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US4621071A
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Composite catalyst for treatment of vehicular exhaust gases and process for the preparation of the catalyst
Assignee: Pro Catalyse SA
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Filing: 1984-12-07
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Granted: 1986-11-04
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Expires: 2004-12-07
Abstract
Abstract A composite active phase/support catalyst adapted for the treatment of internal combustion engine exhaust gases, the active phase of which comprising at least one metal from a first group comprising platinum, palladium, iridium, rhodium, ruthenium, rhenium, silver, gold or plurality thereof and at least one additional metal and the support therefor comprising binder/filler admixture, is facilely prepared by (i) intimately admixing the binder and filler support material with at least 50% by weight but less than all of said at least one first group metal, or precursor thereof, and/or of said at least one additional metal, (ii) forming the resulting admixture into catalyst shaped article, (iii) drying and optionally calcining said catalyst shaped article, (iv) incorporating the remainder of said at least one first group metal, or precursor thereof, and/or said at least one additional metal into said catalyst shaped article, and then (v) drying and activating the composite catalyst.
Inventors
- 👤 Gilbert Blanchard
- 👤 Michel Prigent
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 20:00
CPC Classifications
B; B01; B01J; B01J37/00; B01J37/0009; B01J23/00; B01J23/38; B01J23/54; B01J23/56; B01J23/66; B01J37/02; B01J37/0236
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
241 words
A process for the preparation of a composite active phase/support catalyst adapted for the treatment of internal combustion engine exhaust gases, the active phase of which comprises at least one metal from a first group comprising platinum, palladium, iridium, rhodium, ruthenium, rhenium, silver and gold and at least one metal from an additional group comprises cobalt, zinc, manganese, nickel, tungsten, yttrium, a lanthanide, iron, copper, chromium, ziroconium, molybdenum, tin, calcium, strontium and barium and the support therefor comprising binder/filler admixture, which process comprises (i) forming a first intimate admixture of the binder material and said at least one metal from the first group, or precursor thereof, and/or said at least one metal from the additional group wherein the first admixture contains at least 50% by weight of the total in the composite catalyst of said at least one metal from the first group and/or at least 50% by weight of the total in the composite catalyst of said at least one metal from the additional group, (ii) combining the first admixture with filler to form a second intimate admixture, (iii) forming the second admixture into a catalyst shaped article, (iv) optionally calcining said catalyst shaped article, (v) in an aqueous medium incorporating the remainder of said at least one metal from the first group, or precursor thereof, and/or said at least one metal from the additional group into said catalyst shaped article, and thence (vi) drying and activating the composite catalyst.
Claim 2
Dependent Claim
241 words
A process for the preparation of a composite active phase/support catalyst adapted for the treatment of internal combustion engine exhaust gases, the active phase of which comprises at least one metal from a first group comprising platinum, palladium, iridium, rhodium, ruthenium, rhenium, silver and gold and at least one metal from an additional group comprises cobalt, zinc, manganese, nickel, tungsten, yttrium, a lanthanide, iron, copper, chromium, ziroconium, molybdenum, tin, calcium, strontium and barium and the support therefor comprising binder/filler admixture, which process comprises (i) forming a first intimate admixture of the binder material and said at least one metal from the first group, or precursor thereof, and/or said at least one metal from the additional group wherein the first admixture contains at least 50% by weight of the total in the composite catalyst of said at least one metal from the first group and/or at least 50% by weight of the total in the composite catalyst of said at least one metal from the additional group, (ii) combining the first admixture with filler to form a second intimate admixture, (iii) forming the second admixture into a catalyst shaped article, (iv) optionally calcining said catalyst shaped article, (v) in an aqueous medium incorporating the remainder of said at least one metal from the first group, or precursor thereof, and/or said at least one metal from the additional group into said catalyst shaped article, and thence (vi) drying and activating the composite catalyst.
Claim 3
Dependent Claim
33 words
The process as defined by claim 1, wherein said steps (i) and (ii) of forming intimate admixtures comprise formulating them in aqueous medium and step (iv) is preceded by drying the shaped catalyst.
Claim 4
Dependent Claim
16 words
The process as defined by claim 2, comprising formulating dispersed binder material and undispersed filler material.
Claim 5
Dependent Claim
12 words
The process as defined by claim 1, said binder/filler support comprising alumina.
Claim 6
Dependent Claim
47 words
The process as defined by claim 1, wherein at least 50% by weight of said at least one metal from the first group, or precursor thereof, and all of said at least one metal from the additional group are intimately admixed in said steps (i) and (ii).
Claim 7
Dependent Claim
31 words
The process as defined by claim 1, wherein said at least one metal from the first group, or precursor thereof, is incorporated into the catalyst shaped article in said step (v).
Claim 8
Dependent Claim
53 words
The process as defined by claim 1, said binder and filler material comprising the hydroxides or oxides of aluminum, silicon, titanium, zirconium, magnesium, calcium, strontium, barium, yttrium, a lanthanide, hafnium, thorium, niobium, tantalum, chromium, molybdenum, or tungsten, the amount of weight of binder material relative to filler material ranging from 10 to 80%.
Claim 9
Dependent Claim
24 words
The process as defined by claim 7, wherein said amount by weight of binder material relative to filler material ranges from 15 to 60%.
Claim 10
Dependent Claim
31 words
The process as defined by claim 7, the total amount of said at least one metal from the first group comprising from 0.005 to 0.8% by weight of said composite catalyst.
Claim 11
Dependent Claim
31 words
The process as defined by claim 9, the total amount of said at least one metal from the additional group comprising from 0.1 to 10% by weight of said composite catalyst.
Claim 12
Dependent Claim
43 words
The process as defined by claim 1, said at least one metal from the first group comprising platinum, palladium, iridium, rhodium, or plurality thereof, and said at least one metal from the additional group comprising cerium, iron, zironium, copper, yttrium, or plurality thereof.
Claim 13
Dependent Claim
45 words
The process as defined by claim 11, wherein said at least one metal from the additional group is incorporated with the binder material in said step (i) and platinum, iridium, rhodium, or plurality thereof, is incorporated into the catalyst shaped article in said step (v).
Claim 14
Dependent Claim
19 words
The process as defined by claim 12, wherein palladium is incorporated with the binder material in said step (i).
Claim 15
Dependent Claim
20 words
The process as defined by claim 12, wherein palladium is incorporated into the catalyst shaped article in said step (v).
Claim 16
Dependent Claim
22 words
The process as defined by claim 7, said binder material comprising aluminum hydroxide or oxyhydroxide and said filler material comprising aluminum oxide.
Claim 17
Dependent Claim
24 words
The process as defined by claim 1 wherein said metal from the first group is introduced into said binder during said admixing step (i).
Claim 18
Dependent Claim
39 words
The process as defined by claim 16 wherein a portion of said metal from the additional group is introduced the binder, in the filler, or in both the binder and the filler during said admixing step (i) and (ii).
Claim 19
Dependent Claim
24 words
The process as defined by claim 1 wherein said metal from the additional group is introduced into said binder during said admixing step (i).
Claim 20
Dependent Claim
25 words
The process as defined by claim 18 wherein said metal from the first group is incorporated into said catalyst shaped article during said step (v).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-11-03 | 1990-05-05 | 1990-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-11-03 | 1994-05-05 | 1994-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-11-03 | 1998-05-05 | 1998-11-04 | $7700.00 | Window Closed / Lapsed |