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US4603182A Expired / Lapsed US ⏱️ 0.0 years remaining

Low viscosity epoxy resin compositions

Assignee: General Electric Co
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Filing: 1984-10-05
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Granted: 1986-07-29
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Expires: 2004-10-05
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Abstract

Abstract The viscosities of solventless compositions of epoxy resins containing 1, 2 epoxy groups and having at least two epoxide groups per molecule and effective amounts of catalytic hardener and phenolic accelerator are dramatically reduced to make them useful for vacuum-pressure impregnation and also for pre-impregnated insulating material applications by addition of 3-33% of reactive diluent such as styrene.

Inventors

  • 👤 Mark Markovitz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 16:18
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/40; C; C08; C08F; C08F283/00; C08F283/10; C08G; C08G59/00; C08G59/18; C08G59/68; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2911; Y10T428/2913; Y10T428/2933; Y10T428/2936; Y10T428/31504; Y10T428/31511; Y10T428/31525; Y10T428/31529

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 86 words
A thermosetting resin composition having superior thermal stability consisting essentially of between about 50% and about 95% of 1, 2 epoxy resin having at least two epoxide groups per molecule, between about 3% and about 33% of a reactive diluent selected from the group consisting of styrene, alphamethyl styrene, an isomer or mixture of isomers of vinyl toluene, of t-butyl styrene, of divinyl benzene, and of diisopropenyl benzene, and mixtures thereof, and small but effective amount of a phenolic accelerator and a labile hydrogen-free catalytic hardener.
Claim 2
Dependent Claim 86 words
A thermosetting resin composition having superior thermal stability consisting essentially of between about 50% and about 95% of 1, 2 epoxy resin having at least two epoxide groups per molecule, between about 3% and about 33% of a reactive diluent selected from the group consisting of styrene, alphamethyl styrene, an isomer or mixture of isomers of vinyl toluene, of t-butyl styrene, of divinyl benzene, and of diisopropenyl benzene, and mixtures thereof, and small but effective amount of a phenolic accelerator and a labile hydrogen-free catalytic hardener.
Claim 3
Dependent Claim 21 words
The resin composition of claim 1 in which the diluent is ortho-, meta-, para-t-butyl styrene or a mixture of those isomers.
Claim 4
Dependent Claim 21 words
The resin composition of claim 1 in which the diluent is ortho-, meta-, para-vinyl toluene or a mixture of those isomers.
Claim 5
Dependent Claim 18 words
The resin composition of claim 1 in which the diluent is present in amount between 7.5% and 25%.
Claim 6
Dependent Claim 21 words
The resin composition of claim 4 in which the diluent is ortho-, meta-, para-t-butyl styrene or a mixture of those isomers.
Claim 7
Dependent Claim 21 words
The resin composition of claim 4 in which the diluent is ortho-, meta-, para-vinyl toluene or a mixture of those isomers.
Claim 8
Dependent Claim 12 words
The resin composition of claim 4 in which the diluent is styrene.
Claim 9
Dependent Claim 21 words
The resin composition of claim 4 in which the diluent is ortho-, meta-, para-diisopropenyl benzene or a mixture of those isomers.
Claim 10
Dependent Claim 16 words
The resin composition of claim 1 having viscosity less than about 3000 cps at 25° C.
Claim 11
Dependent Claim 50 words
The resin composition of claim 1 in which the phenolic accelerator is in quantity between 0.1% and 15% by weight of the epoxy resin, and in which the catalytic hardener is selected from the group consisting of 0.025% to 5.0% metal acetylacetonate, 0.05% to 10% organic titanate, and mixtures thereof.
Claim 12
Dependent Claim 30 words
The resin composition of claim 1 in which the catalytic hardener is a metal acetylacetonate selected from the group consisting of aluminum acetylacetonate, zirconium acetylacetonate, titanium acetylacetonate, and mixtures thereof.
Claim 13
Dependent Claim 29 words
The resin composition of claim 11 in which the catalytic hardener is an organic titanate selected from the group consisting of tetraoctylene glycol titanate, tetrabutyl titanate, and mixtures thereof.
Claim 14
Dependent Claim 26 words
The resin composition of claim 11 in which the phenolic accelerator is selected from the group consisting of catechol, resorcinol, phenol novolac resin and mixtures thereof.

References Cited (Backward Citations)

US3812214A Cited
US3776978A Cited
US4113791A Cited
US4173593A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-07-28 1990-01-27 1990-07-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-07-28 1994-01-27 1994-07-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-07-28 1998-01-27 1998-07-29 $7700.00 Window Closed / Lapsed

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