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US4626477A Expired / Lapsed US ⏱️ 0.0 years remaining

Wear and corrosion resistant coatings and method for producing the same

Assignee: Praxair ST Technology Inc
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Filing: 1986-02-20
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Granted: 1986-12-02
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Expires: 2006-02-20
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Abstract

Abstract A coating composition applied to a substrate by a thermal spray process which consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.

Inventors

  • 👤 John E. Jackson
  • 👤 Thomas A. Adler
  • 👤 Jean M. Quets

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:04
CPC Classifications
C; C22; C22C; C22C29/00; C22C29/02; C22C29/06; C22C29/08; C23; C23C; C23C4/00; C23C4/04; C23C4/06; C23C4/067; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T442/00; Y10T442/20; Y10T442/2139; Y10T442/2148; Y10T442/273

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 50 words
A coating composition which has been applied to a substrate by a thermal spray process which consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 2
Dependent Claim 50 words
A coating composition which has been applied to a substrate by a thermal spray process which consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 3
Dependent Claim 41 words
A coating composition according to claim 1 consisting essentially of from about 7.0 to about 8.5 weight percent cobalt, from about 2.5 to about 3.5 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 4
Dependent Claim 18 words
A coating composition according to claim 1 having a hardness value in excess of 900 DPH 300 .
Claim 5
Dependent Claim 56 words
A coating composition according to claim 1 wherein the substrate is a metallic material selected from the group consisting of steel, stainless steel, iron base alloys, nickel, nickel base alloys, cobalt, cobalt base alloys, chromium, chromium base alloys, titanium, titanium base alloys, aluminum, aluminum base alloys, copper, copper base alloys, refractory metals, and refractory-metal base alloys.
Claim 6
Dependent Claim 25 words
A coating composition according to claim 1 wherein the substrate is a non metallic material selected from the group consisting of carbon, graphite and polymers.
Claim 7
Dependent Claim 59 words
An article comprising a substrate and a coating composition applied to said substrate by a thermal spray process, said coating composition which has been applied consisting essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 8
Dependent Claim 59 words
An article comprising a substrate and a coating composition applied to said substrate by a thermal spray process, said coating composition which has been applied consisting essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 9
Dependent Claim 44 words
An article according to claim 6 wherein said coating composition consists essentially of from about 7.0 to about 8.5 weight percent cobalt, from about 2.5 to about 3.5 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 10
Dependent Claim 107 words
An article comprising a substrate and a coating composition applied to said substrate by a D-Gun deposition process, wherein said coating composition which has been applied consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten, and wherein said coating has a hardness value in excess of about 900 DPH 300 , an average volume loss of about 1.1 mm 3 per 1000 revolutions when subjected to a standard dry sand/rubber wheel abrasion test and which is easily ground to a smooth finish.
Claim 11
Dependent Claim 107 words
An article comprising a substrate and a coating composition applied to said substrate by a D-Gun deposition process, wherein said coating composition which has been applied consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten, and wherein said coating has a hardness value in excess of about 900 DPH 300 , an average volume loss of about 1.1 mm 3 per 1000 revolutions when subjected to a standard dry sand/rubber wheel abrasion test and which is easily ground to a smooth finish.
Claim 12
Dependent Claim 23 words
An article according to claim 10 wherein the major portion of said coating composition comprises a mixture of WC and (W,Cr,Co) 2 C.
Claim 13
Dependent Claim 107 words
An article comprising a substrate and a coating composition applied to said substrate by a plasma spray process, wherein said coating composition which has been applied consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten, and wherein said coating has a hardness value in excess of about 830 DPH 300 , an average volume loss of about 4.1 mm 3 per 1000 revolutions when subjected to a standard dry sand/rubber wheel abrasion test and which is easily ground to a smooth finish.
Claim 14
Dependent Claim 107 words
An article comprising a substrate and a coating composition applied to said substrate by a plasma spray process, wherein said coating composition which has been applied consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten, and wherein said coating has a hardness value in excess of about 830 DPH 300 , an average volume loss of about 4.1 mm 3 per 1000 revolutions when subjected to a standard dry sand/rubber wheel abrasion test and which is easily ground to a smooth finish.
Claim 15
Dependent Claim 23 words
An article according to claim 10 wherein the major portion of said coating composition comprises a mixture of WC and (W,Cr,Co) 2 C.
Claim 16
Dependent Claim 54 words
A powdered coating composition for applying a wear and corrosion resistant coating to a substrate by a thermal spray process consisting essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 17
Dependent Claim 54 words
A powdered coating composition for applying a wear and corrosion resistant coating to a substrate by a thermal spray process consisting essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 18
Dependent Claim 42 words
A powdered coating composition according to claim 12 consisting essentially of from about 7.0 to about 8.5 weight percent cobalt, from about 2.5 to about 3.5 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 19
Dependent Claim 12 words
A powdered coating composition according to claim 12 consisting of sintered powder.
Claim 20
Dependent Claim 42 words
A powdered coating composition according to claim 12 consisting essentially of from about 7.0 to about 9.0 weight percent cobalt from about 3.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 21
Dependent Claim 30 words
A powdered coating composition according to claim 15 consisting essentially of about 7.7 weight percent cobalt, about 3.5 weight percent chromium, about 3.8 weight percent carbon and the balance tungsten.
Claim 22
Dependent Claim 123 words
In a method for coating a substrate wherein a powdered coating material is suspended within a high temperature, high velocity gaseous stream and heated to a temperature at least close to the melting point thereof, said gaseous stream being directed against a surface of said substrate to deposit said powdered coating material and form a coating thereon, the improvement for increasing the wear resistance of said coating, said improvement comprising a powdered coating material having a composition such that the coating composition which has been deposited onto said substrate consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 23
Dependent Claim 123 words
In a method for coating a substrate wherein a powdered coating material is suspended within a high temperature, high velocity gaseous stream and heated to a temperature at least close to the melting point thereof, said gaseous stream being directed against a surface of said substrate to deposit said powdered coating material and form a coating thereon, the improvement for increasing the wear resistance of said coating, said improvement comprising a powdered coating material having a composition such that the coating composition which has been deposited onto said substrate consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 24
Dependent Claim 60 words
A method according to claim 17 wherein the powdered coating material has a composition such that the coating composition which has been deposited onto said substrate consists essentially of from about 7.0 to about 8.5 weight percent cobalt, from about 2.5 to about 3.5 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 25
Dependent Claim 26 words
A method according to claim 17 wherein the powdered coating material is suspended within a high temperature, high velocity gaseous stream produced by a detonation device.
Claim 26
Dependent Claim 48 words
A method according to claim 17 wherein the powdered coating material has a composition consisting essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 27
Dependent Claim 48 words
A method according to claim 20 wherein the powdered coating material has a composition consisting essentially of from about 7.0 to about 9.0 weight percent cobalt from about 3.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 28
Dependent Claim 26 words
A method according to claim 12 wherein the powdered coating material is suspended within a high temperature, high velocity gaseous stream produced by plasma arc torch.
Claim 29
Dependent Claim 25 words
A method according to claim 22 wherein the powdered coating material has a composition which is substantially the same as the composition of said coating.
Claim 30
Independent Claim 132 words
A method for coating a substrate comprising: feeding a mixture of oxygen and a fuel gas into the barrel of a detonation gun along with a powdered coating material; igniting the oxygen and fuel gas mixture to produce a detonation wave along the length of said barrel which accelerates said powdered coating material in a high temperature, high velocity gaseous stream; and directing said gaseous stream against a surface of said substrate to deposit said powdered coating material and form a coating thereon, said powdered coating material having a composition such that the coating deposited onto said substrate consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 31
Independent Claim 132 words
A method for coating a substrate comprising: feeding a mixture of oxygen and a fuel gas into the barrel of a detonation gun along with a powdered coating material; igniting the oxygen and fuel gas mixture to produce a detonation wave along the length of said barrel which accelerates said powdered coating material in a high temperature, high velocity gaseous stream; and directing said gaseous stream against a surface of said substrate to deposit said powdered coating material and form a coating thereon, said powdered coating material having a composition such that the coating deposited onto said substrate consists essentially of from about 6.5 to about 9.0 weight percent cobalt, from about 2.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 32
Dependent Claim 56 words
A method according to claim 24 wherein the powdered coating material has a composition such that the coating deposited onto said substrate consists essentially of from about 7.0 to about 8.5 weight percent cobalt, from about 2.5 to about 3.5 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 33
Dependent Claim 20 words
A method according to claim 24 wherein the ratio of oxygen to fuel gas in said mixture is approximately 1.0.
Claim 34
Dependent Claim 48 words
A method according to claim 26 wherein the powdered coating material has a composition consisting essentially of from about 7.0 to about 9.0 weight percent cobalt, from about 3.0 to about 4.0 weight percent chromium, from about 3.0 to about 4.0 weight percent carbon and the balance tungsten.
Claim 35
Dependent Claim 36 words
A method according to claim 27 wherein the powdered coating material has a composition consisting essentially of about 7.7 weight percent cobalt, about 3.5 weight percent chromium, about 3.8 weigh percent carbon and the balance tungsten.
Claim 36
Dependent Claim 23 words
A method according to claim 24 wherein the ratio of oxygen to fuel gas in said mixture is between about 1.1 and 1.2.
Claim 37
Dependent Claim 36 words
A method according to claim 29 wherein the powdered coating material has a composition consisting essentially of about 10 weight percent cobalt, about 4 weight percent chromium, about 5.2 weight percent carbon and the balance tungsten.

References Cited (Backward Citations)

US2714563A Cited
US2950867A Cited
US3016447A Cited
US3421890A Cited
US3914507A Cited
US4519840A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-01 1990-06-02 1990-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-01 1994-06-02 1994-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-01 1998-06-02 1998-12-02 $7700.00 Window Closed / Lapsed

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