US4617253A
Expired / Lapsed
US
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Polymeric pyridinium ylides and products prepared from same
Assignee: Intellectual Ventures I LLC
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Filing: 1984-06-06
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Granted: 1986-10-14
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Expires: 2004-06-06
Abstract
Abstract Polymers containing pyridinium ylide moieties are subjected to actinic irradiation to convert the pyridinium ylide moieties to water-insoluble or hydrophobic N-acyl-diazepine polymers. The polymeric pyridinium ylides can be used for the waterproofing or hydrophobization of surfaces and for the production of printing plates, photoresists, printed circuit boards and the like.
Inventors
- 👤 Lloyd D. Taylor
- 👤 Michael K. Haubs
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 11:12
CPC Classifications
C; C08; C08G; C08G18/00; C08F; C08F246/00; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/36; C08F20/52; C08F20/54; C08F20/60; G; G03; G03F; G03F7/00; G03F7/004; G03F7/038
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
74 words
A method for preparing an article carrying a layer of water-insoluble or hydrophobic protective polymer which comprises subjecting to actinic radiation, an article comprising a support carrying a layer of photosensitive polymeric pyridinium ylide, said article having between said support and said photosensitive polymeric pyridinium ylide, a layer of material etchable by physical or chemical means, said actinic radiation being sufficient to convert said polymeric ylide to a water-insoluble or hydrophobic N-acyl-diazepine protective polymer.
Claim 2
Independent Claim
74 words
A method for preparing an article carrying a layer of water-insoluble or hydrophobic protective polymer which comprises subjecting to actinic radiation, an article comprising a support carrying a layer of photosensitive polymeric pyridinium ylide, said article having between said support and said photosensitive polymeric pyridinium ylide, a layer of material etchable by physical or chemical means, said actinic radiation being sufficient to convert said polymeric ylide to a water-insoluble or hydrophobic N-acyl-diazepine protective polymer.
Claim 3
Independent Claim
106 words
A method for preparing an article carrying an image pattern of water-insoluble or hydrophobic protective polymer which comprises subjecting to an imagewise exposure to actinic radiation, an article comprising a support carrying a layer of photosensitive polymeric pyridinium ylide, said imagewise exposure being effective to expose predetermined areas of said layer of photosensitive polymeric pyridinium ylide to said actinic radiation, while other predetermined areas of said layer of photosensitive polymeric pyridinium ylide are shielded from exposure to said actinic radiation, thereby to imagewise selectively expose said layer of photosensitive polymeric pyridinium ylide and to form water-insoluble or hydrophobic N-acyl-diazepine protective polymer in said selectively exposed areas.
Claim 4
Independent Claim
106 words
A method for preparing an article carrying an image pattern of water-insoluble or hydrophobic protective polymer which comprises subjecting to an imagewise exposure to actinic radiation, an article comprising a support carrying a layer of photosensitive polymeric pyridinium ylide, said imagewise exposure being effective to expose predetermined areas of said layer of photosensitive polymeric pyridinium ylide to said actinic radiation, while other predetermined areas of said layer of photosensitive polymeric pyridinium ylide are shielded from exposure to said actinic radiation, thereby to imagewise selectively expose said layer of photosensitive polymeric pyridinium ylide and to form water-insoluble or hydrophobic N-acyl-diazepine protective polymer in said selectively exposed areas.
Claim 5
Dependent Claim
44 words
The method of claim 2 wherein the areas of said layer of photosensitive polymeric ylide shielded from exposure to said actinic radiation are removed from said support, thereby to provide on said support a predetermined pattern of said water-insoluble or hydrophobic N-acyl-diazepine protective polymer.
Claim 6
Independent Claim
106 words
A method for forming a photoresist which comprises the steps of: selectively exposing to actinic radiation, a photosensitive article comprising a support carrying a layer of metal, and having over said metallic layer, a layer of photosensitive polymeric ylide, said selective exposure being effected by exposing predetermined areas of said photosensitive layer to said actinic radiation while shielding other predetermined areas of said photosensitive layer from exposure to said actinic radiation, said actinic radiation being sufficient to convert said photosensitive polymeric ylide in said areas of exposure to a water-insoluble or hydrophobic N-acyl-diazepine protective polymer; and removing said photosensitive polymeric ylide from said areas of non-exposure.
Claim 7
Independent Claim
106 words
A method for forming a photoresist which comprises the steps of: selectively exposing to actinic radiation, a photosensitive article comprising a support carrying a layer of metal, and having over said metallic layer, a layer of photosensitive polymeric ylide, said selective exposure being effected by exposing predetermined areas of said photosensitive layer to said actinic radiation while shielding other predetermined areas of said photosensitive layer from exposure to said actinic radiation, said actinic radiation being sufficient to convert said photosensitive polymeric ylide in said areas of exposure to a water-insoluble or hydrophobic N-acyl-diazepine protective polymer; and removing said photosensitive polymeric ylide from said areas of non-exposure.
Claim 8
Dependent Claim
43 words
The method of claim 4 wherein said metal is removed by chemical or physical means from said areas of non-exposure, thereby to provide on said support, a predetermined pattern comprising predetermined areas of metal having thereover, said water-insoluble or hydrophobic N-acyl-diazepine protective polymer.
Claim 9
Dependent Claim
27 words
The method of claim 5 wherein said metal removal is effected by a chemical etching solution to which said water-insoluble or hydrophobic N-acyl-diazepine protective polymer is resistant.
Claim 10
Dependent Claim
18 words
The method of claim 4 wherein said support carrying a layer of metal comprises a metal-clad insulator board.
Claim 11
Dependent Claim
18 words
The method of claim 1 wherein said article is subjected to said actinic radiation in an imagewise manner.
Claim 12
Dependent Claim
49 words
The method of claim 2 wherein said photosensitive polymeric pyridinium ylide comprises a polymeric backbone having pendant therefrom or as part of said backbone, a pyridinium ylide moiety of the formula ##STR35## wherein X is ##STR36## or SO 2 --, where R 1 is alkyl, aryl, alkaryl or aralkyl.
Claim 13
Dependent Claim
14 words
The method of claim 9 wherein, in said pyridinium ylide moiety, X is ##STR37##
Claim 14
Dependent Claim
36 words
The method of claim 2 wherein said photosensitive polymeric pyridinium ylide comprises a plurality of repeating units having the formula ##STR38## wherein L is an organic linking group and m is the integer one or two.
Claim 15
Dependent Claim
43 words
The method of claim 11 wherein said photosensitive polymeric pyridinium ylide comprises a plurality of repeating units having the formula ##STR39## wherein L is an organic linking group, m is the integer one or two, and R is hydrogen, halo or lower alkyl.
Claim 16
Dependent Claim
44 words
The method of claim 12 wherein in said repeating units, L is a divalent radical of the formula ##STR40## --Ar--; or --Ar--R 3 --, wherein, in each radical, R is hydrogen, alkyl, aryl, alkaryl or aralkyl, and R 3 is a divalent alkylene radical.
Claim 17
Dependent Claim
36 words
The method of claim 12 wherein in said repeating units, R is hydrogen, or methyl, X is ##STR41## m is two, and L is a divalent radical of the formula ##STR42## wherein R 3 is 1,2-ethylene.
Claim 18
Dependent Claim
19 words
The method of claim 12 wherein said photosensitive polymeric pyridinium ylide includes repeating units from ethylenically unsaturated copolymerizable monomer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-10-13 | 1990-04-14 | 1990-10-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-10-13 | 1994-04-14 | 1994-10-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-10-13 | 1998-04-14 | 1998-10-14 | $7700.00 | Window Closed / Lapsed |