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US4618554A
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Electrophotographic photoreceptor having photosensitive layer made of a phthalocyanine treated with an acrylic resin
Assignee: Minolta Co Ltd
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Filing: 1985-03-26
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Granted: 1986-10-21
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Expires: 2005-03-26
Abstract
Abstract An electrophotographic photoreceptor which has excellent electrophotographic characteristics even when exposed to high-temperature and high-humidity conditions is formed from a phthalocyanine which has been treated with an acrylic resin, the acrylic resin having been obtained by polymerization of not less than 15 mole % of a monomer represented by the general formula, <IMAGE> wherein R1 and R2 independently represent a hydrogen atom or an alkyl, aryl or cycloalkyl group, or R1 and R2, taken together, may form a heterocyclic-ring containing a nitrogen atom, R3 represents a hydrogen atom or methyl group, and n represents an integer of 1 or more, or an acid salt of the monomer.
Inventors
- 👤 Masato Ohashi
- 👤 Motohiko Kashioka
- 👤 Shinichi Tamura
- 👤 Hiromitsu Katsura
- 👤 Hideaki Ueda
- 👤 Akihiro Nakamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 15:55
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/05; G03G5/0528; G03G5/0532; G03G5/0546; G03G5/06; G03G5/0664; G03G5/0696
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
131 words
An electrophotographic photoreceptor having a photosensitive layer comprising a binding resin and phthalocyanine dispersed therein, wherein the phthalocyanine has been treated with an acrylic resin in an amount of 0.5 to 50 parts by weight of acrylic resin based on 100 parts by weight of phthalocyanine; said acrylic resin having been obtained by polymerization of not less than 15 mole % of a monomer represented by the general formula (I), ##STR4## wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl, aryl or cycloalkyl group, or R 1 and R 2 , taken together, may form a heterocyclic-ring containing a nitrogen atom, R 3 represents a hydrogen atom or methyl group, and n represents an integer of 1 or more, or an acid salt of the monomer.
Claim 2
Dependent Claim
131 words
An electrophotographic photoreceptor having a photosensitive layer comprising a binding resin and phthalocyanine dispersed therein, wherein the phthalocyanine has been treated with an acrylic resin in an amount of 0.5 to 50 parts by weight of acrylic resin based on 100 parts by weight of phthalocyanine; said acrylic resin having been obtained by polymerization of not less than 15 mole % of a monomer represented by the general formula (I), ##STR4## wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl, aryl or cycloalkyl group, or R 1 and R 2 , taken together, may form a heterocyclic-ring containing a nitrogen atom, R 3 represents a hydrogen atom or methyl group, and n represents an integer of 1 or more, or an acid salt of the monomer.
Claim 3
Dependent Claim
69 words
An electrophotographic photoreceptor as described in claim 1, wherein a monomer represented by the general formula (I) is selected from the group consisting of the mono- or dimethylaminoethyl ester of acrylic or methacrylic acid, mono- or diethylaminoethyl ester of said acid, mono- or di-n-propylaminoethyl ester of said acid, tert-butyl-aminoethyl ester of said acid, mono- or dicyclohexylaminoethyl ester of said acid, piperidinoethyl ester of said acid and acid salts thereof.
Claim 4
Dependent Claim
45 words
An electrophotographic photoreceptor as described in claim 1 wherein the treatment of phthalocyanine with the acrylic resin is carried out by adding an aqueous slurry of phthalocyanine to an acid aqueous solution of the acrylic resin, and then making the resulting mixture neutral or alkaline.
Claim 5
Dependent Claim
44 words
An electrophotographic photoreceptor as described in claim 1, wherein the acrylic resin is produced from 15 to 100 mole % of the monomer represented by the general formula (I) or the acid salt thereof and 85 to 0 mole % of another polymerizable monomer.
Claim 6
Dependent Claim
24 words
An electrophotographic photoreceptor as described in claim 1, wherein the acrylic resin is soluble in acid aqueous solution, but insoluble in alkaline aqueous solution.
Claim 7
Dependent Claim
188 words
An electrophotographic photoreceptor having a photosensitive layer, said electrophotographic photoreceptor being formed by the steps of (1) providing a substrate, (2) polymerizing not less than 15 mole % of a monomer represented by the general formula (I), ##STR5## wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl, aryl or cycloalkyl group, or R 1 and R 2 , taken together, may form a heterocyclic-ring containing a nitrogen atom, R 3 represents a hydrogen atom or methyl group, and n represents an integer of 1 or more, or an acid salt of the monomer, thereby forming an acrylic resin, (3) treating a phthalocyanine compound with the acrylic resin obtained in step (2), the amount of acrylic resin used ranging from 0.5 to 50 parts by weight based on 100 parts by weight of the phthalocyanine compound, (4) dispersing the treated phthalocyanine compound obtained in step (3) with a binding resin to form a photoconductive composition, and (5) applying a layer of the photoconductive composition obtained in step (4) to said substrate provided in step (1), thus providing said electrophotographic photoreceptor having a photosensitive layer.
Claim 8
Dependent Claim
188 words
An electrophotographic photoreceptor having a photosensitive layer, said electrophotographic photoreceptor being formed by the steps of (1) providing a substrate, (2) polymerizing not less than 15 mole % of a monomer represented by the general formula (I), ##STR5## wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl, aryl or cycloalkyl group, or R 1 and R 2 , taken together, may form a heterocyclic-ring containing a nitrogen atom, R 3 represents a hydrogen atom or methyl group, and n represents an integer of 1 or more, or an acid salt of the monomer, thereby forming an acrylic resin, (3) treating a phthalocyanine compound with the acrylic resin obtained in step (2), the amount of acrylic resin used ranging from 0.5 to 50 parts by weight based on 100 parts by weight of the phthalocyanine compound, (4) dispersing the treated phthalocyanine compound obtained in step (3) with a binding resin to form a photoconductive composition, and (5) applying a layer of the photoconductive composition obtained in step (4) to said substrate provided in step (1), thus providing said electrophotographic photoreceptor having a photosensitive layer.
References Cited (Backward Citations)
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