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US4599274A
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Photo-curable adhesive composition for glass lamination and laminated glass and process for its production
Assignee: Denka Co Ltd
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Filing: 1984-03-01
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Granted: 1986-07-08
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Expires: 2004-03-01
Abstract
Abstract A photo-curable adhesive composition for glass lamination, which comprises: (A) 100 parts by weight of a (meth)acrylate monomer represented by the formula: ##STR1## where R 1 is a hydrogen atom or a CH 3 -- group, each of R 2 , R 3 and R 4 is a straight-chained or branched alkylene group, each of n 1 and n 4 is an integer of at least 1 and each of n 2 and n 3 is an integer of 0 or at least 1, and having a molecular weight of from about 116 to about 5,000; (B) from 0.1 to 5 parts by weight of a photosensitizer; (C) from 0 to 5 parts by weight of a silane coupling agent; and (D) from 0 to 100 parts by weight of a plasticizer.
Inventors
- 👤 Toshihiro Ando
- 👤 Yutaka Nakanishi
- 👤 Kenkichi Ukita
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 22:56
CPC Classifications
B; B32; B32B; B32B17/00; B32B17/06; B32B17/10; B32B17/10005; B32B17/1055; B32B17/10743; B32B17/10706; B32B7/00; B32B7/04; B32B7/12; C; C09; C09J; C09J4/00; B32B38/00; B32B2038/0052; B32B2038/0076; B32B2310/00; B32B2310/08; B32B2310/0806; B32B2310/0831; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31609; Y10T428/31612; Y10T428/31645; Y10T428/31649; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
146 words
A photo-curable adhesive composition for glass lamination, which comprises: (A) 100 parts by weight of a (meth)acrylate monomer represented by the formula: ##STR4## where R 1 is a hydrogen atom or a CH 3 -group, each of R 2 , R 3 and R 4 is a straight-chained or branched alkylene group, each of n 1 and n 4 is an integer of at least 1 and each of n 2 and n 3 is an integer of 0 or at least 1, and having a molecular weight of from about 116 to about 5,000; (B) from 0.1 to 5 parts by weight of a photosensitizer; (C) from 0.1 to 5 parts by weight of a silane coupling agent which improves moisture resistance and durability; and (D) from 0 to 100 parts by weight of a plasticizer that will not decrease the transparency of the adhesive.
Claim 2
Dependent Claim
146 words
A photo-curable adhesive composition for glass lamination, which comprises: (A) 100 parts by weight of a (meth)acrylate monomer represented by the formula: ##STR4## where R 1 is a hydrogen atom or a CH 3 -group, each of R 2 , R 3 and R 4 is a straight-chained or branched alkylene group, each of n 1 and n 4 is an integer of at least 1 and each of n 2 and n 3 is an integer of 0 or at least 1, and having a molecular weight of from about 116 to about 5,000; (B) from 0.1 to 5 parts by weight of a photosensitizer; (C) from 0.1 to 5 parts by weight of a silane coupling agent which improves moisture resistance and durability; and (D) from 0 to 100 parts by weight of a plasticizer that will not decrease the transparency of the adhesive.
Claim 3
Dependent Claim
35 words
The photo-curable adhesive composition according to claim 1, wherein the (meth)acrylate monomer is at least one member selected from the group consisting of (i) 2-hydroxyethyl methacrylate, (ii) 2-hydroxypropyl methacrylate and (iii) a polypropylene glycol monomethacrylate.
Claim 4
Dependent Claim
54 words
The photo-curable adhesive composition according to claim 1, wherein the (meth)acrylate monomer is composed of (a) from 5 to 45 parts by weight of 2-hydroxyethyl methacrylate and/or 2-hydroxypropyl methacrylate and (b) from 55 to 95 parts by weight of a polypropylene glycol monomethacrylate having a molecular weight of from about 300 to about 1,000.
Claim 5
Dependent Claim
40 words
The photo-curable adhesive composition according to claim 1, wherein the plasticizer is a compound represented by the formula: ##STR5## where R 1 is a hydrogen atom or a methyl group and n 1 is an integer of at least 1.
Claim 6
Dependent Claim
15 words
The photo-curable adhesive composition according to claim 1, wherein the plasticizer is a polypropylene glycol.
Claim 7
Dependent Claim
18 words
The photo-curable adhesive composition according to claim 1, wherein the photosensitizer is benzoin diethyl ether or benzyldimethyl ketal.
Claim 8
Dependent Claim
38 words
The photo-curable adhesive composition according to claim 1, wherein the silane coupling agent is a silane coupling agent having an organic group selected from the group consisting of a vinyl group, a methacryloyl group and a mercapto group.
Claim 9
Dependent Claim
25 words
A process for producing a laminated glass product, which comprises laminating glass sheets by means of the photo-curable adhesive composition as defined in claim 1.
Claim 10
Dependent Claim
21 words
A laminated glass product obtained by laminating glass sheets by means of the photo-curable adhesive composition as defined in claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-07-07 | 1990-01-06 | 1990-07-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-07-07 | 1994-01-06 | 1994-07-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-07-07 | 1998-01-06 | 1998-07-08 | $7700.00 | Window Closed / Lapsed |