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US4618634A Expired / Lapsed US ⏱️ 0.0 years remaining

Compounds containing piperidine groups, as stabilizers for synthetic polymers

Assignee: BASF Corp
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Filing: 1985-02-27
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Granted: 1986-10-21
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Expires: 2005-02-27
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Abstract

Abstract Novel compounds containing piperidine groups, of the general formula ##STR1## in which R 1 is hydrogen, O--, cyanomethyl, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkynyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, m is an integer from 1 to 12, n is an integer from 1 to 3 and A is an amine radical, are suitable as light stabilizers, heat stabilizers and oxidation stabilizers for synthetic polymers. Processes for their preparation are also described.

Inventors

  • 👤 Giuseppe Cantatore
  • 👤 Valerio Borzatta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:10
CPC Classifications
C; C07; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/40; C07D211/44; C07D211/46

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 325 words
A compound of the formula ##STR26## in which R 1 is hydrogen, O--, cyanomethyl, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkylnyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, m is an integer from 1 to 12 and n is an integer from 1 to 3, and, if n=1, A is a radical ##STR27## in which R 2 and R 3 can be identical or different and are hydrogen, C 1 -C 18 -alkyl, C 1 -C 18 -alkyl substituted by C 1 -C 18 -alkoxy or C 2 -C 18 -dialkylamino, C 3 -C 18 -alkenyl, C 5 -C 18 -cycloalkyl, C 6 -C 18 -aryl, C 7 -C 18 -aralkyl or a radical of the formula (II) ##STR28## in which R 1 is as defined above, or A is a monovalent radical of a 5-membered to 13-membered heterocyclic compound containing at least one nitrogen atom, the free valency being on the nitrogen atom, and, with n=2, A is a radical of the formula (III), (IV) or (V) ##STR29## in which R 4 , R 6 and R 17 can be identical or different and are as defined for R 2 and R 3 , R 5 is C 2 -C 18 -alkylene, C 4 -C 18 -alkylene substituted by 1 to 3 oxygen atoms, C 5 -C 12 -cycloalkylene, C 6 -C 12 -arylene or C 7 -C 12 -aralkylene, the radicals R 7 -R 16 can be identical or different and are hydrogen or methyl, R 9 together with R 10 and R 13 together with R 14 can be oxygen, p and l indipendently are zero or 1, and, with n=3, A is a radical of the formula (VI) ##STR30## in which R 4 and R 6 are as defined above and q and r can be identical or different and are integers from 2 to 6, or A is a hexahydro-1,3,5-triazine-1,3,5-triyl radical.
Claim 2
Dependent Claim 325 words
A compound of the formula ##STR26## in which R 1 is hydrogen, O--, cyanomethyl, C 1 -C 12 -alkyl, C 3 -C 12 -alkenyl or -alkylnyl, C 7 -C 12 -aralkyl or C 1 -C 12 -acyl, m is an integer from 1 to 12 and n is an integer from 1 to 3, and, if n=1, A is a radical ##STR27## in which R 2 and R 3 can be identical or different and are hydrogen, C 1 -C 18 -alkyl, C 1 -C 18 -alkyl substituted by C 1 -C 18 -alkoxy or C 2 -C 18 -dialkylamino, C 3 -C 18 -alkenyl, C 5 -C 18 -cycloalkyl, C 6 -C 18 -aryl, C 7 -C 18 -aralkyl or a radical of the formula (II) ##STR28## in which R 1 is as defined above, or A is a monovalent radical of a 5-membered to 13-membered heterocyclic compound containing at least one nitrogen atom, the free valency being on the nitrogen atom, and, with n=2, A is a radical of the formula (III), (IV) or (V) ##STR29## in which R 4 , R 6 and R 17 can be identical or different and are as defined for R 2 and R 3 , R 5 is C 2 -C 18 -alkylene, C 4 -C 18 -alkylene substituted by 1 to 3 oxygen atoms, C 5 -C 12 -cycloalkylene, C 6 -C 12 -arylene or C 7 -C 12 -aralkylene, the radicals R 7 -R 16 can be identical or different and are hydrogen or methyl, R 9 together with R 10 and R 13 together with R 14 can be oxygen, p and l indipendently are zero or 1, and, with n=3, A is a radical of the formula (VI) ##STR30## in which R 4 and R 6 are as defined above and q and r can be identical or different and are integers from 2 to 6, or A is a hexahydro-1,3,5-triazine-1,3,5-triyl radical.
Claim 3
Dependent Claim 96 words
A compound according to claim 1 of the formula (I), in which R 1 is hydrogen, methyl, allyl, benzyl or acetyl, m is 1 to 6, R 2 , R 3 , R 4 , R 6 and R 17 are hydrogen, C 1 -C 12 -alkyl, 3-(C 1 -C 6 -alkoxy)-propyl, C 6 -C 12 -cycloalkyl or a radical of the formula (II) ##STR31## in which R 1 is as defined above, and R 5 is C 2 -C 12 -alkylene or A as a heterocyclic radical is piperidin-1-yl, 2,2,6,6-tetramethyl-piperidin-1-yl, hexahydroazepin-1-yl, morpholin-4-yl, piperazine-1,4-diyl or 5,5,7-trimethylhomopiperazine-1,4-diyl.
Claim 4
Dependent Claim 66 words
A compound according to claim 1 of the formula (I), in which R 1 is hydrogen or methyl, m is 1 or 2, R 2 , R 3 , R 4 , R 6 and R 17 are C 1 -C 8 -alkyl, cyclohexyl, 2,2,6,6-tetramethyl-piperidin-4-yl or 1,2,2,6,6-pentamethyl-piperidin-4-yl and R 5 is C 2 -C 6 -alkylene or A as a heterocyclic radical, is piperiazine-1,4-diyl or 5,5,7-trimethylhomopiperazine-1,4-diyl.
Claim 5
Dependent Claim 10 words
The compound of the formula: ##STR32## according to claim 1.
Claim 6
Dependent Claim 10 words
The compound of the formula: ##STR33## according to claim 1.
Claim 7
Dependent Claim 10 words
The compound of the formula: ##STR34## according to claim 1.
Claim 8
Dependent Claim 10 words
The compound of the formula: ##STR35## according to claim 1.
Claim 9
Dependent Claim 10 words
The compound of the formula: ##STR36## according to claim 1.
Claim 10
Dependent Claim 37 words
A light-stabilised, heat-stabilised and oxidation-stabilised polymer composition comprising a synthetic polymer and one or more stabilisers of the formula (I) in a quantity from 0.01 to 5% by weight relative to the weight of the synthetic polymer.
Claim 11
Dependent Claim 37 words
A light-stabilised, heat-stabilised and oxidation-stabilised polymer composition comprising a synthetic polymer and one or more stabilisers of the formula (I) in a quantity from 0.01 to 5% by weight relative to the weight of the synthetic polymer.
Claim 12
Dependent Claim 21 words
A composition according to claim 9, which, in addition to the novel stabiliser, also comprises other conventional additives for synthetic polymers.
Claim 13
Dependent Claim 14 words
A composition according to claim 9, wherein the synthetic polymer is polypropylene or polyethylene.
Claim 14
Dependent Claim 23 words
A composition according to claim 9, comprising a synthetic polymer and as a stabilizer of formula I a compound of the formula ##STR37##
Claim 15
Dependent Claim 23 words
A composition according to claim 9, comprising a synthetic polymer and as a stabilizer of formula I a compound of the formula ##STR38##
Claim 16
Dependent Claim 29 words
A composition according to claim 9 wherein the quantity of the stabilizers by weight relative to the weight of the synthetic polymer is from 0.05 to 1% by weight.

References Cited (Backward Citations)

US4369321A Cited

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