Patent US4597777A successfully refreshed from Google Patents.
US4597777A
Expired / Lapsed
US
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Membrane gas separation processes
Assignee: Permea Inc
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Filing: 1983-02-15
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Granted: 1986-07-01
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Expires: 2003-02-15
Abstract
Abstract This invention relates to membrane gas separation of carbon dioxide and methane containing gas mixtures. More particularly the invention relates to apparatus and processes for recovering a methane-enriched non-permeate gas of natural gas pipe line quality from mixtures of carbon dioxide and methane where membrane permeate gases contain substantially all of the carbon dioxide of the feed gas mixture. An aspect of the process of this invention is that a significant portion of the carbon dioxide containing permeate gas can be utilized as combustion engine fuel to drive feed gas compressors utilized in the process.
Inventors
- 👤 Tommy E. Graham
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 20:25
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/22; B01D53/225; B01D53/226; C; C07; C07C; C07C7/00; C07C7/144; Y; Y02; Y02C; Y02C20/00; Y02C20/40; Y02P; Y02P20/00; Y02P20/151
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
166 words
A membrane gas separator apparatus for recovering a methane-enriched non-permeate gas from a mixture comprising methane and carbon dioxide, said appartaus comprising at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; at least one subsequent separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; a combustion engine for generating power; means for providing said mixture at a permeating pressure to said at least one first separator; means for conducting a non-permeate gas from said at least one first separator to said at least one subsequent separator; means for withdrawing carbon dioxide-enriched permeate gas from said at least one first separator; means for withdrawing a methane-enriched non-permeate gas from said at least one subsequent separator; means for conducting a combustible permeate gas from said at least one subsequent separator to a fuel inlet of said combustion engine; and means for transmitting power from said combustion engine to said means for providing said mixture at a permeating pressure.
Claim 2
Dependent Claim
166 words
A membrane gas separator apparatus for recovering a methane-enriched non-permeate gas from a mixture comprising methane and carbon dioxide, said appartaus comprising at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; at least one subsequent separator having a membrane exhibiting selectivity to the permeation of carbon dioxide; a combustion engine for generating power; means for providing said mixture at a permeating pressure to said at least one first separator; means for conducting a non-permeate gas from said at least one first separator to said at least one subsequent separator; means for withdrawing carbon dioxide-enriched permeate gas from said at least one first separator; means for withdrawing a methane-enriched non-permeate gas from said at least one subsequent separator; means for conducting a combustible permeate gas from said at least one subsequent separator to a fuel inlet of said combustion engine; and means for transmitting power from said combustion engine to said means for providing said mixture at a permeating pressure.
Claim 3
Dependent Claim
52 words
The separator of claim 1 further comprising a manifold having at least one connection to said means for withdrawing a carbon dioxide-enriched permeate gas from said at least one first separator and at least one connection to said means for conducting a combustible permeate gas from said at least one subsequent separator.
Claim 4
Dependent Claim
13 words
The separator of claim 2 having valves in said manifold between said connections.
Claim 5
Dependent Claim
22 words
The separator of claim 3 further comprising means for operating said valves responsive to a fuel requirement of said combustion engine-driven means.
Claim 6
Dependent Claim
215 words
A membrane gas separation process for recovering from a mixture comprising from 30 to 70 mole percent methane and from 30 to 60 mole percent carbon dioxide a methane-enriched non-permeate gas said process comprising (a) passing said mixture to means for providing said mixture at a permeating pressure; (b) passing said mixture at a permeating pressure to at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide, wherein the separation factor, αCO 2 /CH 4 , is at least about 9; (c) allowing the non-permeate gas from said at least one first separator to pass at a permeating pressure to at least one subsequent separator having a membrane exhibiting selectivity to the permeation of carbon dioxide, wherein the separation factor, αCO 2 /CH 4 , is at least about 9; (d) withdrawing a carbon dioxide-enriched permeate gas from said at least one first separator; (e) withdrawing a methane-enriched non-permeate gas comprising at least about 90 mole percent methane from said at least one subsequent separator; and (f) allowing a combustible permeate gas comprising at least about 40 mole percent methane to flow from said at least one subsequent separator to a combustion engine having means to transmit power to said means for providing said mixture at a permeating pressure.
Claim 7
Dependent Claim
215 words
A membrane gas separation process for recovering from a mixture comprising from 30 to 70 mole percent methane and from 30 to 60 mole percent carbon dioxide a methane-enriched non-permeate gas said process comprising (a) passing said mixture to means for providing said mixture at a permeating pressure; (b) passing said mixture at a permeating pressure to at least one first separator having a membrane exhibiting selectivity to the permeation of carbon dioxide, wherein the separation factor, αCO 2 /CH 4 , is at least about 9; (c) allowing the non-permeate gas from said at least one first separator to pass at a permeating pressure to at least one subsequent separator having a membrane exhibiting selectivity to the permeation of carbon dioxide, wherein the separation factor, αCO 2 /CH 4 , is at least about 9; (d) withdrawing a carbon dioxide-enriched permeate gas from said at least one first separator; (e) withdrawing a methane-enriched non-permeate gas comprising at least about 90 mole percent methane from said at least one subsequent separator; and (f) allowing a combustible permeate gas comprising at least about 40 mole percent methane to flow from said at least one subsequent separator to a combustion engine having means to transmit power to said means for providing said mixture at a permeating pressure.
Claim 8
Dependent Claim
22 words
The process of claim 5 wherein said methane-enriched non-permeate gas comprises at least 60 percent of the total methane in said mixture.
Claim 9
Dependent Claim
25 words
The process of claim 6 wherein power is mechanically transmitted from said combustion engine to said means for providing said mixture at a permeating pressure.
Claim 10
Dependent Claim
37 words
The process of claim 6 wherein said means for providing said mixture at a permeating pressure is driven by electric power and said combustible permeate gas is used as fuel for a combustion engine-driven electric power generator.
Claim 11
Dependent Claim
20 words
The process of claim 6 wherein a portion of said methane-enriched non-permeate gas is added to said combustible permeate gas.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-06-30 | 1989-12-30 | 1990-07-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-06-30 | 1993-12-30 | 1994-07-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-06-30 | 1997-12-30 | 1998-07-01 | $7700.00 | Window Closed / Lapsed |