Resin composition

Claim 2

A resin composition which comprises (A) a spiro ortho ester compound and/or a spiro ortho carbonate compound; (B) an aluminum compound; and (C) a silanol compound or a silicon compound which is capable of generating a silanol group; the amounts of components (B) and (C) being within the range of 0.001 to 10% by weight and 0.1 to 20% by weight, based on the amount of component (A), respectively.

Claim 3

The resin composition according to claim 1, wherein the spiro ortho ester compound is a reaction product of an epoxy compound and a lactone.

Claim 4

The resin composition according to claim 2, wherein the epoxy compound (A) is selected from the group of compounds consisting of ethylene oxide, propylene oxide, butylene oxide, styrene oxide, phenyl glycidyl ether, butyl glycidyl ether, a bisphenol A epoxy resin, a bisphenol F epoxy resin, a phenol-novolac epoxy resin, an alicyclic epoxy resin, a heterocyclic ring-containing epoxy resin, a hydrogenated bisphenol A epoxy resin, an aliphatic epoxy resin, an epoxy resin obtained by the reaction of an aromatic, aliphatic or alicyclic carboxylic acid with epichlorohydrin; a spiro ring-containing epoxy resin, a glycidyl ether epoxy resin and a glycidyl ester epoxy resin or (B) is a mixture of two or more compounds selected from said group of compounds.

Claim 5

The resin composition according to claim 3, wherein the lactone (A) is selected from the group of lactones consisting of β-propiolactone, γ-butyrolactone, α-chlorobutyrolactone, β-methylburtyrolactone, γ,γ-dimethylbutyrolactone, γ-valerolactone, δ-valerolactone, ε-caprolactone and phthalide or (B) is a mixture of two or more compounds selected from said group of lactones.

Claim 6

The resin composition according to claim 2, wherein the spiro ortho carbonate compound is a compound represented by the formula: ##STR26## wherein Y represents a divalent hydrocarbon group.

Claim 7

The resin composition according to claim 1, wherein the aluminum compound is an organic aluminum chelate compound.

Claim 8

The resin composition according to claim 6, wherein the aluminum compound is an organic aluminum compound having a ligand selected from the group consisting of an alkoxy group, a phenoxy grouo, an acyloxy group, a β-diketonato group and an o-carbonylphenolato group.

Claim 9

The resin composition according to claim 7, wherein the aluminum compound (A) is selected from the group of compounds consisting of trisacetylacetonatoaluminum, trisethylacetoacetatoaluminum, trissalycilaldehydatoaluminum, trispropylacetoacetatoaluminum and tris(n-butylacetoacetonato)aluminum or (B) is a mixture of two or more compounds selected from said group of compounds.

Claim 10

The resin composition according to claim 6, wherein the aluminum compound is present in an amount of 0.1 to 5% by weight based on the component (A).

Claim 11

The resin composition according to claim 1, wherein the silanol compound is a compound represented by the following formula (I) or (II): ##STR27## wherein R 1 , R 2 and R 3 each represent a hydrogen atom, an alkyl group, a phenyl group or an unsaturated group which is unsubstituted or is substituted with an alkoxy group or a siloxane group; m is a number of 1 or more; n is 0 or an integer of 1 or more; and R 4 , R 5 and R 6 each represent an alkyl group, a phenyl group, an alkoxy group or a hydroxy group.

Claim 12

The resin composition according to claim 1, wherein compound (C) is a silicon compound capable of generating a silanol group by hydrolysis.

Claim 13

The resin composition according to claim 11, wherein the silicon compound capable of generating a silanol group by hydrolysis comprises an organosilane represented by the following formula (III): ##STR28## wherein Mul represents a phenyl group, a vinyl group, a 2-butenyl group or a 2-pentenyl group; Hydr represents a hydrolyzable group; X represents a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms, provided that the substituent is an inactive group which does not participate in the polymerization reaction, or an aralkyl group which is unsubstituted or carries a substituent that is inactive in the polymerization reaction; and p represents an integer of 1 to 3, q represents an integer from 1 to 4 and p+q are 4 or less, or an organosiloxane comprising a bifunctional unit represented by the following formula (IV) and/or a trifunctional unit represented by the following formula (V), and the terminal end of the organosiloxane has been stopped with the monofunctional unit represented by the following formula (VI): ##STR29## wherein Y 1 , Y 2 , Y 3 , Y 4 , Y 5 and Y 6 are the same or different and each represents a hydrolyzable group; a group having an ethylenically unsaturated double bond; or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms, provided that each substituent is an inactive group which does not participate in the polymerization reaction.

Claim 14

The resin composition according to claim 1, wherein compound (C) is a silicon compound capable of generating a silanol group by irradiation of light.

Claim 15

The resin composition according to claim 13, wherein the silicon compound capable of generating a silanol group by irradiation of light is a compound having a group selected from the group consisting of a peroxysilyl group, an o-nitrobenzyloxy group and an α-ketosilyl group.

Claim 16

The resin composition according to claim 14, wherein compound (C) is a silicon compound having a peroxysilyl group, represented by the following formula (IX): (R.sup.7).sub.r Si--O--O--R.sup.8).sub.4-r (IX) wherein R 7 represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms or an aryl group; R 8 represents an alkyl group having 1 to 5 carbon atoms or an aryl group; and r is an integer of 0 to 3.

Claim 17

The resin composition according to claim 13, wherein compound (C) is a silicon compound having an o-nitrobenzyloxy group, represented by the following formula (X): ##STR30## wherein R 9 , R 10 and R 11 are the same or different and each represents a hydrogen atom, a halogen atom, a vinyl group, an allyl group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group, an aryloxy group or a siloxy group; R 12 represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms or a substituted or unsubstituted phenyl group; R 13 , R 14 , R 15 and R 16 are the same or different and each represents a hydrogen atom, a nitro group, a cyano group, a hydroxy group, a mercapto group, a halogen atom, an acetyl group, an allyl group, an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, a substituted or unsubstituted aryl group or aryloxy group; and s, t and u are integers satisfying the conditions of 0≦s, t, u≦3 and 1≦s+t+u≦3.

Claim 18

The resin composition according to claim 13, wherein compound (C) is a silicon compound having as a terminal group an o-nitrobenzyloxysilyl group and as a principle chain a group represented by the formula (XI): ##STR31## wherein n is an integer of 1 or more; R 9 and R 10 are the same or different and each represents a hydrogen atom, a halogen atom, a vinyl group, an allyl group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group, an aryloxy group or a siloxy group; and X and Y are same or different and each represents an oxygen atom, an alkylene group or an aryl group.

Claim 19

The resin composition according to claim 14, wherein the silicon compound capable of generating a silanol group by irradiation of light has an α-ketosilyl group and is represented by the following formula (XII): ##STR32## wherein R 17 represents a substitutent selected from the group consisting of an alkyl group having 1 to 10 carbon atoms, a vinyl group, an allkyl group, an aryl group, and an aryloxy group and an alkoxy group having 1 to 10 carbon atoms, said substituent being unsubstituted or substituted by a halogen atom, --NO 2 , --CN or --OCH 3 ; and v represents an integer of 0 to 3.

Claim 20

The resin composition according to claim 1, wherein the silanol compound or silicon compound which is capable of generating a silanol group is present in an amount of 1 to 15% by weight based on the component (A).

Claim 21

The resin composition according to claim 1, wherein the resin composition further comprises a photosensitizer.

Claim 22

The resin composition according to claim 20, wherein the photosensitizer (A) is selected from the group of compounds consisting of aromatic hydrocarbons, benzophenone and derivatives thereof, esters of o-benzoylbenzoic acids, acetophenone and derivatives thereof, benzoin and benzoin ethers and derivatives thereof, xanthone and derivatives thereof, thioxanthone and derivatives thereof, disulfide compounds, quinone compounds, halogenated hydrocarbons and amines or (B) is a mixture of two or more compounds selected from said group of compounds.

Claim 23

A resin composition according to claim 5, wherein said divalent hydrocarbon group is selected from the group consisting ##STR33##