US4605591A
Expired / Lapsed
US
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Thermoplastic resin film laminate and production thereof
Assignee: Toyobo Co Ltd
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Filing: 1984-10-24
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Granted: 1986-08-12
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Expires: 2004-10-24
Abstract
Abstract A thermoplastic resin film laminate which comprises a thermoplastic resin film, particularly, a polyester film and a layer of a polyester resin composition provided on at least one surface of the film, said composition comprising (A) a water insoluble polyester copolymer composed of a mixed dicarboxylic acid component containing a dicarboxylic acid having metal sulfonate group in an amount of 0.5 to 15 mol % based on all the dicarboxylic acid component and a glycol component; and (B) inert particles; the weight ratio of (A)/(B)=100,000/0.5-3,000. Optionally, the composition can contain one or more ingredients selected from the group consisting of a water soluble silicone, a polyfunctional reactive compound, a polyethylene glycol and its derivative and an antistatic agent. The thermoplastic resin film laminate is preferably produced by so-called in-line coating.
Inventors
- 👤 Katsuhiko Nose
- 👤 Hajime Suzuki
- 👤 Osamu Makimura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 15:52
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/795; G03C1/7954; C; C08; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08J7/044; C08J7/056; C08J2467/00; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/31504; Y10T428/31786; Y10T428/31797
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
97 words
A thermoplastic resin film laminate which comprises a thermolastic resin film and a layer of a polyester resin composition provided on at least one surface of the film, said composition consisting essentially of (A) a water-insoluble polyester copolymer of a mixed dicarboxylic acid component composed of 0.5 to 15 mole% of a dicarboxylic acid having a metal sulfonate group and 85 to 99.5 mole % of aromatic dicarboxylic acid having no metal sulfonate group reacted with a glycol component; (B) inert particles having an average particle size of 0.01 to 10 microns; the weight ratio of (A)/(B)=100,000/0.5-3,000.
Claim 2
Dependent Claim
97 words
A thermoplastic resin film laminate which comprises a thermolastic resin film and a layer of a polyester resin composition provided on at least one surface of the film, said composition consisting essentially of (A) a water-insoluble polyester copolymer of a mixed dicarboxylic acid component composed of 0.5 to 15 mole% of a dicarboxylic acid having a metal sulfonate group and 85 to 99.5 mole % of aromatic dicarboxylic acid having no metal sulfonate group reacted with a glycol component; (B) inert particles having an average particle size of 0.01 to 10 microns; the weight ratio of (A)/(B)=100,000/0.5-3,000.
Claim 3
Dependent Claim
153 words
A thermoplastic resin film laminate according to claim 1, wherein the composition further includes one or more ingredients selected from the group consisting of (E) a water soluble silicone, (F) a polyfunctional reactive compound, (G) polyethylene glycol and its derivatives and (H) an antistatic agent; said water soluble silicone (E) being represented by the following formula (I) or (II) or is a mixture thereof, the ratio of ethylene oxide and propylene oxide having the relation of the equation (III) and the molecular weight thereof being 500 to 20,000; ##STR13## wherein R is hydrogen or lower alkyl having 1 to 4 carbon atoms, R' is lower alkyl having 1 to 4 carbon atoms, R" is hydrogen or lower alkyl, R"' is lower alkylene having 1 to 4 carbon atoms, x and a are each 0 or an integer of 1 or more and y and b are each an integer of 1 or more.
Claim 4
Dependent Claim
27 words
A thermoplastic resin film laminate according to claim 2, wherein the composition contains water soluble silicone (E) and the weight ratio of (A)/(E) is 100/0.05 to 10.
Claim 5
Dependent Claim
28 words
A thermoplastic resin film laminate according to claim 2, wherein the composition contains (F) a polyfunctional reactive compound and the weight ratio of (A)/(F) is 100/1 to 40.
Claim 6
Dependent Claim
29 words
A thermoplastic resin film laminate according to claim 2, wherein the composition contains (G) polyethylene glycol or its derivative and the weight ratio of (A)/(G) is 100/1 to 20.
Claim 7
Dependent Claim
27 words
A thermoplastic resin film laminate according to claim 2, wherein the composition contains (H) an antistatic agent and the weight ratio of (A)/(G) is 100/0.1 to 15.
Claim 8
Dependent Claim
33 words
A thermoplastic resin film laminate according to claim 1, wherein the thermoplastic resin film is a melt extruded, unoriented or uniaxially oriented film and the resulting laminate is further uiaxially or biaxially oriented.
Claim 9
Dependent Claim
29 words
A thermoplastic resin film laminate according to claim 7 wherein the melt extruded, unoriented or uniaxially oriented film contains a lubricant in an amount of 300 ppm or less.
Claim 10
Dependent Claim
18 words
A thermoplastic resin film laminate according to claim 1, wherein the thermoplastic resin film is a polyester film.
Claim 11
Dependent Claim
18 words
A thermoplastic resin film laminate according to claim 9, wherein the polyester film is a polyethylene terephthalate film.
Claim 12
Dependent Claim
118 words
A thermoplastic resin film lamiante according to claim 1, additionally containing water soluble silicone which is represented by the following formula (I) or (II) or is a mixture thereof, the ratio of ethylene oxide and propylene oxide having the relation of the equation (III) and the molecular weight thereof being 500 to 20,000; ##STR14## wherein R is hydrogen or lower alkyl having 1 to 4 carbon atoms, R' is lower alkyl having 1 to 4 carbon atoms, R" is hydrogen or lower alkyl, R'" is lower alkylene having 1 to 4 carbon atoms, x and a are each 0 or an integer of 1 or more and y and b are each an integer of 1 or more.
Claim 13
Dependent Claim
133 words
A process for the production of a thermoplastic resin film laminate which comprises applying an aqueous dispersion of a polyester resin composition on at least one surface of a thermoplastic resin film to form a layer of polyester resin composition thereon, said aqueous dispersion consisting essentially of (A) a water-insoluble polyester copolymer of a mixed dicarboxylic acid component composed of 0.5 to 15 mole % of a dicarboxylic acid having a metal sulfonate group and 85 to 99.5 mole % of aromatic dicarboxylic acid having no metal sulfonate group reacted with a glycol component; (B) inert particles having an average particle size of 0.01 to 10 microns; (C) a water soluble organic compound having a boiling point of 60°-200° C.; and (D) water; the weight ratios of (A)/(B)=100,000/0.5-3,000, of (A)/(C)=100/20-5,000 and of (C)/(D)=100/50-1,000.
Claim 14
Dependent Claim
133 words
A process for the production of a thermoplastic resin film laminate which comprises applying an aqueous dispersion of a polyester resin composition on at least one surface of a thermoplastic resin film to form a layer of polyester resin composition thereon, said aqueous dispersion consisting essentially of (A) a water-insoluble polyester copolymer of a mixed dicarboxylic acid component composed of 0.5 to 15 mole % of a dicarboxylic acid having a metal sulfonate group and 85 to 99.5 mole % of aromatic dicarboxylic acid having no metal sulfonate group reacted with a glycol component; (B) inert particles having an average particle size of 0.01 to 10 microns; (C) a water soluble organic compound having a boiling point of 60°-200° C.; and (D) water; the weight ratios of (A)/(B)=100,000/0.5-3,000, of (A)/(C)=100/20-5,000 and of (C)/(D)=100/50-1,000.
References Cited (Backward Citations)
US4476189A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-08-11 | 1990-02-10 | 1990-08-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-08-11 | 1994-02-10 | 1994-08-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-08-11 | 1998-02-10 | 1998-08-12 | $7700.00 | Window Closed / Lapsed |