← Back to Patent Explorer
US4608429A Expired / Lapsed US ⏱️ 0.0 years remaining

Low-melting aromatic polyesters with repeating 2,2'-substituted-biphenylene radicals

Assignee: Polaroid Corp
•
Filing: 1984-11-23
•
Granted: 1986-08-26
•
Expires: 2004-11-23
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A class of aromatic polyesters exhibiting melt processability is disclosed. A portion of repeating 2,2'-substituted-biphenylene radicals in an aromatic polyester is replaced by certain other aromatic radicals to provide an aromatic polyester which exhibits low-melting properties, melt processability and melt anisotropy. The aromatic polyesters can be melt processed to films and fibers.

Inventors

  • 👤 Howard G. Rogers
  • 👤 Russell A. Gaudiana
  • 👤 Richard A. Minns
  • 👤 Roger F. Sinta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 22:36
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/19; C08G63/191; C08G63/66; C08G63/668; C08G63/672; C08G63/68; C08G63/682; C08G63/6824; C08G63/6826

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 129 words
A melt-processable polyester comprising repeating radicals of the formulas ##STR20## wherein X is a substituent other than hydrogen, and k represents the molar amount of the formula (I) radical in the polyester; ##STR21## wherein Y is hydrogen or a substituent other than hydrogen, and m represents the molar amount of the formula (II) radical in the polyester; ##STR22## wherein each of Y' and Y" represents hydrogen or a substituent other than hydrogen, and n represents the molar amount of the formula (III) radical in the polyester; and ##STR23## wherein Y"' is hydrogen or a substituent other than hydrogen, and p represents the mole ratio of the formula (IV) radical in the polyester; the molar proportions of formula (I), (II), (III) and (IV) radicals conforming to the following relationships: ##EQU2##
Claim 2
Dependent Claim 129 words
A melt-processable polyester comprising repeating radicals of the formulas ##STR20## wherein X is a substituent other than hydrogen, and k represents the molar amount of the formula (I) radical in the polyester; ##STR21## wherein Y is hydrogen or a substituent other than hydrogen, and m represents the molar amount of the formula (II) radical in the polyester; ##STR22## wherein each of Y' and Y" represents hydrogen or a substituent other than hydrogen, and n represents the molar amount of the formula (III) radical in the polyester; and ##STR23## wherein Y"' is hydrogen or a substituent other than hydrogen, and p represents the mole ratio of the formula (IV) radical in the polyester; the molar proportions of formula (I), (II), (III) and (IV) radicals conforming to the following relationships: ##EQU2##
Claim 3
Dependent Claim 21 words
The polyester of claim 1 wherein, in said formula (I) radical, each X group is independently halogen, nitro, alkoxy or substituted-alkyl.
Claim 4
Dependent Claim 14 words
The polyester of claim 2 wherein each of said X groups is a substituted-alkyl.
Claim 5
Dependent Claim 13 words
The polyester of claim 3 wherein each of said X groups is trifluoromethyl.
Claim 6
Dependent Claim 17 words
The polyester of claim 1 wherein, in said formula (II) radical, Y is hydrogen or a substituted-alkyl.
Claim 7
Dependent Claim 10 words
The polyester of claim 5 wherein said Y is hydrogen.
Claim 8
Dependent Claim 10 words
The polyester of claim 5 wherein said Y is trifluoromethyl.
Claim 9
Dependent Claim 18 words
The polyester of claim 1 wherein, in said formula (III) radical, each of Y' and Y" is hydrogen.
Claim 10
Dependent Claim 17 words
The polyester of claim 1 wherein, in said formula (IV) radical, Y"' is hydrogen, halogen or alkyl.
Claim 11
Dependent Claim 9 words
The polyester of claim 9 wherein Y"' is chloro.
Claim 12
Dependent Claim 10 words
The polyester of claim 9 wherein said Y"' is methyl.
Claim 13
Dependent Claim 53 words
The polyester of claim 1 wherein said n is zero, the ratio of k to the sum of k and m is in the molar range of from 0.3 to 0.6, and the ratio of m to the sum of k and m is in the molar range of from 0.3 to 0.6.
Claim 14
Dependent Claim 14 words
The polyester of claim 12 wherein each of said molar ratios is about 0.5.
Claim 15
Dependent Claim 16 words
The polyester of claim 12 wherein, in said formula (I) radical, each X group is trifluoromethyl.
Claim 16
Dependent Claim 14 words
The polyester of claim 14 wherein, in said formula (II) radical, Y is trifluoroalkyl.
Claim 17
Dependent Claim 14 words
The polyester of claim 15 wherein, in said formula (IV) radical, Y' is chloro.
Claim 18
Dependent Claim 14 words
The polyester of claim 15 wherein, in said formula (IV) radical, Y"' is hydrogen.
Claim 19
Dependent Claim 14 words
The polyester of claim 15 wherein, in said formula (IV) radical, Y"' is methyl.
Claim 20
Dependent Claim 14 words
The polyester of claim 14 wherein, in said formula (II) radical, Y is hydrogen.
Claim 21
Dependent Claim 13 words
The polyester of claim 19 wherein, in said formula (IV), Y"' is chloro.
Claim 22
Dependent Claim 15 words
The polyester of claim 1 in the form of a molecularly oriented film or fiber.
Claim 23
Dependent Claim 24 words
A melt-processable polyester comprising repeating units of the formula ##STR24## wherein each subscript represents the molar amount of the respective radical in said polyester.
Claim 24
Dependent Claim 24 words
A melt-processable polyester comprising repeating units of the formula ##STR24## wherein each subscript represents the molar amount of the respective radical in said polyester.

References Cited (Backward Citations)

US3008929A Cited
US3786022A Cited
US4066620A Cited
US4288588A Cited
US4083829A Cited
US4238600A Cited
US4433132A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-08-25 1990-02-24 1990-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-08-25 1994-02-24 1994-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-08-25 1998-02-24 1998-08-26 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag