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Carboxylic/sulfonic/polyalkylene oxide polymer for use as scale, corrosion, and iron oxide deposit control

Assignee: ECC SPECIALTY CHEMICALS Inc
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Filing: 1985-09-04
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Granted: 1986-10-21
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Expires: 2005-09-04
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Abstract

Abstract The instant invention is directed to a process for inhibiting corrosion and the formation and deposition of scale and iron oxide in aqueous systems, comprising adding to the system at least 0.1 ppm of a water-soluble polymer having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from: (a) 35 to 90%, by weight, of an unsaturated carboxylic acid, or its salt; (b) 5 to 40%, by weight of an unsaturated sulfonic acid, or its salt; and (c) 5 to 40%, by weight, of an unsaturated, polyalkylene oxide compound, the total of (a), (b) and (c) being 100% weight of the polymer.

Inventors

  • 👤 Charles Y. Cha
  • 👤 Richard G. Varsanik
  • 👤 Shih-Ruey T. Chen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 11:05
CPC Classifications
C; C02; C02F; C02F5/00; C02F5/08; C02F5/10; C02F5/12; C23; C23F; C23F11/00; C23F11/08; C23F11/10; C23F11/173; C23F14/00; C23F14/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 99 words
A process for inhibiting corrosion and the formation and deposition of scale and iron oxide in an aqueous system, comprising adding to said system at least 0.1 ppm of a water soluble polymer having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from: (a) 35 to 90%, by weight, of an unsaturated carboxylic acid, or its salt; (b) 5 to 40%, by weight, of an unsaturated sulfonic acid, or its salt; and (c) 5 to 40%, by weight, of an unsaturated, polyalkylene oxide compound, the total of (a), (b), and (c) being 100% by weight of the polymer.
Claim 2
Dependent Claim 99 words
A process for inhibiting corrosion and the formation and deposition of scale and iron oxide in an aqueous system, comprising adding to said system at least 0.1 ppm of a water soluble polymer having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from: (a) 35 to 90%, by weight, of an unsaturated carboxylic acid, or its salt; (b) 5 to 40%, by weight, of an unsaturated sulfonic acid, or its salt; and (c) 5 to 40%, by weight, of an unsaturated, polyalkylene oxide compound, the total of (a), (b), and (c) being 100% by weight of the polymer.
Claim 3
Dependent Claim 52 words
The process of claim 1, wherein said polymer is prepared from: (a) 50 to 70%, by weight, of an unsaturated carboxylic acid or its salt; (b) 10 to 40%, by weight, of an unsaturated sulfonic acid, or its salt; and (c) 10 to 30%, by weight, of an unsaturated, polyalkylene oxide compound.
Claim 4
Dependent Claim 17 words
The process of claim 1, wherein said polymer has an intrinsic viscosity of 0.05 to 0.5 dl/g.
Claim 5
Dependent Claim 14 words
The process of claim 1, wherein 0.1 to 100 ppm of polymer is added.
Claim 6
Dependent Claim 119 words
The process of claim 1, wherein: (a) said carboxylic compound is selected from the group consisting of acrylic acid, methacrylic acid, α-halo acrylic acid, itaconic acid, vinyl acetic acid, allyl acetic acid, β-carboxyethyl acrylate, fumaric acid, and maleic acid, or their salts; (b) said sulfonic compound is selected from the group consisting of 2-acrylamido-2-methyl propyl sulfonic acid, allyl sulfonic acid, styrene sulfonic acid and vinyl sulfonic acid, or their salts; and (c) said unsaturated, polyalkylene oxide compound is selected from the group consisting of allyl polyalkylene glycol, methallyl polyethylene glycol, polyethylene glycol acrylate, polyethylene glycol methacrylate, methoxy allyl polyethylene oxide, alkoxy allyl polyethylene oxide, polypropylene equivalents thereof and mixtures of polyethers formed from polyethylene oxide with other polyalkylene oxides.
Claim 7
Dependent Claim 62 words
The process of claim 5, wherein said carboxylic compound is selected from the group consisting of acrylic acid, methacrylic acid and their salts, said sulfonic compound is selected from the group consisting of 2-acrylamido-2-methyl propyl sulfonic acid, 2-methacrylamido-2-methylpropylsulfonic acid and their salts, and said unsaturated polyethylene oxide compound is selected from the group consisting of allyl polyethylene glycol and methallyl polyethylene glycol.
Claim 8
Dependent Claim 94 words
A water soluble polymer, having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from: (a) 35 to 90%, by weight, of an unsaturated carboxylic compound selected from the group consisting of acrylic acid, methacrylic acid, their salts and mixtures thereof; (b) 5 to 40%, by weight, of an unsaturated sulfonic compound selected from the group consisting of 2-acrylamido-2-methylpropylsulfonic acid, 2-methacrylamido-2-methylpropylsulfonic acid, their salts and mixtures thereof; and (c) 5 to 40%, by weight, of an unsaturated polyalkylene oxide compound, the total of (a), (b) and (c) being 100% by weight of the polymer.
Claim 9
Dependent Claim 94 words
A water soluble polymer, having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from: (a) 35 to 90%, by weight, of an unsaturated carboxylic compound selected from the group consisting of acrylic acid, methacrylic acid, their salts and mixtures thereof; (b) 5 to 40%, by weight, of an unsaturated sulfonic compound selected from the group consisting of 2-acrylamido-2-methylpropylsulfonic acid, 2-methacrylamido-2-methylpropylsulfonic acid, their salts and mixtures thereof; and (c) 5 to 40%, by weight, of an unsaturated polyalkylene oxide compound, the total of (a), (b) and (c) being 100% by weight of the polymer.
Claim 10
Dependent Claim 45 words
The water soluble polymer of claim 7, wherein said polymer is prepared from: (a) 50 to 70%, by weight, acrylic acid, or its salt; (b) 10 to 40%, by weight, 2-acrylamido-2-methyl propyl sulfonic acid, and (c) 10 to 30%, by weight, allyl methoxy polyethylene glycol.
Claim 11
Dependent Claim 19 words
The water soluble polymer of claim 7, wherein said polymer has an intrinsic viscosity of 0.05 to 0.5 dl/g.

References Cited (Backward Citations)

US3928196A Cited
JPS5784794A Cited
JPS58147413A Cited
JPS58149911A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-10-20 1990-04-21 1990-10-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-10-20 1994-04-21 1994-10-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-10-20 1998-04-21 1998-10-21 $7700.00 Window Closed / Lapsed

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