Silicone release coatings containing higher alkenyl functional siloxanes

Claim 2

A curable coating composition comprising: (A) a triorganosiloxane-endblocked polydiorganosiloxane polymer having a viscosity at 25° C. of at least 25 centistokes, wherein 90 to 99.5 percent of all organic radicals are methyl, from 0.5 to 10 percent of all organic radicals are unsaturated radicals independently selected from the group consisting of the vinyl radical and higher alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5, with the proviso that at least 50 mole percent of the unsaturated radicals are higher alkenyl radicals; (B) a catalytic amount of a metal, hydrosilylation catalyst; (C) a methylhydrogenpolysiloxane cross-linking agent, compatible with (A) and having an average of at least three silicon-bonded hydrogen atoms per molecule with the hydrogen radicals being bonded to separate silicon atoms; (D) an effective amount of an inhibitor for the metal, hydrosilylation catalyst; and wherein the composition contains 0.8 to 1.5 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.

Claim 3

A curable coating composition in accordance with claim 1 wherein (A) has a viscosity at 25° C. of 100 to 1000 centistokes and is a dimethylvinylsiloxane-endblocked polydiorganosiloxane polymer consisting essentially of dimethylsiloxane units and alkenylmethylsiloxane units wherein the alkenyl radicals are represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.

Claim 4

A curable coating composition in accordance with claim 1 wherein the unsaturated radicals in (A) are alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.

Claim 5

A curable coating composition in accordance with claim 3 wherein the siloxane units of (A) are selected independently from the group consisting of dimethylsiloxane units, trimethylsiloxane units, alkenylmethylsiloxane units, and alkenyldimethylsiloxane units and the composition contains 0.9 to 1.2 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.

Claim 6

A curable coating composition in accordance with claim 4 wherein (A) has a viscosity at 25° C. of 100 to 1000 centistokes and the alkenyl radicals are selected from the group consisting of 5-hexenyl, 7-octenyl, 9-decenyl, and 5,9-decadienyl radicals.

Claim 7

A curable coating composition in accordance with claim 5 wherein (A) has a viscosity at 25° C. of 200 to 600 centistokes and the alkenyl radical is the 5-hexenyl radical.

Claim 8

A curable coating composition in accordance with claim 6 wherein (A) is a 5-hexenyldimethylsiloxane-endblocked copolymer of dimethylsiloxane and 5-hexenylmethylsiloxane units.

Claim 9

A curable coating composition in accordance with claim 7 wherein 1.0 to 4.0 mole percent of the diorganosiloxane units are 5-hexenylmethylsiloxane units.

Claim 10

A curable coating composition in accordance with claim 8 wherein (B) is a platinum-containing catalyst.

Claim 11

A curable coating composition in accordance with claim 9 wherein (B) is a complex of platinum and cyclopolyvinylmethylsiloxane.

Claim 12

A process for preparing a laminate of a substrate and an adhesive wherein the adhesive will release from the substrate, the process comprising the steps of: (I) coating a curable silicone release composition on the surface of the substrate wherein the composition comprises (A) a triorganosiloxane-endblocked polydiorganosiloxane polymer having a viscosity at 25° C. of at least 25 centistokes, wherein 90 to 99.5 percent of all organic radicals are methyl, from 0.5 to 10 percent of all organic radicals are unsaturated radicals independently selected from the group consisting of the vinyl radical and higher alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5, with the proviso that at least 50 mole percent of the unsaturated radicals are higher alkenyl radicals; (B) a catalytic amount of a metal, hydrosilylation catalyst; (C) a methylhydrogenpolysiloxane cross-linking agent, compatible with (A) and having an average of at least three silicon-bonded hydrogen atoms per molecule with the hydrogen radicals being bonded to separate silicon atoms; (D) an effective amount of an inhibitor for the metal, hydrosilylation catalyst; and wherein the composition contains 0.8 to 1.5 silicon-bonded hydrogen radicals for every unsaturated radical in the composition; (II) curing the silicone release composition with an effective amount of heat; (III) applying, on line, an adhesive to the silicone surface of the substrate.

Claim 13

A process for preparing a laminate of a substrate and an adhesive wherein the adhesive will release from the substrate, the process comprising the steps of: (I) coating a curable silicone release composition on the surface of the substrate wherein the composition comprises (A) a triorganosiloxane-endblocked polydiorganosiloxane polymer having a viscosity at 25° C. of at least 25 centistokes, wherein 90 to 99.5 percent of all organic radicals are methyl, from 0.5 to 10 percent of all organic radicals are unsaturated radicals independently selected from the group consisting of the vinyl radical and higher alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5, with the proviso that at least 50 mole percent of the unsaturated radicals are higher alkenyl radicals; (B) a catalytic amount of a metal, hydrosilylation catalyst; (C) a methylhydrogenpolysiloxane cross-linking agent, compatible with (A) and having an average of at least three silicon-bonded hydrogen atoms per molecule with the hydrogen radicals being bonded to separate silicon atoms; (D) an effective amount of an inhibitor for the metal, hydrosilylation catalyst; and wherein the composition contains 0.8 to 1.5 silicon-bonded hydrogen radicals for every unsaturated radical in the composition; (II) curing the silicone release composition with an effective amount of heat; (III) applying, on line, an adhesive to the silicone surface of the substrate.

Claim 14

A process in accordance with claim 11 wherein (A) has a viscosity at 25° C. of 100 to 1000 centistokes and is a dimethylvinylsiloxane-endblocked polydiorganosiloxane polymer consisting essentially of dimethylsiloxane units and alkenylmethylsiloxane units wherein the alkenyl radicals are represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.

Claim 15

A process in accordance with claim 11 wherein the unsaturated radicals in (A) are alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.

Claim 16

A process in accordance with claim 13 wherein the siloxane units of (A) are selected independently from the group consisting of dimethylsiloxane units, trimethylsiloxane units, alkenylmethylsiloxane units, and alkenyldimethylsiloxane units and the composition contains 0.9 to 1.2 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.

Claim 17

A process in accordance with claim 14 wherein (A) has a viscosity at 25° C. of 100 to 1000 centistokes and the alkenyl radicals are selected from the group consisting of 5-hexenyl, 7-octenyl, 9-decenyl, and 5,9-decadienyl radicals.

Claim 18

A process in accordance with claim 15 wherein (A) has a viscosity at 25° C. of 200 to 600 centistokes and the alkenyl radical is the 5-hexenyl radical.

Claim 19

A process in accordance with claim 16 wherein (A) is a 5-hexenyldimethylsiloxane-endblocked copolymer of dimethylsiloxane and 5-hexenylmethylsiloxane units.

Claim 20

A process in accordance with claim 17 wherein 1.0 to 4.0 mole percent of the diorganosiloxane units are 5-hexenylmethylsiloxane units.

Claim 21

A process in accordance with claim 18 wherein (B) is a platinum-containing catalyst.

Claim 22

A process in accordance with claim 19 wherein (B) is a complex of platinum and cyclopolyvinylmethylsiloxane.

Claim 23

In a process for preparing a laminate of a substrate and adhesive wherein the adhesive will release from the substrate, the process comprising coating a curable silicone release composition on a surface of the substrate, thereafter curing the silicone composition, and applying an adhesive to the silicone surface of the substrate, the improvement comprising coating as the curable silicone release composition, a composition comprising (A) a triorganosiloxane-endblocked polydiorganosiloxane polymer having a viscosity at 25° C. of at least 25 centistokes, wherein 90 to 99.5 percent of all organic radicals are methyl, from 0.5 to 10 percent of all organic radicals are unsaturated radicals independently selected from the group consisting of the vinyl radical and higher alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5, with the proviso that at least 50 mole percent of the unsaturated radicals are higher alkenyl radicals; (B) a catalytic amount of a metal, hydrosilylation catalyst; (C) a methylhydrogenpolysiloxane cross-linking agent, compatible with (A) and having an average of at least three silicon-bonded hydrogen atoms per molecule with the hydrogen radicals being bonded to separate silicon atoms; (D) an effective amount of an inhibitor for the metal, hydrosilylation catalyst; and wherein the composition contains 0.8 to 1.5 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.

Claim 24

In a process for preparing a laminate of a substrate and adhesive wherein the adhesive will release from the substrate, the process comprising coating a curable silicone release composition on a surface of the substrate, thereafter curing the silicone composition, and applying an adhesive to the silicone surface of the substrate, the improvement comprising coating as the curable silicone release composition, a composition comprising (A) a triorganosiloxane-endblocked polydiorganosiloxane polymer having a viscosity at 25° C. of at least 25 centistokes, wherein 90 to 99.5 percent of all organic radicals are methyl, from 0.5 to 10 percent of all organic radicals are unsaturated radicals independently selected from the group consisting of the vinyl radical and higher alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5, with the proviso that at least 50 mole percent of the unsaturated radicals are higher alkenyl radicals; (B) a catalytic amount of a metal, hydrosilylation catalyst; (C) a methylhydrogenpolysiloxane cross-linking agent, compatible with (A) and having an average of at least three silicon-bonded hydrogen atoms per molecule with the hydrogen radicals being bonded to separate silicon atoms; (D) an effective amount of an inhibitor for the metal, hydrosilylation catalyst; and wherein the composition contains 0.8 to 1.5 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.

Claim 25

A process in accordance with claim 21 wherein (A) has a viscosity at 25° C. of 100 to 1000 centistokes and is a dimethylvinylsiloxane-endblocked polydiorganosiloxane polymer consisting essentially of dimethylsiloxane units and alkenylmethylsiloxane units wherein the alkenyl radicals are represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.

Claim 26

A process in accordance with claim 21 wherein the unsaturated radicals in (A) are alkenyl radicals represented by the formula --R(CH 2 ) m CH═CH 2 wherein R denotes --(CH 2 ) n -- or --(CH 2 ) p CH═CH-- and m has the value of 1, 2, or 3; n has the value of 3 or 6; and p has the value of 3, 4, or 5.

Claim 27

A process in accordance with claim 23 wherein the siloxane units of (A) are selected independently from the group consisting of dimethylsiloxane units, trimethylsiloxane units, alkenylmethylsiloxane units, and alkenyldimethylsiloxane units and the composition contains 0.9 to 1.2 silicon-bonded hydrogen radicals for every unsaturated radical in the composition.

Claim 28

A process in accordance with claim 24 wherein (A) has a viscosity at 25° C. of 100 to 1000 centistokes and the alkenyl radicals are selected from the group consisting of 5-hexenyl, 7-octenyl, 9-decenyl, and 5,9-decadienyl radicals.

Claim 29

A process in accordance with claim 25 wherein (A) has a viscosity at 25° C. of 200 to 600 centistokes and the alkenyl radical is the 5-hexenyl radical.

Claim 30

A process in accordance with claim 26 wherein (A) is a 5-hexenyldimethylsiloxane-endblocked copolymer of dimethylsiloxane and 5-hexenylmethylsiloxane units.

Claim 31

A process in accordance with claim 27 wherein 1.0 to 4.0 mole percent of the diorganosiloxane units are 5-hexenylmethylsiloxane units.

Claim 32

A process in accordance with claim 28 wherein (B) is a platinum-containing catalyst.

Claim 33

A process in accordance with claim 29 wherein (B) is a complex of platinum and cyclopolyvinylmethylsiloxane.