Patent US4609443A successfully refreshed from Google Patents.
US4609443A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Procedure for the cathodic electrowinning of metals, with the corresponding acid generation, from its salt solution
Assignee: Individual
•
Filing: 1985-07-01
•
Granted: 1986-09-02
•
Expires: 2005-07-01
Abstract
Abstract The present invention relates to cathodic electrowinning of metals involving simultaneous metal winning and acid regeneration in the same electromechanical cell.
Inventors
- 👤 Eduardo D. Nogueira
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 19:54
CPC Classifications
C; C25; C25C; C25C1/00; C25C1/18
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
141 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, comprising the use of an electrochemical cell having anodic and cathodic compartments physically separated by a cation permo-selective membrane, in such a way that different electrolytes are used in each electrodic space, the cathode receiving a solution of the corresponding metallic salt, the metal being discharged at the cathode, and the electrical equilibrium being maintained by protons coming from the anolyte, across the cation permo-selective membrane, there being a change in the catholyte composition from a neutral salt solution into an acidic solution, where the acid and the salt have the same anion; the anode functioning with a different electrolyte comprising a solution of inorganic oxygenated acid, where the applied current discharges oxygen at the anode, thus originating an excess of protons that pass toward the catholyte across the membrane.
Claim 2
Dependent Claim
141 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, comprising the use of an electrochemical cell having anodic and cathodic compartments physically separated by a cation permo-selective membrane, in such a way that different electrolytes are used in each electrodic space, the cathode receiving a solution of the corresponding metallic salt, the metal being discharged at the cathode, and the electrical equilibrium being maintained by protons coming from the anolyte, across the cation permo-selective membrane, there being a change in the catholyte composition from a neutral salt solution into an acidic solution, where the acid and the salt have the same anion; the anode functioning with a different electrolyte comprising a solution of inorganic oxygenated acid, where the applied current discharges oxygen at the anode, thus originating an excess of protons that pass toward the catholyte across the membrane.
Claim 3
Dependent Claim
37 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, according to claim 1, wherein the electrolysis of the metallic salt is performed with a metal concentration in the catholyte in the range of 5-50 g/L.
Claim 4
Dependent Claim
56 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, according to claim 1, wherein an aqueous solution of sulfuric acid is used as anolyte, with periodic addition of water to compensate the electrolysis of water and its diffusion from anolyte to catholyte, thus keeping constant the acid concentration in a range of 50-200 g/L.
Claim 5
Dependent Claim
38 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 1, wherein the cathodic current density ranges from 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
Claim 6
Dependent Claim
56 words
Process for the cathodic electrowinning of metals, with corresponding acid generation, according to claim 2, wherein an aqueous solution of sulfuric acid is used, as anolyte, with periodic addition of water to compensate the electrolysis of water and its diffusion from anolyte to catholyte, thus keeping constant the acid concentration in a range of 50-200 g/L.
Claim 7
Dependent Claim
38 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 2, wherein the cathodic current density ranges from 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
Claim 8
Dependent Claim
36 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 3, wherein the cathodic current ranges 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
Claim 9
Dependent Claim
38 words
Process for cathodic electrowinning of metals, with corresponding acid generation, according to claim 5, wherein the cathodic current density ranges from 0.1 to 10 kiloamps per square meter, depending upon the metal and its desired final deposit form.
References Cited (Backward Citations)
US1952850A
Cited
US3537961A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-09-01 | 1990-03-03 | 1990-09-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-09-01 | 1994-03-03 | 1994-09-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-09-01 | 1998-03-03 | 1998-09-02 | $7700.00 | Window Closed / Lapsed |