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US4612361A
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Poly(etherimides) and compositions containing the same
Assignee: General Electric Co
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Filing: 1985-09-23
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Granted: 1986-09-16
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Expires: 2005-09-23
Abstract
Abstract Novel fluoro-containing polyetherimides are prepared from bis ether dianhydrides, fluoro-containing dianhydrides, and organic diamines. The compolymers exhibit both increased Tg and increased solubility in halogenated solvents which enhances their value in a wide variety of uses including films, molding compounds, and coatings.
Inventors
- 👤 Edward N. Peters
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 03:15
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1046; C08G73/1053; C08G73/1057; C08G73/1064; C08G73/1067; C08G73/1071
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
215 words
A polyetherimide of the formula [A].sub.m [B].sub.1-m where m is a number greater than 0 and smaller than 1, where A units are of the formula: ##STR30## where --O--Z--O-- is in the 3 or 3'- and 4 or 4'- positions and Z is a member of the class consisting of (1) ##STR31## and (2) divalent organic radicals of the general formula: ##STR32## where X is a member selected from the class consisting of divalent radicals of the formulas, C y H 2y , ##STR33## --O-- and --S--, where q is 0 or 1, y is a whole number from 1 to 5, R is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (c) divalent radicals included by the formula ##STR34## where Q is a member selected from the class consisting of --O--, ##STR35## --S--, and --C x H 2x --, and x is a whole number from 1 to 5 inclusive, and where the B units are of the formula: ##STR36## where R is a divalent organic radical as previously defined, and independently a and b represent a whole number in excess of 1.
Claim 2
Dependent Claim
215 words
A polyetherimide of the formula [A].sub.m [B].sub.1-m where m is a number greater than 0 and smaller than 1, where A units are of the formula: ##STR30## where --O--Z--O-- is in the 3 or 3'- and 4 or 4'- positions and Z is a member of the class consisting of (1) ##STR31## and (2) divalent organic radicals of the general formula: ##STR32## where X is a member selected from the class consisting of divalent radicals of the formulas, C y H 2y , ##STR33## --O-- and --S--, where q is 0 or 1, y is a whole number from 1 to 5, R is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (c) divalent radicals included by the formula ##STR34## where Q is a member selected from the class consisting of --O--, ##STR35## --S--, and --C x H 2x --, and x is a whole number from 1 to 5 inclusive, and where the B units are of the formula: ##STR36## where R is a divalent organic radical as previously defined, and independently a and b represent a whole number in excess of 1.
Claim 3
Dependent Claim
24 words
A polyetherimide as defined in claim 1 wherein A is of the formula ##STR37## and R is a divalent organic radical as defined therein.
Claim 4
Dependent Claim
11 words
A polyetherimide as defined in claim 2 wherein R comprises ##STR38##
Claim 5
Dependent Claim
16 words
A polyetherimide as defined in claim 1 wherein m is from about 0.25 to about 0.75.
Claim 6
Dependent Claim
31 words
A polyetherimide as defined in claim 1 wherein m is about 0.67, Z is ##STR39## wherein q is 1 and X is --C 3 H 6 --; and R is ##STR40##
Claim 7
Dependent Claim
31 words
A polyetherimide as defined in claim 1 wherein m is about 0.33, Z is ##STR41## wherein q is 1 and X is --C 3 H 6 --; and R is ##STR42##
Claim 8
Dependent Claim
31 words
A polyetherimide as defined in claim 1 wherein m is about 0.67, Z is ##STR43## wherein q is 1 and X is --C 3 H 6 --; and R is ##STR44##
Claim 9
Dependent Claim
32 words
A polyetherimide as defined in claim 1 wherein m is about 0.50, and Z is ##STR45## wherein q is 1 and X is --C 3 H 6 --; and R is ##STR46##
Claim 10
Dependent Claim
32 words
A polyetherimide as defined in claim 1 wherein m is about 0.50; and Z is ##STR47## wherein q is 1 and X is --C 3 H 6 --; and R is ##STR48##
Claim 11
Dependent Claim
27 words
A composition adapted for use as a coating composition comprising a solution of (i) a polyetherimide as defined in claim 1, and (ii) a halogenated hydrocarbon solvent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-09-15 | 1990-03-17 | 1990-09-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-09-15 | 1994-03-17 | 1994-09-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-09-15 | 1998-03-17 | 1998-09-16 | $7700.00 | Window Closed / Lapsed |