Abstract An improved digestion chamber (10) is provided for use in a carbon analysis system. A catalyst (16), selected from the platinum metals group consisting of platinum, rhodium, palladium, osmium, iridium and ruthenium, provides an oxidizing surface for the sample being analyzed. The oxidant (26) is preferably persulfate, which may be stored in a generally stable solution until needed for sample oxidation. The catalyst (16) may be provided as a digestion chamber wire insert, such as a rod or as a plating on the chamber walls, enabling an increased variety of materials to be used for the vessel. In a preferred embodiment of the digestion chamber, polytetrafluoroethylene is used to reduce the background carbon which must be corrected in the analysis.
A process for analyzing the carbon content of a carbon-containing sample by reacting said sample with an oxidizing agent in a wet oxidation process to generate carbon dioxide in a digestion chamber, comprising the steps of: introducing said oxidizing agent within said digestion chamber; introducing said sample within said digestion chamber; contacting said sample with said oxidizing agent on a catalytic surface formed from a member of the platinum materials group consisting of platinum, rhodium, paladium, osmium, iridium and ruthenium; heating said sample and said oxidizing agent contacting said catalytic surface to a temperature in a range effective to generate carbon dioxide in a liquid phase oxidation reaction; withdrawing said carbon dioxide from said digestion chamber; and analyzing said carbon dioxide withdrawn from said digestion chamber.
Claim 2
Dependent Claim
126 words
A process for analyzing the carbon content of a carbon-containing sample by reacting said sample with an oxidizing agent in a wet oxidation process to generate carbon dioxide in a digestion chamber, comprising the steps of: introducing said oxidizing agent within said digestion chamber; introducing said sample within said digestion chamber; contacting said sample with said oxidizing agent on a catalytic surface formed from a member of the platinum materials group consisting of platinum, rhodium, paladium, osmium, iridium and ruthenium; heating said sample and said oxidizing agent contacting said catalytic surface to a temperature in a range effective to generate carbon dioxide in a liquid phase oxidation reaction; withdrawing said carbon dioxide from said digestion chamber; and analyzing said carbon dioxide withdrawn from said digestion chamber.
Claim 3
Dependent Claim
28 words
The process according to claim 1, wherein said oxidizing agent is selected from a group consisting of persulfate, perchlorate, permanganate, dichromate, ozone, peroxide, sulphuric acid and nitric acid.
Claim 4
Dependent Claim
17 words
The process according to claim 1, wherein said temperature range is 90 degrees to 100 degrees Centigrade.