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Transition metal aluminates

Assignee: Dow Chemical Co
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Filing: 1984-05-11
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Granted: 1986-06-10
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Expires: 2004-05-11
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Abstract

Abstract Crystalline transition metal aluminate compounds are formed by reacting transition metal compounds with crystalline hydrous alumina, such as gibbsite, bayerite, norstrandite, boehmite and the like. The crystalline hydrous alumina may be unsupported by a solid substrate or may be supported on a solid substrate or within the pores of a solid substrate, such as a macroporous resin.

Inventors

  • 👤 John L. Burba, III
  • 👤 Richard A. Wolcott

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:44
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/005; B01J23/06; B01J23/16; B01J23/32; B01J23/34; B01J23/70; B01J23/74; B01J31/00; B01J31/02; B01J31/06; B01J31/08; C; C01; C01G; C01G51/00; C01G51/80; C01G51/82; C01G53/00; C01G53/80; C01G53/82

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 172 words
In a method for preparing a compound comforming substantially to the empirical formula MA a v Z b v .nAl(OH) 3 .mH 2 O where M represents at least one divalent transition metal selected from the group comprising Cu, Zn, Mn, Fe, Co, and Ni, where A and Z represent anions or negative-valence radicals of mono-, di- , or polyvalences, v represents the valence, a is an amount in the range of 0-2, b is an amount in the range of 0-2, with (va)+(vb) equal to 2 to satisfy the valence requirements of divalent M, where n represents a numerical value such that the ratio of Al/M is at least 1/1, and where m represents a numerical value for waters of hydration of zero or greater, said process comprising reacting hydrous alumina, in an alkaline aqueous carrier, with a transition metal compound of the empirical formula MAZ, where M, A, and Z are as described above, said process being further characterized by performing said reaction at elevated temperature, using crystalline hydrous alumina.
Claim 2
Dependent Claim 172 words
In a method for preparing a compound comforming substantially to the empirical formula MA a v Z b v .nAl(OH) 3 .mH 2 O where M represents at least one divalent transition metal selected from the group comprising Cu, Zn, Mn, Fe, Co, and Ni, where A and Z represent anions or negative-valence radicals of mono-, di- , or polyvalences, v represents the valence, a is an amount in the range of 0-2, b is an amount in the range of 0-2, with (va)+(vb) equal to 2 to satisfy the valence requirements of divalent M, where n represents a numerical value such that the ratio of Al/M is at least 1/1, and where m represents a numerical value for waters of hydration of zero or greater, said process comprising reacting hydrous alumina, in an alkaline aqueous carrier, with a transition metal compound of the empirical formula MAZ, where M, A, and Z are as described above, said process being further characterized by performing said reaction at elevated temperature, using crystalline hydrous alumina.
Claim 3
Dependent Claim 12 words
The method of claim 1 wherein the crystalline hydrous alumina is gibbsite.
Claim 4
Dependent Claim 12 words
The method of claim 1 wherein the crystalline hydrous alumina is bayerite.
Claim 5
Dependent Claim 12 words
The method of claim 1 wherein the crystalline hydrous alumina is boehmite.
Claim 6
Dependent Claim 27 words
The method of claim 1 wherein the crystalline hydrous alumina conforms substantially to the formula Al(OH) 3 , Al 2 O 3 nH 2 O or AlOOH.
Claim 7
Dependent Claim 27 words
The method of claim 1 wherein the reaction of the crystalline hydrous alumina with the transition metal compound is performed in an alkaline carrier comprising aqueous NaOH.
Claim 8
Dependent Claim 35 words
The method of claim 1 wherein the reaction of the crystalline hydrous alumina with the transition metal compound is performed at an elevated temperature in the range of about 95° C. to about 100° C.
Claim 9
Dependent Claim 13 words
The method of claim 1 wherein the anions or negative-valence radicals are monovalent.
Claim 10
Dependent Claim 13 words
The method of claim 1 wherein the anions or neagative-valence radicals are divalent.
Claim 11
Dependent Claim 13 words
The method of claim 1 wherein the anions or negative-valence radicals are polyvalent.
Claim 12
Dependent Claim 13 words
The method of claim 1 wherein the anions or negative-valence radicals are inorganic.
Claim 13
Dependent Claim 13 words
The method of claim 1 wherein the anions or negative-valence radicals are organic.
Claim 14
Dependent Claim 17 words
The method of claim 1 wherein the anions or negative-valence radicals comprise both organic and inorganic varieties.
Claim 15
Dependent Claim 17 words
The method of claim 1 wherein the anions or negative-valence radicals comprise both monovalent and polyvalent varieties.
Claim 16
Dependent Claim 15 words
The method of claim 1 wherein the value of m is from zero to 6.
Claim 17
Dependent Claim 18 words
The method of claim 1 wherein the crystalline product formed is M(OH) 2 .2Al(OH) 3 .mH 2 O.
Claim 18
Dependent Claim 18 words
The method of claim 1 wherein the crystalline product formed is MCl 2 .2Al(OH) 3 .mH 2 O.
Claim 19
Dependent Claim 9 words
The method of claim 1 wherein M is Co.
Claim 20
Dependent Claim 9 words
The method of claim 1 wherein M is Ni.
Claim 21
Dependent Claim 16 words
The method of claim 1 wherein the crystalline hydrous alumina is supported by a solid substrate.
Claim 22
Dependent Claim 15 words
The method of claim 1 wherein the crystalline hydrous alumina is supported by a resin.
Claim 23
Dependent Claim 19 words
The method of claim 1 wherein the crystalline hydrous alumina is supported within the pores of a porous substrate.
Claim 24
Dependent Claim 19 words
The method of claim 1 wherein the crystalline hydrous alumina is supported within the pores of a porous resin.
Claim 25
Dependent Claim 21 words
The method of claim 1 wherein the crystalline hydrous alumina is supported within the pores of a macroporous ion exchange resin.

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3.5 Years (Year 4) 1989-06-09 1989-12-09 1990-06-10 $2000.00 Window Closed / Lapsed
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