Scavengers for the removal of impurities from inert fluids

Claim 2

A process for the purification of fluids inert to macroreticulate polymer scavengers and containing Lewis acid and oxidant impurities which comprises contacting the fluid with a macroreticulate polymer scavenger to remove said impurities from said fluid, said scavenger comprising a macroreticulate polymer backbone having a plurality of pendant functional groups or a mixture of functional groups corresponding to the general formula: ##STR4## where Ar is an aromatic hydrocarbon radical containing from one to three rings; R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, alkyl hydrocarbon radicals containing 1 to 12 carbon atoms, methylene-bridged benzophenone radicals, alkali or alkaline earth metal salts of methylene-bridged benzophenone; methylene-bridged fluorenone radicals, and alkali or alkaline earth metal salts of methylene-bridged fluorenone; and M is selected from the group consisting of lithium, potassium, sodium, alkyl magnesium, or alkyl zinc where the alkyl groups are hydrocarbon alkyl radicals containing from 1 to 12 carbon atoms and then separating the thus contacted fluid from the macroreticulate polymer.

Claim 3

The process of claim 1 wherein M is lithium, R 1 is hydrogen and R 2 is a pentyl radical.

Claim 4

The process of claim 1 wherein M is butylmagnesium, R 1 is hydrogen and R 2 is a pentyl radical.

Claim 5

The process of claim 1 wherein the fluid inert to the scavenger is a saturated aliphatic hydrocarbon.

Claim 6

The process of claim 1 wherein the fluid inert to the scavenger is an olefin.

Claim 7

The process of claim 5 wherein the fluid inert to the scavenger is ethylene.

Claim 8

The process of claim 5 wherein the fluid inert to the scavenger is propylene.

Claim 9

The process of claim 1 wherein the fluid inert to the scavenger is selected from the group consisting of nitrogen, argon, helium, xenon, hydrogen, carbon tetrafluoride, ammonia and silane.

Claim 10

The process of claim 8 wherein the fluid inert to the scavenger is hydrogen.

Claim 11

The process of claim 8 wherein the fluid inert to the scavenger is nitrogen.

Claim 12

In a device for the purification of fluids to remove impurities, said impurities comprising oxidants and Lewis acids, said device comprising a chamber which is impermeable to the fluid to be purified, an inlet port at one end of the chamber, and an outlet port at the other end of said chamber, said chamber being filled with the fluid and a scavenger wherein said scavenger removes said impurities from said fluid, the improvement wherein the scavenger is a macroreticulate polymer comprising a macroreticulate polymer backbone having a plurality of pendant functional groups or mixtures of functional groups where the functional groups correspond to the general formula: ##STR5## where Ar is an aromatic hydrocarbon radical containing from one to three rings; R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, alkyl hydrocarbon radicals containing from 1 to 12 carbon atoms, methylene-bridged benzophenone radicals, alkali or alkaline earth metal salts of methylene-bridged benzophenone; methylene-bridged fluorenone radicals and alkali or alkaline earth metal salts of methylene-bridged fluorenone; and M is selected from the group consisting of lithium, potassium, sodium, alkyl magnesium, and alkyl zinc where the alkyl groups are hydrocarbon alkyl radicals containing from 1 to 12 carbon atoms.

Claim 13

In a device for the purification of fluids to remove impurities, said impurities comprising oxidants and Lewis acids, said device comprising a chamber which is impermeable to the fluid to be purified, an inlet port at one end of the chamber, and an outlet port at the other end of said chamber, said chamber being filled with the fluid and a scavenger wherein said scavenger removes said impurities from said fluid, the improvement wherein the scavenger is a macroreticulate polymer comprising a macroreticulate polymer backbone having a plurality of pendant functional groups or mixtures of functional groups where the functional groups correspond to the general formula: ##STR5## where Ar is an aromatic hydrocarbon radical containing from one to three rings; R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, alkyl hydrocarbon radicals containing from 1 to 12 carbon atoms, methylene-bridged benzophenone radicals, alkali or alkaline earth metal salts of methylene-bridged benzophenone; methylene-bridged fluorenone radicals and alkali or alkaline earth metal salts of methylene-bridged fluorenone; and M is selected from the group consisting of lithium, potassium, sodium, alkyl magnesium, and alkyl zinc where the alkyl groups are hydrocarbon alkyl radicals containing from 1 to 12 carbon atoms.

Claim 14

The device of claim 11 wherein N is lithium, R 1 is hydrogen and R 2 is a pentyl radical.

Claim 15

The device of claim 11 wherein M is butylmagnesium, R 1 is hydrogen and R 2 is a pentyl radical.