Patent US4609443A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4609443A Expired / Lapsed US ⏱️ 0.0 years remaining

Procedure for the cathodic electrowinning of metals, with the corresponding acid generation, from its salt solution

Assignee: Individual
•
Filing: 1985-07-01
•
Granted: 1986-09-02
•
Expires: 2005-07-01
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The present invention relates to cathodic electrowinning of metals involving simultaneous metal winning and acid regeneration in the same electromechanical cell.

Inventors

  • 👤 Eduardo D. Nogueira

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 19:54
CPC Classifications
C; C25; C25C; C25C1/00; C25C1/18

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 141 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, comprising the use of an electrochemical cell having anodic and cathodic compartments physically separated by a cation permo-selective membrane, in such a way that different electrolytes are used in each electrodic space, the cathode receiving a solution of the corresponding metallic salt, the metal being discharged at the cathode, and the electrical equilibrium being maintained by protons coming from the anolyte, across the cation permo-selective membrane, there being a change in the catholyte composition from a neutral salt solution into an acidic solution, where the acid and the salt have the same anion; the anode functioning with a different electrolyte comprising a solution of inorganic oxygenated acid, where the applied current discharges oxygen at the anode, thus originating an excess of protons that pass toward the catholyte across the membrane.
Claim 2
Dependent Claim 141 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, comprising the use of an electrochemical cell having anodic and cathodic compartments physically separated by a cation permo-selective membrane, in such a way that different electrolytes are used in each electrodic space, the cathode receiving a solution of the corresponding metallic salt, the metal being discharged at the cathode, and the electrical equilibrium being maintained by protons coming from the anolyte, across the cation permo-selective membrane, there being a change in the catholyte composition from a neutral salt solution into an acidic solution, where the acid and the salt have the same anion; the anode functioning with a different electrolyte comprising a solution of inorganic oxygenated acid, where the applied current discharges oxygen at the anode, thus originating an excess of protons that pass toward the catholyte across the membrane.
Claim 3
Dependent Claim 37 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, according to claim 1, wherein the electrolysis of the metallic salt is performed with a metal concentration in the catholyte in the range of 5-50 g/L.
Claim 4
Dependent Claim 56 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, according to claim 1, wherein an aqueous solution of sulfuric acid is used as anolyte, with periodic addition of water to compensate the electrolysis of water and its diffusion from anolyte to catholyte, thus keeping constant the acid concentration in a range of 50-200 g/L.
Claim 5
Dependent Claim 38 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 1, wherein the cathodic current density ranges from 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
Claim 6
Dependent Claim 56 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, according to claim 2, wherein an aqueous solution of sulfuric acid is used, as anolyte, with periodic addition of water to compensate the electrolysis of water and its diffusion from anolyte to catholyte, thus keeping constant the acid concentration in a range of 50-200 g/L.
Claim 7
Dependent Claim 38 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 2, wherein the cathodic current density ranges from 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
Claim 8
Dependent Claim 36 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 3, wherein the cathodic current ranges 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
Claim 9
Dependent Claim 38 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 5, wherein the cathodic current density ranges from 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.

References Cited (Backward Citations)

US1952850A Cited
US3537961A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-09-01 1990-03-03 1990-09-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-09-01 1994-03-03 1994-09-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-09-01 1998-03-03 1998-09-02 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag