Wettable, gas permeable contact lens

Claim 2

A composition, having permeability to oxygen and carbon dioxide exchange, potential wettability, mechanical and dimensional stability when fabricated, which comprises a polymer comprising a major portion of styrene or a substituted styrene compound, an effective amount of an ethylenically unsaturated silicone-containing compound sufficient to provide oxygen and carbon dioxide exchange, an effective amount of an ethylenically polyunsaturated crosslinking compound, and an effective amount of an α, β-ethylenically unsaturated dicarboxylic acid anhydride compound sufficient to provide wettability when hydrolyzed.

Claim 3

The composition of claim 1 wherein the substituted styrene compound comprises a compound of the formula: ##STR6## wherein n is an integer of 1-5 and R is a branched chain alkyl group or alkoxy group having 1 to 8 carbon atoms or mixtures of such compounds.

Claim 4

The composition of claim 2 wherein the substituted styrene compound comprises 1-vinyl-4-t-butyl benzene, 1-vinyl-3-t-butyl-benzene, 1-vinyl-3-i-propyl-benzene, 1-vinyl-4-i-propyl benzene or mixtures thereof.

Claim 5

The composition of claim 2 wherein the substituted styrene compound comprises a 1-vinyl-3-alkoxy-benzene, a 1-vinyl-4-alkoxy-benzene or mixtures thereof.

Claim 6

The composition of claim 1 wherein the ethylenically unsaturated silicone containing compound comprises a vinyl trialkyl silane, a vinyl tris(β-alkoxy alkoxy) silane, a γ-methacryloxypropyltrimethoxy silane or mixtures thereof.

Claim 7

The composition of claim 1 wherein the ethylenically unsaturated silicone-containing compound comprises pentamethyl disiloxanyl methacrylate.

Claim 8

The composition of claim 5 wherein the ethylenically unsaturated silicone-containing compound is combined with about 0.01 to 2 parts by weight of an alkyl acrylate or an alkyl methacrylate per part of the ethylenically unsaturated silicone containing monomer.

Claim 9

The composition of claim 1 wherein the ethylenically polyunsaturated crosslinking compound comprises a compound having at least two vinyl groups bonded to a polyvalent group.

Claim 10

The composition of claim 1 wherein the ethylenically polyunsaturated crosslinking agent comprises divinyl benzene, trivinyl benzene, 1,6-hexadiene, divinyl maleate, or mixtures thereof.

Claim 11

The composition of claim 8 wherein the ethylenically unsaturated crosslinking compound comprises an ester of a polyhydroxy compound and an unsaturated carboxylic acid compound.

Claim 12

The composition of claim 10 wherein the polyhydroxy compound is ethylene glycol, propylene glycol, trimethylol propane, mannitol or mixtures thereof and the unsaturated carboxylic acid is acrylic acid or methacrylic acid.

Claim 13

The composition of claim 8 wherein the ethylenically unsaturated crosslinking agent comprises tri-methylol propane trimethacrylate.

Claim 14

The composition of claim 1 wherein the α,β-ethylenically unsaturated carboxylic anhydride compound comprises maleic anhydride.

Claim 15

The composition of claim 1 wherein the polymer in the product of the reaction of the styrene or substituted styrene compound, the ethylenically unsaturated silicone-containing compound, the polyunsaturated crosslinking compound and α,β-ethylenically unsaturated dicarboxylic acid anhydride compound in the presence of a catalyst compound that yields free radical polymerization initiators in the presence of ultraviolet light.

Claim 16

A lens blank which comprises the composition of claim 1, 3 or 12.

Claim 17

The composition of claim 1 wherein there are about 50 to 80 parts by weight of styrene or substituted styrene compound, about 5 to 20 parts of the ethylenically unsaturated crosslinking compound, about 4 to 10 parts of the ethylenically unsaturated silicone-containing compound, and about 4 to 15 parts of the α,β-ethylenically unsaturated dicarboxylic acid anhydride compound.

Claim 18

A contact lens manufactured from a lens blank composition having permeability to oxygen exchange, surface wettability when hydrolyzed, mechanical and dimensional stability when fabricated, which comprises a polymer comprising a major proportion of styrene or a substitute styrene compound, and an effective amount of an ethylenically unsaturated silicone-containing compound sufficient to provide oxygen and carbon dioxide exchange, an effective amount of an ethylenically polyunsaturated crosslinking compound, and an effective amount of an α,β-ethylenically unsaturated dicarboxylic acid anhydride compound sufficient to provide wettability when hydrolyzed.

Claim 19

A contact lens manufactured from a lens blank composition having permeability to oxygen exchange, surface wettability when hydrolyzed, mechanical and dimensional stability when fabricated, which comprises a polymer comprising a major proportion of styrene or a substitute styrene compound, and an effective amount of an ethylenically unsaturated silicone-containing compound sufficient to provide oxygen and carbon dioxide exchange, an effective amount of an ethylenically polyunsaturated crosslinking compound, and an effective amount of an α,β-ethylenically unsaturated dicarboxylic acid anhydride compound sufficient to provide wettability when hydrolyzed.

Claim 20

The contact lens of claim 17 wherein the substituted styrene compound comprises a compound of the formula: ##STR7## wherein n is an integer of 1-5 and R is a branched chain alkyl group or alkoxy group having 1 to 8 carbon atoms or mixtures of such compounds.

Claim 21

The contact lens of claim 18 wherein the substituted styrene compound comprises 1-vinyl-4-t-butyl benzene, 1-vinyl-3-t-butyl-benzene, 1-vinyl-3-i-propyl-benzene, 1-vinyl-4-i-propyl benzene or mixtures thereof.

Claim 22

The composition of claim 18 wherein the substituted styrene compound comprises a 1-vinyl-3-alkoxy-benzene, a 1-vinyl-4-alkoxy-benzene or mixtures thereof.

Claim 23

The contact lens of claim 17 wherein the ethylenically unsaturated silicone containing compound comprises a vinyl trialkyl silane, a vinyl tris(β-alkoxy alkoxy) silane, or mixtures thereof.

Claim 24

The contact lens of claim 21 wherein the ethylenically unsaturated silicone-containing compound comprises pentamethyl disiloxanyl methacrylate.

Claim 25

The contact lens of claim 21 wherein the ethylenically unsaturated silicone containing compound is used in combination with about 0.01 to 2 parts by weight of an an alkyl acrylate or an alkyl methacrylate per part of the ethylenically unsaturated silicone containing monomer.

Claim 26

The contact lens of claim 17 wherein the ethylenically polyunsaturated crosslinking compound comprises a compound having at least two vinyl groups bonded to a polyvalent group.

Claim 27

The contact lens of claim 24 wherein the ethylenically polyunsaturated crosslinking agent comprises divinyl benzene, trivinyl benzene, 1,6-hexadiene, divinyl maleate, or mixtures thereof.

Claim 28

The contact lens of claim 24 wherein the ethylenically unsaturated crosslinking compound comprises an ester of a polyhydroxy compound and an unsaturated carboxylic acid compound.

Claim 29

The contact lens of claim 26 wherein the polyhydroxy compound is ethylene glycol, propylene glycol, trimethylol propane, mannitol or mixtures thereof and the unsaturated carboxylic acid is acrylic acid or methacrylic acid.

Claim 30

The contact lens of claim 24 wherein the ethylenically unsaturated crosslinking agent comprises tri-methylol propane trimethacrylate.

Claim 31

The contact lens of claim 17 wherein the α,β-ethylenically unsaturated dicarboxylic anhydride compound comprises maleic anhydride.

Claim 32

The contact lens of claim 17 wherein the polymer is the product of the reaction of the styrene or substituted styrene compound, the ethylenically unsaturated silicone-containing compound, the polyunsaturated crosslinking compound and α,β-ethylenically unsaturated dicarboxylic acid anhydride compound in the presence of a catalyst compound that yields free radical polymerization initiators in the presence of ultraviolet light, or heat.

Claim 33

The contact lens of claim 30 wherein after manufacturing the lens blank the contact lens is contacted with a basic aqueous solution to hydrolyze the anhydride groups.

Claim 34

The contact lens of claim 17 wherein there is about 50 to 80 parts by weight of styrene or the substituted styrene compound, about 5 to 20 parts of the ethylenically polyunsaturated crosslinking compound, about 4 to 10 parts of the ethylenically unsaturated silicone-containing compound, and about 4 to 15 parts of the α,β-ethylenically unsaturated dicarboxylic acid anhydride compound.

Claim 35

A composite contact lens which comprises a hard center portion comprising the composition of claim 1 and a soft outer skirt comprising a hydrated hydrophilic copolymer.