Patent US4622277A successfully refreshed from Google Patents.
US4622277A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electrochemical cells
Assignee: Duracell Inc USA
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Filing: 1985-09-30
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Granted: 1986-11-11
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Expires: 2005-09-30
Abstract
Abstract This invention provides a design for spirally wound electrochemical cells which improves their safety during abuse such as voltage reversal. The invention comprises coupling a first segment of inert conductive metal to the cathode and a dendrite target comprised of an inert conductive metal to the anode. When these electrodes are spirally wound together the two segments of inert conductive metal face each other, held in physical separation by the separator, whereby during voltage reversal a dendrite grows from said first segment to said dendrite target.
Inventors
- 👤 Paul L. Bedder
- 👤 Peter R. Moses
- 👤 Bhupendra Patel
- 👤 Terrence F. Reise
- 👤 Alwyn H. Taylor
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 13:35
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/50; H01M6/5005; H01M6/04; H01M6/06; H01M6/10; H01M10/00; H01M10/42; H01M10/4235; H01M2200/00; H01M2200/30; H01M50/00; H01M50/50; H01M50/531; H01M50/534; H01M6/14; H01M6/16; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
153 words
An electrochemical cell having a positive terminal, a negative terminal, and at least two electrodes comprising: an anode connected to the negative terminal; a cathode connected to the positive terminal; a separator interposed between said anode and cathode; a nonaqueous electrolyte; a first segment of exposed inert conductive metal coupled mechanically and electrically to the cathode; and an inert metal dendrite target comprised of a second segment of exposed inert conductive metal coupled mechanically and electrically to the anode; wherein the position of said first segment of inert metal coupled to the cathode and the position of said second segment of inert metal coupled to the anode are such that said first segment and said second segment face each other and are held in physical separation by the separator, whereby during voltage reversal a dendrite will grow from said first segment toward said dendrite target and come in contact with said dendrite target.
Claim 2
Dependent Claim
153 words
An electrochemical cell having a positive terminal, a negative terminal, and at least two electrodes comprising: an anode connected to the negative terminal; a cathode connected to the positive terminal; a separator interposed between said anode and cathode; a nonaqueous electrolyte; a first segment of exposed inert conductive metal coupled mechanically and electrically to the cathode; and an inert metal dendrite target comprised of a second segment of exposed inert conductive metal coupled mechanically and electrically to the anode; wherein the position of said first segment of inert metal coupled to the cathode and the position of said second segment of inert metal coupled to the anode are such that said first segment and said second segment face each other and are held in physical separation by the separator, whereby during voltage reversal a dendrite will grow from said first segment toward said dendrite target and come in contact with said dendrite target.
Claim 3
Dependent Claim
121 words
The cell recited in claim 1 wherein said anode is comprised of an alkali or alkaline earth metal having a length substantially greater than width; wherein said cathode is comprised of a cathode material compressingly adhered to a conductive metal grid and said cathode has a length substantially greater than width; wherein said anode and said cathode have lengths such that the cathode is longer than the anode, such that when said anode, cathode, and separator are spirallly wound together a length of anode protrudes from between a first and a second outermost spirals of cathode, said protruding length being no greater than 25% of the circumference of the cell, and said protruding length being the location of said dendrite target.
Claim 4
Dependent Claim
58 words
The cell recited in claim 2 wherein said first segment of inert metal coupled to the cathode is an exposed segment, on just one side of the cathode, of the conductive metal grid, said area of exposure being no greater than 5%, but not less than 1%, of the cathode surface area on that side of the cathode.
Claim 5
Dependent Claim
75 words
The cell recited in claim 3 wherein said dendrite target of inert metal coupled to the anode is comprised of a strip of metal positioned so that its lengthwise direction is perpendicular to the lengthwise direction of the anode, said target having a thickness greater than 1 mil but less than one half the thickness of the cathode, said target also functioning as an anode tab for connection to the negative terminal of the cell.
Claim 6
Dependent Claim
34 words
The cell recited in claim 4 wherein said dendrite target coupled to the anode is selected from the group consisting of nickel, nickel plated cold rolled steel, copper, stainless steel, and cold rolled steel.
Claim 7
Dependent Claim
109 words
The cell recited in claim 3 wherein said dendrite target of inert metal coupled to the anode is comprised of a piece of metal having an area not greater than 5% of the anode surface area but less than the surface area of the exposed metal grid of the cathode, said target having a thickness greater than 1 mil but less than one half the thickness of the cathode, said target fixed onto the surface of the anode such that it does not extend beyond any edge of the anode, and located behind and aligned with said target on the other side of the anode is an anode tab.
Claim 8
Dependent Claim
34 words
The cell recited in claim 6 wherein said dendrite target coupled to the anode is selected from the group consisting of nickel, nickel plated cold rolled steel, copper, stainless steel, and cold rolled steel.
Claim 9
Dependent Claim
26 words
The cell recited in claim 6 wherein the anode is comprised of lithium and the nonaqueous electrolyte comprises a cathode active material of SO 2 .
Claim 10
Dependent Claim
31 words
The cell recited in claim 3 wherein the conductive metal grid is comprised of a metal selected from the group consisting of metals or alloys that form an alloy with lithium.
Claim 11
Dependent Claim
30 words
The cell recited in claim 3 wherein the conductive metal grid is comprised of a metal selected from the group consisting of titanium, tantalum, niobium, aluminum, stainless steel, or nickel.
Claim 12
Dependent Claim
14 words
The cell recited in claim 3 wherein the anode is lithium or alloys thereof.
Claim 13
Dependent Claim
32 words
The cell recited in claim 3 wherein the cathode material is selected from the group consisting of carbons, metal oxides, carbon fluorides, metal sulfides, transition metal polysulfides, metal halides, and mixtures thereof.
Claim 14
Dependent Claim
90 words
The cell recited in claim 3 wherein the cathode material is selected from the group consisting of MnO 2 , CFx, V 2 O 5 , WO 3 , MoO 3 , MoS 2 , lead oxides, cobalt oxides, copper oxides, CuS, CuS 2 , In 2 O 3 , iron sulfides, NiS, Ag 2 CrO 4 , Ag 3 PO 4 , TiS 2 , transition metal polysulfides, CoCl 2 , NiCl 2 , FeBr 3 , PbCl 2 , CuCl 2 , CuBr 2 , and mixtures thereof.
Claim 15
Dependent Claim
41 words
The cell recited in claim 3 wherein the cathode material is comprised of carbon and the nonaqueous electrolyte comprises a cathode active material selected from the group consisting of SO 2 , SOCl 2 , and SO 2 Cl 2 .
Claim 16
Dependent Claim
26 words
The cell recited in claim 1 wherein the anode is comprised of lithium and the nonaqueous electrolyte comprises a cathode active material of SO 2 .
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-11-10 | 1990-05-12 | 1990-11-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-11-10 | 1994-05-12 | 1994-11-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-11-10 | 1998-05-12 | 1998-11-11 | $7700.00 | Window Closed / Lapsed |