 to 60% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950° C. and 2% by weight at 800° C. and having an iron content of not more than about 1.0% by weight analyzed as iron oxide, such that during molding at elevated temperatures said composition is not blistered or bubbled or cracked.
Claim 17
Dependent Claim 26 words
The composition of claim 14 wherein the talc is selected from the group consisting of high purity talc, highly refined talc, calcined talc and acid-treated talc.
Claim 18
Dependent Claim 15 words
The composition of claim 14 comprising about 35 to 55% by weight of said talc.
Claim 19
Dependent Claim 27 words
The article of claim 14 wherein said talc comprises a particle size distribution in which at least about 95% of the particles are less than about 40μ.
Claim 20
Dependent Claim 15 words
The composition of claim 14 comprising about 2 to 20% by weight of titanium dioxide.
Claim 21
Dependent Claim 15 words
The composition of claim 18 comprising about 5 to 15% by weight of titanium dioxide.
Claim 22
Dependent Claim 13 words
The composition of claim 14 wherein the aromatic polyester is an oxybenzoyl polyester.
Claim 23
Dependent Claim 41 words
The composition of claim 20 wherein the oxybenzoyl polyester comprises recurrent moieties selected from the following formulas: ##STR8## where X is O, S, CO, NH, or SO 2 ; n is zero or one; and p+q+r+s+t+u is about 3 to 800.
Claim 24
Dependent Claim 26 words
The composition of claim 21 wherein each of the ratios q:r, q:u, t:r, t:u, (q+t):(r+u), and t:(r+u) of the moieties present is about 10:10 to 11:10.
Claim 25
Dependent Claim 13 words
The composition of claim 22 wherein each of said ratios is about 10:10.
Claim 26
Dependent Claim 9 words
The composition of claim 21 wherein n is zero.
Claim 27
Dependent Claim 105 words
The composition of claim 20 wherein the oxybenzoyl polyester comprises recurrent moieties selected from the following formulas: ##STR9## where X is O or SO 2 ; m is zero or one; n is zero or one; q:r is about 10:15 to 15:10; p:q is about 1:100 to 100:1; p+q+r is about 3 to 600; the carbonyl groups of the moiety of formula VII or VIII are linked to the oxy groups of the moiety of formula VII or IX; and the oxy groups of the moiety of formula VII or IX are linked to the carbonyl groups of the moiety of formula VII or VIII.
Claim 28
Dependent Claim 17 words
The composition of claim 20 wherein the oxybenzoyl polyester comprises recurrent units of the following formula: ##STR10##
Claim 29
Dependent Claim 106 words
A molded article of nonblistering permanent ovenware comprising: at least about 35% by weight of an oxybenzoyl polyester; about 35 to 55% by weight of a talc, having a minimum content of materials decomposable at elevated temperatures characterized as a weight loss on ignition of not more than about 6% by weight of 950° C. and 2% by weight at 800° C., an iron content of not more than about 1% by weight analyzed as iron oxide, and a particle size distribution in which at least about 95% of the particles are less than about 40μ; and about 2 to 20% by weight of titanium dioxide.
Claim 30
Dependent Claim 106 words
A molded article of nonblistering permanent ovenware comprising: at least about 35% by weight of an oxybenzoyl polyester; about 35 to 55% by weight of a talc, having a minimum content of materials decomposable at elevated temperatures characterized as a weight loss on ignition of not more than about 6% by weight of 950° C. and 2% by weight at 800° C., an iron content of not more than about 1% by weight analyzed as iron oxide, and a particle size distribution in which at least about 95% of the particles are less than about 40μ; and about 2 to 20% by weight of titanium dioxide.
Claim 31
Dependent Claim 92 words
A molding composition for permanent ovenware, comprising at least about 35% to 85% by weight of a wholly aromatic polyester and about 35 to 55% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950° C. and 2% by weight at 800° C., and having an iron content of not more than about 0.6% by weight analyzed as iron oxide, and about 2 to 20% by weight of titanium dioxide.
Claim 32
Dependent Claim 92 words
A molding composition for permanent ovenware, comprising at least about 35% to 85% by weight of a wholly aromatic polyester and about 35 to 55% by weight of a talc containing a minimum amount of materials decomposable at elevated temperatures characterized by a weight loss on ignition of not more than about 6% by weight at 950° C. and 2% by weight at 800° C., and having an iron content of not more than about 0.6% by weight analyzed as iron oxide, and about 2 to 20% by weight of titanium dioxide.

References Cited (Backward Citations)

GB1592204A Cited
US4244859A Cited
GB2011439A Cited
US4219629A Cited
WO1980002430A1 Cited
GB2058102A Cited
EP0044175A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-01 1990-06-02 1990-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-01 1994-06-02 1994-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-01 1998-06-02 1998-12-02 $7700.00 Window Closed / Lapsed

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