2-(thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides

Claim 2

2-Ethyl-2-thiono-1,3,2-oxazaphospholane of the formula ##STR67##

Claim 3

In a synergistic insecticidal and acaricidal composition comprising (1) an insecticidally and acaricidally active compound and (2) a synergizing agent in amount sufficient to synergize the insecticidal and acaricidal activity of the insecticidally and acaricidally active compound, the improvement which comprises employing as the synergizing agent the compound according to claim 1.

Claim 4

A method of combating pests comprising applying to the pests or a habitat thereof a pesticidally effective amount of a composition according to claim 2.

Claim 5

A composition according to claim 2, wherein (1) is selected from (A) carbamic acid esters, (B) carboxylic acid esters, including the naturally occurring and the synthetic pyrethroids, (C) phosphoric acid esters and phosphonic acid esters and (D) halogeno(cyclo)alkanes.

Claim 6

A composition according to claim 2, wherein (1) is selected from (A) carbamic acid esters of the formula ##STR68## in which R 5 represents hydrogen or C 1 -C 4 -alkyl, R 6 represents C 1 -C 4 -alkyl, C 1 -C 4 -alkylcarbonyl which is optionally substituted by halogen, by hydroxyl or by methylthio, or the radical S-Z, Z represents optionally halogen-substituted C 1 -C 4 -alkyl, phenyl which optionally carries one or more substituents selected from halogen, cyano, C 1 -C 4 -alkyl, trihalogenomethylthio, trihalogenomethyl and nitro, or C 1 -C 4 -alkoxy-carbonyl and R 7 represents an optionally substituted aryl, heterocyclic or oxime radical, (B) carboxylic acid esters of the formula ##STR69## in which R 12 represents an open-chain or cyclic alkyl radical which is optionally substituted by halogen, by alkyl, by cycloalkyl, by alkenyl which is optionally substituted by halogen and/or alkoxy, by phenyl or styryl, in either case optionally substituted by halogen or one or more substituents selected from optionally halogen-substituted alkyl, alkoxy, alkylenedioxy and alkylthio radicals, or by cycloalk(en)yl which is linked in a spirocyclic-like manner and is optionalldy halogen-substituted and optionally benzo-fused, R 10 represents hydrogen, alkyl, halogenoalkyl, alkenyl, alkynyl or cyano and R 11 represents an optionally substituted aryl radical or a heterocyclic radical, or R 10 and R 11 , together with the carbon atom to which the two radicals are bonded, form a cyclopentenone ring, and naturally occurring pyrethroids, (C) phosphoric acid esters and phosphonic acid esters of the formula ##STR70## in which X' represents oxygen or sulphur, Y' represents oxygen, sulphur, imino or a direct bond between the P atom and R 19 , R 17 and R 18 are identical or different and each represents an optionally substituted alkyl or aryl radical and R 19 represents an optionally substituted alkyl, aryl, heteroaryl, aralkyl or alkenyl radical, an optionally substituted oxime radical, or a radical identical to that to which it is bonded, and (D) hexachlorocyclohexane, 1,1,1-trichloro-2,2-bis-(4-chlorophenyl)-ethane, 1,1,1-trichloro-2,2,-bis-(4-methoxyphenyl)-ethane and 1,1-dichloro-2,2-bis-(4-ethylphenyl)-ethane.