Patent US6438574B1 successfully refreshed from Google Patents.
Patent US4594303A successfully refreshed from Google Patents.
US4594303A
Expired / Lapsed
US
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Electrophotographic photoreceptor
Assignee: Fujifilm Holdings Corp
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Filing: 1985-08-28
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Granted: 1986-06-10
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Expires: 2005-08-28
Abstract
Abstract An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing as a charge generating material a particular organic compound having the general formula described hereinafter in this disclosure in a combination with a charge transporting material. The compounds improve upon the sensitivity, durability and selectivity to photosensitive wavelengths of photoreceptors. Furthermore, the photoreceptors can be easily manufactured.
Inventors
- 👤 Seiji Horie
- 👤 Masayoshi Nagata
- 👤 Junji Nakano
- 👤 Hideo Sato
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-10 02:21
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0666; G03G5/0668; G03G5/067; G03G5/0622; G03G5/0624; G03G5/0627; G03G5/0629; G03G5/0631; G03G5/0635; G03G5/0637; G03G5/0638; G03G5/0644; G03G5/0661
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
513 words
An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing a charge generating material and a charge transporting material, said charge generating material being a compound of the following general formula (I) or (II): ##STR11## wherein: (i) m is 0, and n is 0, 1, or 2, (ii) R 1 to R 5 may be the same or different, and each is a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a monovalent group produced by removing one hydrogen atom from a heterocyclic ring, (iii) A 1 is substituted phenyl group, a monovalent group produced by removing one hydrogen atom from a monocyclic 5-membered hetero-ring, a condensed 5-membered hetero-ring or a condensed 6-membered hetero-ring, which have the following structural formulae, respectively; ##STR12## wherein R 6 is an alkoxy group, an aralkyloxy group or a substituted amino group of the formula ##STR13## R 12 and R 13 each is a substituted or non-substituted alkyl group or a substituted or non-substituted phenyl group, or they may combine with each other and form a nitrogen-containing hetero-ring, and they may be the same or different; R 7 and R 8 may be the same or different, and each is a hydrogen atom, a halogen atom, an alkyl group or a lower alkoxy group; Y and Z are S, O or N--R 14 , wherein R 14 is an alkyl group having 1 to 4 carbon atoms, and they may be the same or different; R 9 and R 10 may be the same or different, and each is a hydrogen atom, an alkyl group or an alkoxy group, or they may combine with each other and form a benzene ring or a naphthalene ring; and R 11 is a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarcarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amido group or a nitro group, which groups each may be substituted; (iv) A 2 is a divalent group produced by removing two hydrogen atoms attached to the same carbon from a heterocyclic ring selected from a group consisting of imidazoles, 3H-indoles, thiazoles, benzothiazoles, naphthothiazoles, thianaphtheno-7',6',4,5-thiazoles, oxazoles, benzoxazoles, naphthooxazoles, selenazoles, benzoselenazoles, naphthoselenazoles, thiazolines, quinolines, isoquinolines, benzimidazoles and pyridines, and (v) B 1 is a divalent group selected from substituents of the following structural formulae; ##STR14## wherein R 15 and R 16 each is an alkyl group or an aryl group; X is an oxygen atom or a sulfur atom; and B 2 is a cyano group, a carboxyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group, an alkylcarbonyl group, an arylcarbonyl group, a nitro group, a nitro-substituted aryl group, a sulfo group, a trifluoromethylsulfonyl group, a carbamoyl group, an alkylcarbamoyl group, an arylcarbamoyl group or an acyl group whose carbonyl group is attached to a monovalent group produced by removing one hydrogen atom from a heterocyclic ring, and said charge transporting material is at least one compound selected from the group consisting of triphenylamine derivatives, polyarylalkane derivatives, pyrazoline derivatives and hydrazone derivatives.
Claim 2
Dependent Claim
513 words
An electrophotographic photoreceptor which has an electrophotographic photoreceptive layer containing a charge generating material and a charge transporting material, said charge generating material being a compound of the following general formula (I) or (II): ##STR11## wherein: (i) m is 0, and n is 0, 1, or 2, (ii) R 1 to R 5 may be the same or different, and each is a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a monovalent group produced by removing one hydrogen atom from a heterocyclic ring, (iii) A 1 is substituted phenyl group, a monovalent group produced by removing one hydrogen atom from a monocyclic 5-membered hetero-ring, a condensed 5-membered hetero-ring or a condensed 6-membered hetero-ring, which have the following structural formulae, respectively; ##STR12## wherein R 6 is an alkoxy group, an aralkyloxy group or a substituted amino group of the formula ##STR13## R 12 and R 13 each is a substituted or non-substituted alkyl group or a substituted or non-substituted phenyl group, or they may combine with each other and form a nitrogen-containing hetero-ring, and they may be the same or different; R 7 and R 8 may be the same or different, and each is a hydrogen atom, a halogen atom, an alkyl group or a lower alkoxy group; Y and Z are S, O or N--R 14 , wherein R 14 is an alkyl group having 1 to 4 carbon atoms, and they may be the same or different; R 9 and R 10 may be the same or different, and each is a hydrogen atom, an alkyl group or an alkoxy group, or they may combine with each other and form a benzene ring or a naphthalene ring; and R 11 is a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarcarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amido group or a nitro group, which groups each may be substituted; (iv) A 2 is a divalent group produced by removing two hydrogen atoms attached to the same carbon from a heterocyclic ring selected from a group consisting of imidazoles, 3H-indoles, thiazoles, benzothiazoles, naphthothiazoles, thianaphtheno-7',6',4,5-thiazoles, oxazoles, benzoxazoles, naphthooxazoles, selenazoles, benzoselenazoles, naphthoselenazoles, thiazolines, quinolines, isoquinolines, benzimidazoles and pyridines, and (v) B 1 is a divalent group selected from substituents of the following structural formulae; ##STR14## wherein R 15 and R 16 each is an alkyl group or an aryl group; X is an oxygen atom or a sulfur atom; and B 2 is a cyano group, a carboxyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group, an alkylcarbonyl group, an arylcarbonyl group, a nitro group, a nitro-substituted aryl group, a sulfo group, a trifluoromethylsulfonyl group, a carbamoyl group, an alkylcarbamoyl group, an arylcarbamoyl group or an acyl group whose carbonyl group is attached to a monovalent group produced by removing one hydrogen atom from a heterocyclic ring, and said charge transporting material is at least one compound selected from the group consisting of triphenylamine derivatives, polyarylalkane derivatives, pyrazoline derivatives and hydrazone derivatives.
Claim 3
Dependent Claim
27 words
The electrophotographic photoreceptor described in claim 1, wherein said electrophotographic photoreceptive layer is a single layer containing both said charge generating material and said charge transporting material.
Claim 4
Dependent Claim
44 words
The electrophotographic photoreceptor described in claim 1, wherein said electrophotographic photoreceptive layer is comprised of two layers, a first layer being a charge generating layer containing said charge generating material, and a second layer being a charge transporting layer containing said charge transporting material.
Claim 5
Dependent Claim
23 words
An electrophotographic photoreceptor as claimed in claim 2, wherein the electrophotographic photoreceptive layer has a thickness of from 3 μm to 50 μm.
Claim 6
Dependent Claim
22 words
An electrophotographic photoreceptor as claimed in claim 4, wherein the thickness of the electrophotographic photoreceptive layer is 5 μm to 20 μm.
Claim 7
Dependent Claim
20 words
An electrophotographic photoreceptor as claimed in claim 3, wherein the charge-generating layer has a thickness of 5 μm or less.
Claim 8
Dependent Claim
20 words
An electrophotographic photoreceptor as claimed in claim 6, wherein the charge-generating layer has a thickness of 2 μm or less.
Claim 9
Dependent Claim
22 words
An electrophotographic photoreceptor as claimed in claim 3, wherein the charge transporting layer has a thickness of 3 μm to 50 μm.
Claim 10
Dependent Claim
23 words
An electrophotographic photoreceptor as claimed in claim 8, wherein the thickness of the charge transporting layer is from 5 μm to 20 μm.
Claim 11
Dependent Claim
78 words
An electrophotographic photoreceptor as claimed in claim 2, wherein the charge generating material is dispersed homogeneously or heterogeneously in a charge transporting medium comprising a charge transporting material and a binder and wherein the charge transporting material is from 10 to 150 weight percent with respect to the binder and further wherein the compound represented by the general formula (I) or (II) is contained in an amount of 1 to 150 weight percent with respect to the binder.
Claim 12
Dependent Claim
59 words
An electrophotographic photoreceptor as claimed in claim 10, wherein the charge transporting material is contained in an amount of 30 to 100 weight percent with respect to the weight of the binder and the compound represented by the general formula (I) or (II) is contained in an amount of 5 to 50 weight percent with respect to the binder.
Claim 13
Dependent Claim
41 words
An electrophotographic photoreceptor as claimed in claim 3, wherein the charge transporting material is contained in a binder and said charge transporting material is present in an amount of 10 to 150 weight percent based on the weight of the binder.
Claim 14
Dependent Claim
31 words
An electrophotographic photoreceptor as claimed in claim 12, wherein the charge transporting material is contained in an amount of 30 to 100 weight percent based on the weight of the binder.
Claim 15
Dependent Claim
49 words
An electrophotographic photoreceptor as claimed in claim 3, wherein the charge generating layer comprises the charge generating material dispersed in the binder present in an amount of 10 parts by weight or less per 1 part by weight of the compound represented by the general formula (I) or (II).
Claim 16
Dependent Claim
28 words
An electrophotographic photoreceptor as claimed in any of claims 1, 2, or 3, wherein a plurality of compounds represented by the general formula (I) or (II) are present.
Claim 17
Dependent Claim
17 words
An electrophotographic photoreceptor as claimed in any of claims 1, 2, or 3, further comprising sensitizer dyes.
Claim 18
Dependent Claim
25 words
An electrophotographic photoreceptor as claimed in claim 1, further comprising an adhesive layer or barrier layer positioned between the photoreceptive layer and the conductive surface.
Claim 19
Dependent Claim
24 words
An electrophotographic photoreceptor as claimed in claim 17, wherein the adhesive layer or the barrier layer has a thickness of 1 μm or less.
Claim 20
Dependent Claim
17 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the triphenylamine derivatives.
Claim 21
Dependent Claim
17 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the polyarylalkane derivatives.
Claim 22
Dependent Claim
17 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the pyrazoline derivatives.
Claim 23
Dependent Claim
17 words
An electrophotographic photoreceptor as claimed in claim 1, wherein said charge transporting material is the hydrazone derivatives.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-06-09 | 1989-12-09 | 1990-06-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-06-09 | 1993-12-09 | 1994-06-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-06-09 | 1997-12-09 | 1998-06-10 | $7700.00 | Window Closed / Lapsed |