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US4610967A Expired / Lapsed US ⏱️ 0.0 years remaining

Zirconia porcelain and method of manufacturing the same

Assignee: NGK Insulators Ltd
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Filing: 1984-09-06
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Granted: 1986-09-09
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Expires: 2004-09-06
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Abstract

Abstract Disclosed herein is a zirconia porcelain which includes 1.5-5 mol % of yttrium oxide, 1-5.5 mol % of cerium oxide and the balance being substantially zirconium oxide. Disclosed herein also is a method of producing a zirconia porcelain, which includes the steps of preparing a mixed powder including 1.5-5 mol % of yttrium oxide, 1-5.5 mol % of cerium oxide and the balance being substantially zirconium oxide having an average particle size of less than 1.5 mu m when measured according to an air permeation method, shaping the mixed powder into a molding, and firing the molding thus at a temperature of 1,100 DEG C.-1,700 DEG C.

Inventors

  • 👤 Yuichiro Imanishi
  • 👤 Minoru Matsui

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:58
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/10; H01M8/12; H01M8/124; H01M8/1246; H01M8/1253; C; C04; C04B; C04B35/00; C04B35/01; C04B35/48; C04B35/486; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 27 words
A zirconia porcelain ceramic body consisting essentially of 97.5-89.5 mol % of zirconia oxide, 1.5-5 mol % of yttrium oxide and 1-5.5 mol % of cerium oxide.
Claim 2
Dependent Claim 27 words
A zirconia porcelain ceramic body consisting essentially of 97.5-89.5 mol % of zirconia oxide, 1.5-5 mol % of yttrium oxide and 1-5.5 mol % of cerium oxide.
Claim 3
Dependent Claim 23 words
A zirconia porcelain according to claim 1, wherein said yttrium oxide is 2-3 mol % and said cerium oxide is 2-4 mol %.
Claim 4
Dependent Claim 22 words
A zirconia porcelain according to claim 1, wherein the zirconium oxide has an average particle size of not greater than 10 μm.
Claim 5
Dependent Claim 22 words
A zirconia porcelain according to claim 3, wherein the average particle size of the zirconium oxide is not greater than 2 μm.
Claim 6
Dependent Claim 33 words
A zirconia porcelain according to claim 1, wherein a total volume fraction of tetragonal zirconium oxide and cubic zirconium oxide is not less than 3 times the volume fraction of monoclinic zirconium oxide.
Claim 7
Dependent Claim 33 words
A zirconia porcelain according to claim 3, wherein a total volume fraction of tetragonal zirconium oxide and cubic zirconium oxide is not less than 3 times the volume fraction of monoclinic zirconium oxide.
Claim 8
Dependent Claim 33 words
A zirconia porcelain according to claim 4, wherein a total volume fraction of tetragonal zirconium oxide and cubic zirconium oxide is not less than 3 times the volume fraction of monoclinic zirconium oxide.
Claim 9
Dependent Claim 30 words
A zirconia porcelain according to claim 1, wherein a volume fraction of cubic zirconium oxide is less than the total volume fraction of tetragonal zirconium oxide and monoclinic zirconium oxide.
Claim 10
Dependent Claim 30 words
A zirconia porcelain according to claim 3, wherein a volume fraction of cubic zirconium oxide is less than the total volume fraction of tetragonal zirconium oxide and monoclinic zirconium oxide.
Claim 11
Dependent Claim 30 words
A zirconia porcelain according to claim 4, wherein a volume fraction of cubic zirconium oxide is less than the total volume fraction of tetragonal zirconium oxide and monoclinic zirconium oxide.
Claim 12
Dependent Claim 30 words
A zirconia porcelain according to claim 5, wherein a volume fraction of cubic zirconium oxide is less than the total volume fraction of tetragonal zirconium oxide and monoclinic zirconium oxide.
Claim 13
Dependent Claim 30 words
A zirconia porcelain according to claim 6, wherein a volume fraction of cubic zirconium oxide is less than the total volume fraction of tetragonal zirconium oxide and monoclinic zirconium oxide.
Claim 14
Dependent Claim 30 words
A zirconia porcelain according to claim 7, wherein a volume fraction of cubic zirconium oxide is less than the total volume fraction of tetragonal zirconium oxide and monoclinic zirconium oxide.
Claim 15
Independent Claim 74 words
A method of producing a zirconia porcelain ceramic body, comprising the steps of preparing a mixed powder consisting essentially of 1.5-5 mol % of yttrium oxide, 1-5.5mol % of cerium oxide and 97.5-89.5 mol % zirconium oxide, said zirconium oxide having an average particle size of less than 1.5 μm when measured according to an air permeation method, shaping the mixed powder into a desired molding, and firing the molding at 1,100° C.-1,700° C.
Claim 16
Independent Claim 74 words
A method of producing a zirconia porcelain ceramic body, comprising the steps of preparing a mixed powder consisting essentially of 1.5-5 mol % of yttrium oxide, 1-5.5mol % of cerium oxide and 97.5-89.5 mol % zirconium oxide, said zirconium oxide having an average particle size of less than 1.5 μm when measured according to an air permeation method, shaping the mixed powder into a desired molding, and firing the molding at 1,100° C.-1,700° C.
Claim 17
Dependent Claim 22 words
A method according to claim 14, wherein the yttrium oxide is 2-3 mol %, and the cerium oxide is 2-4 mol %.
Claim 18
Dependent Claim 18 words
A method according to claim 14, wherein the molding is fied at a temperature of 1,200° C.-1,500° C.
Claim 19
Dependent Claim 31 words
A method according to claim 14, wherein a powder obtained by finely crushing oxides of zirconium, yttrium, and cerium or pyrolyzed products of these compounds are used as the mixed powder.
Claim 20
Dependent Claim 31 words
A method according to claim 16, wherein a powder obtained by finely crushing oxides of zirconium, yttrium, and cerium or pyrolyzed products of these compounds are used as the mixed powder.

References Cited (Backward Citations)

US3287143A Cited
US3957500A Cited
US4370393A Cited
US4328296A Cited
US4360598A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-08 1990-03-10 1990-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-08 1994-03-10 1994-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-08 1998-03-10 1998-09-09 $7700.00 Window Closed / Lapsed

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