Isocyanate functional urethanes as flexibilizing additives in coating vehicles

Claim 2

A coating composition comprising: (i) 30-99 parts by weight of a thermoplastic or thermosetting film-forming polymer vehicle; and (ii) 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate having an average of at least 2.1 isocyanate groups per molecule and selected from the group consisting of the biurets and isocyanurates of linear aliphatic diisocyanates; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and which is selected from the group consisting of: ##STR11## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 12 carbons; R 2 is H or CH 3 ; R 3 and R 4 are independently aliphatic of 1 to about 12 carbons or H; R 5 is an aliphatic radical of 1 to about 8 carbons or nothing; X is ##STR12## where R 6 is an aliphatic radical of 1 to about 12 carbons; and (c) at least one diol having the formula: ##STR13## wherein R 7 is H or CH 3 and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is greater than 1.0 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.3:1 to 2.0:1.0.

Claim 3

The coating composition of claim 1 further characterized in that the thermoplastic or thermosetting film-forming vehicle is selected from the group of vehicles consisting of acrylic polymers, nitrocellulose polymers, polyurethane polymers, alkyd polymers and polyester polymers.

Claim 4

The coating composition of claim 1 further characterized in that it also contains an inert organic solvent.

Claim 5

The coating composition of claim 1 further characterized in that it also contains pigment.

Claim 6

The coating composition of claim 1 further characterized in that the film-forming polymer vehicle is an acrylic lacquer.

Claim 7

A substrate coated with the coating composition of claim 1.

Claim 8

A coating composition comprising: (i) 30-99 parts by weight of a thermoplastic or thermosetting film-forming vehicle; and (ii) 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate selected from the group consisting of the biuret and isocyanurate of hexamethylene diisocyanate; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and having the structure: ##STR14## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 6 carbons; R 2 is H or CH 3 ; and (c) at least one diol having the formula: ##STR15## wherein R 7 is H or CH 3 ; and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is from 1/0.5 to 1/0.99 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.5:1 to 2.0:1.

Claim 9

A coating composition comprising: (i) 30-99 parts by weight of a thermoplastic or thermosetting film-forming vehicle; and (ii) 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate selected from the group consisting of the biuret and isocyanurate of hexamethylene diisocyanate; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and having the structure: ##STR14## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 6 carbons; R 2 is H or CH 3 ; and (c) at least one diol having the formula: ##STR15## wherein R 7 is H or CH 3 ; and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is from 1/0.5 to 1/0.99 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.5:1 to 2.0:1.

Claim 10

The coating composition of claim 7 further characterized in that the thermoplastic or thermosetting vehicle is selected from the group of vehicles consisting of acrylic polymers, nitrocellulose polymers, polyurethane polymers, alkyd polymers and polyester polymers.

Claim 11

The coating composition of claim 7 further characterized in that it also contains an inert organic solvent.

Claim 12

The coating composition of claim 7 further characterized in that it also contains pigment.

Claim 13

The coating composition of claim 7 further characterized in that the film-forming polymer vehicle is an acrylic lacquer.

Claim 14

A substrate coated with the coating composition of claim 7.

Claim 15

A process for improving the flexibility of a thermoplastic or thermosetting film-forming polymer vehicle which process comprises adding to 30-99 parts by weight of the thermoplastic or thermosetting film-forming polymer vehicle 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate having an average of at least 2.1 isocyanate groups per molecule and selected from the group consisting of the biurets and isocyanurates of linear aliphatic diisocyanates; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and which is selected from the group consisting of: ##STR16## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 12 carbons; R 2 is H or CH 3 ; R 3 and R 4 are independently aliphatic of 1 to about 12 carbons or H; R 5 is an aliphatic radical of 1 to about 8 carbons or nothing; X is ##STR17## and where R 6 is an aliphatic radical of 1 to about 12 carbons; and (c) at least one diol having the formula: ##STR18## wherein R 7 is H or CH 3 and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is greater than 1.0 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.3:1 to 2.0:1.0.

Claim 16

A process for improving the flexibility of a thermoplastic or thermosetting film-forming polymer vehicle which process comprises adding to 30-99 parts by weight of the thermoplastic or thermosetting film-forming polymer vehicle 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate having an average of at least 2.1 isocyanate groups per molecule and selected from the group consisting of the biurets and isocyanurates of linear aliphatic diisocyanates; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and which is selected from the group consisting of: ##STR16## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 12 carbons; R 2 is H or CH 3 ; R 3 and R 4 are independently aliphatic of 1 to about 12 carbons or H; R 5 is an aliphatic radical of 1 to about 8 carbons or nothing; X is ##STR17## and where R 6 is an aliphatic radical of 1 to about 12 carbons; and (c) at least one diol having the formula: ##STR18## wherein R 7 is H or CH 3 and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is greater than 1.0 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.3:1 to 2.0:1.0.

Claim 17

A process for improving the flexibility of a thermoplastic or thermosetting film-forming polymer vehicle which process comprises adding to about 30-99 parts by weight of the thermoplastic or thermosetting film-forming polymer vehicle from 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate selected from the group consisting of the biuret and the isocyanurate of hexamethylene diisocyanate; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and having the structure: ##STR19## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 6 carbons; R 2 is H or CH 3 ; and (c) at least one diol having the formula: ##STR20## wherein R 7 is H or CH 3 ; and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is from 1/0.5 to 1/0.99 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.5:1 to 2.0:1.

Claim 18

A process for improving the flexibility of a thermoplastic or thermosetting film-forming polymer vehicle which process comprises adding to about 30-99 parts by weight of the thermoplastic or thermosetting film-forming polymer vehicle from 1-70 parts by weight of an isocyanate functional urethane which comprises the reaction product of: (a) an aliphatic polyisocyanate selected from the group consisting of the biuret and the isocyanurate of hexamethylene diisocyanate; and (b) at least one monofunctional alcohol having a molecular weight less than about 500 and having the structure: ##STR19## wherein n is from 1 to about 10; R 1 is an aliphatic radical of 1 to about 6 carbons; R 2 is H or CH 3 ; and (c) at least one diol having the formula: ##STR20## wherein R 7 is H or CH 3 ; and y is from 1 to about 40; wherein the total NCO/OH equivalents ratio is from 1/0.5 to 1/0.99 and the ratio of OH equivalents from (b) to OH equivalents from (c) ranges from 0.5:1 to 2.0:1.