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US4617286A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for polyurethane having delay property

Assignee: Tosoh Corp
•
Filing: 1984-09-05
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Granted: 1986-10-14
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Expires: 2004-09-05
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Abstract

Abstract The disclosed catalyst for polyurethane comprises an organic carboxylic acid salt of a tertiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine. The tertiary amine compound is selected from the group of triethylenediamine, bis(2-dimethylaminoethyl)ether and N,N,N',N'',N''-pentamethyldiethylenetriamine and the organic carboxylic acid is selected from the organic carboxylic acids having 1-20 carbon atoms.

Inventors

  • 👤 Shoji Arai
  • 👤 Yutaka Tamano
  • 👤 Yukihiro Tsutsumi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:12
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/18; C08G18/1875; C08G18/20; C08G18/2009; C08G18/2027

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 58 words
A catalyst for the foaming of polyurethanes, comprising: the combination of an organic carboxylic acid salt of a teritiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine in 5-70% by weight of an organic solvent, wherein the amount of said 1-methyl-4-(2-dimethylaminoethyl)piperazine compound ranges from 0.01 to 10.0 times the molar amount of the tertiary amine component of said organic carboxylic acid salt.
Claim 2
Dependent Claim 58 words
A catalyst for the foaming of polyurethanes, comprising: the combination of an organic carboxylic acid salt of a teritiary amine compound and 1-methyl-4-(2-dimethylaminoethyl)piperazine in 5-70% by weight of an organic solvent, wherein the amount of said 1-methyl-4-(2-dimethylaminoethyl)piperazine compound ranges from 0.01 to 10.0 times the molar amount of the tertiary amine component of said organic carboxylic acid salt.
Claim 3
Dependent Claim 24 words
The catalyst of claim 1, wherein said tertiary amine compound is selected from the group consisting of triethylenediamine, bis(2-dimethylaminoethyl)ether, dimethylcyclohexylamine, N,N,N',N'-tetramethylhexamethylenediamine, N,N,N',N",N"-pentamethyldiethylenetriamine and N,N,N',N",N"-pentamethyldipropylenetriamine.
Claim 4
Dependent Claim 15 words
The catalyst of claim 2, wherein said tertiary amine compound is triethylenediamine, bis(2-dimethylaminoethyl)ether or N,N,N',N",N"-pentamethyldiethylenetriamine.
Claim 5
Dependent Claim 24 words
The catalyst of claim 1, wherein said organic carboxylic acid component of said salt is an organic carboxylic acid having from 1-20 carbon atoms.
Claim 6
Dependent Claim 40 words
The catalyst of claim 4, wherein said organic carboxylic acid is formic acid, acetic acid, propionic acid, butyric acid, caproic acid, 2-ethylhexanoic acid, caprylic acid, cyanoacetic acid, pyruvic acid, benzoic acid, oxalic acid, malonic acid, succinic acid or maleic acid.
Claim 7
Dependent Claim 16 words
The catalyst of claim 5, wherein said organic carboxylic acid is formic acid or 2-ethylhexanoic acid.
Claim 8
Dependent Claim 20 words
The catalyst of claim 1, wherein siad organic solvent is ethyleneglycol, diethyleneglycol, propylene glycol, dipropyleneglycol, a butanediol, 1,6-hexanediol or glycerine.
Claim 9
Dependent Claim 16 words
The catalyst of claim 7, wherein said organic solvent is ethyleneglycol, diethyleneglycol, propyleneglycol, dipropyleneglycol or 1,4-butanediol.
Claim 10
Dependent Claim 39 words
The catalyst of claim 1, wherein, in the preparation of said organic carboxylic acid salt, the amount of said organic carboxylic acid reacted with said tertiary amine ranges from 0.05 to 1.0 equivalents per 1 equivalent of amino group.
Claim 11
Dependent Claim 19 words
The catalyst of claim: 9, wherein the amount of said organic carboxylic acid ranges from 0.1 to 0.8 equivalents.

References Cited (Backward Citations)

US2949431A Cited
CA936649A Cited
GB1379985A Cited
US3862150A Cited
US4098731A Cited
US4165412A Cited
EP0004309A1 Cited
US4456696A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-10-13 1990-04-14 1990-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-10-13 1994-04-14 1994-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-10-13 1998-04-14 1998-10-14 $7700.00 Window Closed / Lapsed

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