Patent US4594335A successfully refreshed from Google Patents.
US4594335A
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Transition metal aluminates
Assignee: Dow Chemical Co
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Filing: 1984-05-11
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Granted: 1986-06-10
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Expires: 2004-05-11
Abstract
Abstract Crystalline transition metal aluminate compounds are formed by reacting transition metal compounds with crystalline hydrous alumina, such as gibbsite, bayerite, norstrandite, boehmite and the like. The crystalline hydrous alumina may be unsupported by a solid substrate or may be supported on a solid substrate or within the pores of a solid substrate, such as a macroporous resin.
Inventors
- 👤 John L. Burba, III
- 👤 Richard A. Wolcott
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:44
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/005; B01J23/06; B01J23/16; B01J23/32; B01J23/34; B01J23/70; B01J23/74; B01J31/00; B01J31/02; B01J31/06; B01J31/08; C; C01; C01G; C01G51/00; C01G51/80; C01G51/82; C01G53/00; C01G53/80; C01G53/82
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
172 words
In a method for preparing a compound comforming substantially to the empirical formula MA a v Z b v .nAl(OH) 3 .mH 2 O where M represents at least one divalent transition metal selected from the group comprising Cu, Zn, Mn, Fe, Co, and Ni, where A and Z represent anions or negative-valence radicals of mono-, di- , or polyvalences, v represents the valence, a is an amount in the range of 0-2, b is an amount in the range of 0-2, with (va)+(vb) equal to 2 to satisfy the valence requirements of divalent M, where n represents a numerical value such that the ratio of Al/M is at least 1/1, and where m represents a numerical value for waters of hydration of zero or greater, said process comprising reacting hydrous alumina, in an alkaline aqueous carrier, with a transition metal compound of the empirical formula MAZ, where M, A, and Z are as described above, said process being further characterized by performing said reaction at elevated temperature, using crystalline hydrous alumina.
Claim 2
Dependent Claim
172 words
In a method for preparing a compound comforming substantially to the empirical formula MA a v Z b v .nAl(OH) 3 .mH 2 O where M represents at least one divalent transition metal selected from the group comprising Cu, Zn, Mn, Fe, Co, and Ni, where A and Z represent anions or negative-valence radicals of mono-, di- , or polyvalences, v represents the valence, a is an amount in the range of 0-2, b is an amount in the range of 0-2, with (va)+(vb) equal to 2 to satisfy the valence requirements of divalent M, where n represents a numerical value such that the ratio of Al/M is at least 1/1, and where m represents a numerical value for waters of hydration of zero or greater, said process comprising reacting hydrous alumina, in an alkaline aqueous carrier, with a transition metal compound of the empirical formula MAZ, where M, A, and Z are as described above, said process being further characterized by performing said reaction at elevated temperature, using crystalline hydrous alumina.
Claim 3
Dependent Claim
12 words
The method of claim 1 wherein the crystalline hydrous alumina is gibbsite.
Claim 4
Dependent Claim
12 words
The method of claim 1 wherein the crystalline hydrous alumina is bayerite.
Claim 5
Dependent Claim
12 words
The method of claim 1 wherein the crystalline hydrous alumina is boehmite.
Claim 6
Dependent Claim
27 words
The method of claim 1 wherein the crystalline hydrous alumina conforms substantially to the formula Al(OH) 3 , Al 2 O 3 nH 2 O or AlOOH.
Claim 7
Dependent Claim
27 words
The method of claim 1 wherein the reaction of the crystalline hydrous alumina with the transition metal compound is performed in an alkaline carrier comprising aqueous NaOH.
Claim 8
Dependent Claim
35 words
The method of claim 1 wherein the reaction of the crystalline hydrous alumina with the transition metal compound is performed at an elevated temperature in the range of about 95° C. to about 100° C.
Claim 9
Dependent Claim
13 words
The method of claim 1 wherein the anions or negative-valence radicals are monovalent.
Claim 10
Dependent Claim
13 words
The method of claim 1 wherein the anions or neagative-valence radicals are divalent.
Claim 11
Dependent Claim
13 words
The method of claim 1 wherein the anions or negative-valence radicals are polyvalent.
Claim 12
Dependent Claim
13 words
The method of claim 1 wherein the anions or negative-valence radicals are inorganic.
Claim 13
Dependent Claim
13 words
The method of claim 1 wherein the anions or negative-valence radicals are organic.
Claim 14
Dependent Claim
17 words
The method of claim 1 wherein the anions or negative-valence radicals comprise both organic and inorganic varieties.
Claim 15
Dependent Claim
17 words
The method of claim 1 wherein the anions or negative-valence radicals comprise both monovalent and polyvalent varieties.
Claim 16
Dependent Claim
15 words
The method of claim 1 wherein the value of m is from zero to 6.
Claim 17
Dependent Claim
18 words
The method of claim 1 wherein the crystalline product formed is M(OH) 2 .2Al(OH) 3 .mH 2 O.
Claim 18
Dependent Claim
18 words
The method of claim 1 wherein the crystalline product formed is MCl 2 .2Al(OH) 3 .mH 2 O.
Claim 19
Dependent Claim
9 words
The method of claim 1 wherein M is Co.
Claim 20
Dependent Claim
9 words
The method of claim 1 wherein M is Ni.
Claim 21
Dependent Claim
16 words
The method of claim 1 wherein the crystalline hydrous alumina is supported by a solid substrate.
Claim 22
Dependent Claim
15 words
The method of claim 1 wherein the crystalline hydrous alumina is supported by a resin.
Claim 23
Dependent Claim
19 words
The method of claim 1 wherein the crystalline hydrous alumina is supported within the pores of a porous substrate.
Claim 24
Dependent Claim
19 words
The method of claim 1 wherein the crystalline hydrous alumina is supported within the pores of a porous resin.
Claim 25
Dependent Claim
21 words
The method of claim 1 wherein the crystalline hydrous alumina is supported within the pores of a macroporous ion exchange resin.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-06-09 | 1989-12-09 | 1990-06-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-06-09 | 1993-12-09 | 1994-06-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-06-09 | 1997-12-09 | 1998-06-10 | $7700.00 | Window Closed / Lapsed |