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US4603035A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrogen sulfide removal process

Assignee: Chevron USA Inc
•
Filing: 1983-09-30
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Granted: 1986-07-29
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Expires: 2003-09-30
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Abstract

Abstract A Stretford process for removing hydrogen sulfide from a high volumetric flow gas stream includes devices for introducing transverse momentum components in a multiphase flow. These momentum components enhance gas/liquid contact and improve the efficiency of hydrogen sulfide removal. Various devices for introducing the momentum components are disclosed including baffle trays, static mixer and tertiary spray devices.

Inventors

  • 👤 David E. Connell
  • 👤 Colin M. Chapman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:07
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; Y; Y10; Y10S; Y10S261/00; Y10S261/54

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 176 words
A Stretford process for removing hydrogen sulfide from a gas stream comprising the steps of: flowing a gas stream containing a hydrogen sulfide constituent into a venturi scrubbing device; spraying a Stretford solution into cocurrent contact with the gas stream which reacts with the hydrogen sulfide constituent and generates elemental sulfur resulting in a multiphase fluid flow leaving the scrubbing device; inducing in the multiphase fluid flow downstream of the scrubbing device fluid momentum components transverse to the direction of the multiphase fluid flow leaving the scrubbing device to enhance gas/liquid contact; discharging the multiphase flow into an absorbing column; separating both Stretford liquid and the solid phase from the gaseous phase by centrifugal action in the absorber column; contacting the gaseous phase with additional Stretford solution that reacts with the hydrogen sulfide constituent in the absorber column in countercurrent relationship; gravitationally separating the additional Stretford solution from the gaseous phase in the absorber column; separating elemental sulfur from the liquid and regenerating the Stretford liquid with an oxygencontaining gas; and recirculating the regenerated Stretford liquid.
Claim 2
Dependent Claim 176 words
A Stretford process for removing hydrogen sulfide from a gas stream comprising the steps of: flowing a gas stream containing a hydrogen sulfide constituent into a venturi scrubbing device; spraying a Stretford solution into cocurrent contact with the gas stream which reacts with the hydrogen sulfide constituent and generates elemental sulfur resulting in a multiphase fluid flow leaving the scrubbing device; inducing in the multiphase fluid flow downstream of the scrubbing device fluid momentum components transverse to the direction of the multiphase fluid flow leaving the scrubbing device to enhance gas/liquid contact; discharging the multiphase flow into an absorbing column; separating both Stretford liquid and the solid phase from the gaseous phase by centrifugal action in the absorber column; contacting the gaseous phase with additional Stretford solution that reacts with the hydrogen sulfide constituent in the absorber column in countercurrent relationship; gravitationally separating the additional Stretford solution from the gaseous phase in the absorber column; separating elemental sulfur from the liquid and regenerating the Stretford liquid with an oxygencontaining gas; and recirculating the regenerated Stretford liquid.
Claim 3
Dependent Claim 35 words
The process of claim 1 wherein the momentum inducing step includes passing the multiphase flow around members protruding into the path of the multiphase flow so that the multiphase flow traverses a serpentine flow path.
Claim 4
Dependent Claim 15 words
The process of claim 2 wherein the serpentine flow path is induced by baffle trays.
Claim 5
Dependent Claim 16 words
The process of claim 2 wherein the serpentine flow path is induced by sloped baffle trays.
Claim 6
Dependent Claim 18 words
The process of claim 2 wherein the serpentine flow path is induced by interdigitated disc and doughnut plates.
Claim 7
Dependent Claim 51 words
The process of claim 1 wherein the momentum inducing step includes passing a portion of the multiphase flow through a spiral flow path and a second portion of the multiphase flow through a generally cylindrical flow path, the spiral and cylindrical flow paths being in lateral fluid communication with one another.
Claim 8
Dependent Claim 17 words
The process of claim 6 wherein the multiphase flow is split into portions by a static mixer.
Claim 9
Dependent Claim 27 words
The process of claim 1 wherein the momentum inducing step includes spraying liquid into the multiphase flow so that a radially outwardly directed flow component is obtained.
Claim 10
Dependent Claim 27 words
The process of claim 1 wherein the momentum inducing step includes spraying liquid into the multiphase flow so that a radially inwardly directed flow component is obtained.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-07-28 1990-01-27 1990-07-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-07-28 1994-01-27 1994-07-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-07-28 1998-01-27 1998-07-29 $7700.00 Window Closed / Lapsed

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