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US4619951A Expired / Lapsed US ⏱️ 0.0 years remaining

Sealing compositions for electric cables

Assignee: Huels AG
•
Filing: 1985-09-20
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Granted: 1986-10-28
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Expires: 2005-09-20
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Abstract

Abstract The present invention relates to a method of manufacturing sealing compositions for electric wires, wherein one mixes together a filler (comprised chiefly of an alkaline earth carbonate), a binder component, and possibly additives of the type common in the art. The binder component is a combination of two binders: binder I is a homopolymer of 1,3-butadiene or a copolymer which is essentially obtained from 1,3-butadiene; and binder II is a polymer based on 1,3-butadiene and having laterally extending succinic anhydride groups. The sealing compositions are distinguished by good processibility and high dielectric strength.

Inventors

  • 👤 Klaus Gorke
  • 👤 Josef Schoppen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:25
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; C; C08; C08K; C08K3/00; C08K3/18; C08K3/24; C08K3/26; C09; C09D; C09D109/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 241 words
A sealing composition for electric wires comprising: a binder component; and an inorganic, water-insoluble, powdered filler material; wherein: a. the binder component is a combination of two binders--binder I (in an amount of 70-97 wt. %), and binder II (in an amount of 3-30 wt. %); a.1 binder I is a homopolymer of 1,3-butadiene or a copolymer based on 1,3-butadiene (in an amount of ≧80 wt. %) and at least one other copolymerizable 1,3-diene or 1,3-cyclodiene or at least one other copolymerizable alpha-olefin (in an amount of ≦20 wt. %) (with the indicated composition of the said copolymer determined by IR analysis); the average relative molecular weight (referred to hydrogen), Mn, of the homopolymer or copolymer is 500 to 5,000, and its viscosity (at 20° C. according to DIN 53 015) is 2-80 dPa-sec; a.2 binder II is a polymer based on 1,3-butadiene with laterally extending succinic anhydride groups (i.e., a maleinized polymer based on 1,3-butadiene) with an acid number of 15 to 150 (mg KOH/g); this polymer being prepared by adding maleic anhydride to a polymer of the type of binder I (feature a.1); and b. the filler material is comprised of at least 80 wt. % of an alkaline earth carbonate which has not been provided with a hydrophobic coating and which is capable of reacting with the anhydride groups of binder II; said filler being present in an amount of 65-80 wt. % of the total sealing composition.
Claim 2
Dependent Claim 241 words
A sealing composition for electric wires comprising: a binder component; and an inorganic, water-insoluble, powdered filler material; wherein: a. the binder component is a combination of two binders--binder I (in an amount of 70-97 wt. %), and binder II (in an amount of 3-30 wt. %); a.1 binder I is a homopolymer of 1,3-butadiene or a copolymer based on 1,3-butadiene (in an amount of ≧80 wt. %) and at least one other copolymerizable 1,3-diene or 1,3-cyclodiene or at least one other copolymerizable alpha-olefin (in an amount of ≦20 wt. %) (with the indicated composition of the said copolymer determined by IR analysis); the average relative molecular weight (referred to hydrogen), Mn, of the homopolymer or copolymer is 500 to 5,000, and its viscosity (at 20° C. according to DIN 53 015) is 2-80 dPa-sec; a.2 binder II is a polymer based on 1,3-butadiene with laterally extending succinic anhydride groups (i.e., a maleinized polymer based on 1,3-butadiene) with an acid number of 15 to 150 (mg KOH/g); this polymer being prepared by adding maleic anhydride to a polymer of the type of binder I (feature a.1); and b. the filler material is comprised of at least 80 wt. % of an alkaline earth carbonate which has not been provided with a hydrophobic coating and which is capable of reacting with the anhydride groups of binder II; said filler being present in an amount of 65-80 wt. % of the total sealing composition.
Claim 3
Dependent Claim 22 words
The sealing composition of claim 1, wherein the said homopolymer or copolymer of feature a.1 is modified by isomerization or partial cyclization.
Claim 4
Dependent Claim 189 words
The sealing composition of claim 1, wherein: c. the binder component is comprised of binder I in an amount of 80-95 wt. % and binder II in an amount of 5-20 wt. %; c.1 binder I is a homopolymer of 1,3-butadiene; and has a content of ≦50 wt. % (based on IR analysis) of recurring units obtained by 1,4-trans-polymerization of 1,3-butadiene; an average relative molecular weight (based on hydrogen), Mn, of 1,000 to 4,000; and a viscosity of 6-60 dPa-sec; c.2 binder II has an acid number of 30-100; and is prepared by adding maleic anhydride to a polymer which is a homopolymer of 1,3-butadiene with a content of ≦50 wt. % of recurring units obtained by 1,4-trans-polymerization of 1,3-butadiene; and has Mn=1,000 to 3,000; and a viscosity of 6-40 dPa-sec; and d. the filler material is a natural calcium carbonate or calcium magnesium carbonate; its particle size distribution is characterized as follows (by sieve analysis): 90 wt. % <5-150 micron, and <35 wt. % <1 micron; and the said filler is present in an amount of 70-78 wt. % (based on the total weight of the sealing composition).
Claim 5
Dependent Claim 24 words
The sealing composition of claim 1, wherein the said sealing composition comprises a fire retardant, a smoke inhibitor, a drying agent or a siccative.
Claim 6
Dependent Claim 23 words
The sealing composition of claim 4, wherein the said drying agent is a molecular sieve or wherein the said siccative is cobalt octoate.
Claim 7
Dependent Claim 15 words
The sealing composition of claim 1, wherein said binder I is prepared by Ziegler polymerization.
Claim 8
Dependent Claim 18 words
The sealing composition of claim 6, wherein the said Ziegler polymerization is carried out with a nickel catalyst.
Claim 9
Dependent Claim 16 words
The sealing composition of claim 3, wherein the said binder I is prepared by Ziegler polymerization.
Claim 10
Dependent Claim 17 words
The sealing composition of claim 8, wherein the said Ziegler polymerization is run with a nickel catalyst.

References Cited (Backward Citations)

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JPS56109237A Cited
DE3104196A1 Cited
US4352906A Cited
US4444924A Cited
US4447564A Cited
FR2538808A1 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-10-27 1990-04-28 1990-10-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-10-27 1994-04-28 1994-10-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-10-27 1998-04-28 1998-10-28 $7700.00 Window Closed / Lapsed

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