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US4614699A
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Liquid developers for electrostatic images
Assignee: Fujifilm Holdings Corp
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Filing: 1984-07-16
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Granted: 1986-09-30
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Expires: 2004-07-16
Abstract
Abstract A liquid developer for electrostatic images which comprises at least one charge controlling agent selected from the group consisting of compounds represented by formula (I) or (II) and complex salts containing a molecular structure shown by the formula (I) or (II): ##STR1## wherein R 1 and R 2 each represents a hydrogen atom, an alkyl and substituted alkyl group, an aryl and a substituted aryl group, an aralkyl group, an aliphatic acyl group, an aromatic acyl group, an alkylsulfonyl group, an arylsulfonyl group, R 1 and R 2 represent identical group or different groups, or R 1 and R 2 together form a heterocyclic ring with the nitrogen atom in the formulae, and when one of R 1 and R 2 represents a hydrogen atom, the other represents a group other than a hydrogen atom; A represents an alkylene group or a substituted alkylene group; X represents a hydrogen atom, a monovalent to tetravalent metal atom, a quaternary ammonium cation, and n represents a positive integer of 1 to 4, and when X represents the metal atom defined above and the number represented by n is not sufficient to satisfy the valence of the metal atom represented by X, the residual metal valence bond or bonds are occupied with one or more ligands to form the complex salt.
Inventors
- 👤 Katsugi Kitatani
- 👤 Masataka Murata
- 👤 Hiroaki Yokoya
- 👤 Nobuo Suzuki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 16:59
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/12; G03G9/135; G03G9/1355
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
263 words
A liquid developer for electrostatic images which comprises a liquid carrier having an electric resistance of at least 10 9 Ω·cm and a dielectric constant of not more than 3 and at least one negative charge controlling agent selected from the group consisting of compounds represented by formula (I) or (II) and complex salts containing a molecular structure shown by the formula (I) or (II): ##STR9## wherein R 1 and R 2 each represents a hydrogen atom, an alkyl and substituted alkyl group, and aryl and a substituted aryl group, an aralkyl group, an aliphatic acyl group, and aromatic acyl group, an alkylsulfonyl group, an arylsulfonyl group, R 1 and R 2 represent identical group or different groups, or R 1 and R 2 together form a heterocyclic ring with the nitrogen atom in the formulae, and when one of R 1 and R 2 represents an hydrogen atom, the other represents a group other than a hydrogen atom; A represents an alkylene group or a substituted alkylene group; X represents a hydrogen atom, a monovalent to tetravalent metal atom, a quarternary ammonium cation, and n represents a positive integer of 1 to 4, and when X represents the metal atom defined above and the number represented by n is not sufficient to satisfy the valence of the metal atom represented by X, the residual metal valence bond or bonds are occupied with one or more ligands to form the complex salt containing a molecular structure shown by the formula (I) or (II), said charge controlling agent being dissolved in said liquid carrier.
Claim 2
Dependent Claim
263 words
A liquid developer for electrostatic images which comprises a liquid carrier having an electric resistance of at least 10 9 Ω·cm and a dielectric constant of not more than 3 and at least one negative charge controlling agent selected from the group consisting of compounds represented by formula (I) or (II) and complex salts containing a molecular structure shown by the formula (I) or (II): ##STR9## wherein R 1 and R 2 each represents a hydrogen atom, an alkyl and substituted alkyl group, and aryl and a substituted aryl group, an aralkyl group, an aliphatic acyl group, and aromatic acyl group, an alkylsulfonyl group, an arylsulfonyl group, R 1 and R 2 represent identical group or different groups, or R 1 and R 2 together form a heterocyclic ring with the nitrogen atom in the formulae, and when one of R 1 and R 2 represents an hydrogen atom, the other represents a group other than a hydrogen atom; A represents an alkylene group or a substituted alkylene group; X represents a hydrogen atom, a monovalent to tetravalent metal atom, a quarternary ammonium cation, and n represents a positive integer of 1 to 4, and when X represents the metal atom defined above and the number represented by n is not sufficient to satisfy the valence of the metal atom represented by X, the residual metal valence bond or bonds are occupied with one or more ligands to form the complex salt containing a molecular structure shown by the formula (I) or (II), said charge controlling agent being dissolved in said liquid carrier.
Claim 3
Dependent Claim
45 words
A liquid developer for electrostatic images as in claim 1, wherein said substituted alkyl group represented by R 1 or R 2 has a substituent selected from the group consisting of a dialkylamino group, a cyclic amino group, an alkoxy group, and an alkylthio group.
Claim 4
Dependent Claim
60 words
A liquid developer for electrostatic images as in claim 1, wherein said substituted aryl group represented by R 1 or R 2 has a substituent selected from the group consisting of a dialkylamino group, a cyclic amino group, an alkoxy group, an alkylthio group, a chlorine atom, a bromine atom, a cyano group, a nitro group, and a hydroxyl group.
Claim 5
Dependent Claim
25 words
A liquid developer for electrostatic images as in claim 1, wherein said heterocyclic ring formed by R 1 and R 2 contains an oxygen atom.
Claim 6
Dependent Claim
38 words
A liquid developer for electrostatic images as in claim 1, wherein said substituted alkylene group represented by A contains a substituent selected from the group consisting of an alkyl group, a substituted alkyl group and an aryl group.
Claim 7
Dependent Claim
44 words
A liquid developer for electrostatic images as in claim 5, wherein said substituted alkyl group has a substituent selected from the group consisting of an aryl group, aromatic acylamino group, an alkylthio group, an aliphatic acylamino group, a dialkylamino group, and an alkoxy group.
Claim 8
Dependent Claim
32 words
A liquid developer for electrostatic images as in claim 1, wherein the total number of carbon atoms in R 1 and R 2 is in a range of from 8 to 36.
Claim 9
Dependent Claim
43 words
A liquid developer for electrostatic images as in claim 1, wherein said metal atom is selected from the group consisting of calcium, barium, manganese, copper, lithium, titanium, zinc, lead, zirconium, cobalt, nickel, aluminum, cerium, lanthanum, chromium, strontium, vanadium, tin, magnesium, iron and cadmium.
Claim 10
Dependent Claim
25 words
A liquid developer for electrostatic images as in claim 1, wherein said metal atom is selected from the group consisting of cobalt, nickel and titanium.
Claim 11
Dependent Claim
57 words
A liquid developer for electrostatic images as in claim 1, wherein said quarternary ammonium cation represented by X is selected from the group consisting of groups represented by the following formulae ##STR10## wherein said R 3 , R 4 , R 5 , R 6 and R 7 each represents an alkyl group and an aryl group.
Claim 12
Dependent Claim
33 words
A liquid developer for electrostatic images as in claim 1, wherein said ligand is selected from the group consisting of halogens, a hydroxyl group, an oxygen atom, water, ammonia, amines, phosphines, and sulfides.
Claim 13
Dependent Claim
43 words
A liquid developer for electrostatic images as in claim 1, wherein said charge controlling agent is selected from the group consisting of compounds represented by the following formulae ##STR11## wherein the valence of X is the same as the number represented by n.
Claim 14
Dependent Claim
74 words
A liquid developer for electrostatic images as in claim 1, wherein the number represented by n does not show a sufficient number of acid residue of formula (I) or (II) to satisfy the valence of the metal represented by X, and the residual velence bond or bonds of the metal are occupied by one or more ligands to form a complex salt containing a molecular structure shown by the general formula (I) or (II).
Claim 15
Dependent Claim
176 words
A liquid developer for electrostatic images as in claim 13, wherein said ligand is selected from the group consisting of compounds represented by the following formulae ##STR12## wherein R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 and R 19 each represents a hydrogen atom, an alkyl group or an aryl group, provided that in each formula R 15 , R 16 and R 17 , R 18 and R 19 do not all represent hydrogen atoms at the same time; or in each combination of two groups among R 8 , R 9 and R 10 , R 11 and R 12 , R 13 and R 14 , two groups among R 15 , R 16 and R 17 , and R 18 and R 19 each group represents an alkylene group or an oxyalkylene group to form a heterocyclic ring containing an N, P, or S atom in each formula.
Claim 16
Dependent Claim
60 words
A liquid developer for electrostatic images as in claim 1, wherein said charge controlling agent is used in a state of a reaction mixture produced by reacting an inorganic or organic metal salt and at least one compound represented by the formulae ##STR13## wherein definitions of R 1 , R 2 and A are the same as in claim 1.
Claim 17
Dependent Claim
23 words
A liquid developer for electrostatic images as in claim 15, wherein said inorganic metal salt is selected from titanium salts and zirconium salts.
Claim 18
Dependent Claim
70 words
A liquid developer for electrostatic images as in claim 15, wherein said organic metal salt is a compound represented by the formula R.sub.m TiY.sub.4-m wherein R represents an alkyl group, an aralkyl group, and an aryl group, Y represents a halogen or an alkoxy group, m represents 0 or an integer of 1 to 3, and when m is 0, at least one of Y 4 represents an alkoxy group.
Claim 19
Dependent Claim
18 words
A liquid developer for electrostatic images as in claim 15, wherein said inorganic salt is TiCl 4 .
Claim 20
Dependent Claim
33 words
A liquid developer for electrostatic images as in claim 1, wherein the developer comprises a liquid carrier and from 0.01 g to 100 g of toner particles per liter of the liquid carrier.
Claim 21
Dependent Claim
38 words
A liquid developer for electrostatic images as in claim 1, wherein the charge controlling agent is contained in an amount of from 0.001 g to 10 g per liter of the developer in a final state of using.
Claim 22
Dependent Claim
19 words
A liquid developer for electrostatic images as in claim 1, wherein said liquid developer is a negatively charged developer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-09-29 | 1990-03-31 | 1990-09-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-09-29 | 1994-03-31 | 1994-09-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-09-29 | 1998-03-31 | 1998-09-30 | $7700.00 | Window Closed / Lapsed |