Patent US4592993A successfully refreshed from Google Patents.
US4592993A
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Pattern forming and etching process using radiation sensitive negative resist
Assignee: NEC Corp
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Filing: 1985-10-15
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Granted: 1986-06-03
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Expires: 2005-10-15
Abstract
Abstract A process for fabrication of resist comprising a substrate and an overlying radiation sensitive layer, said overlying layer consisting essentially of a specific polymer or copolymer of vinylnaphthalene.
Inventors
- 👤 Yoshitake Ohnishi
- 👤 Takeshi Endo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 12:38
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/038
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
184 words
A pattern forming and etching process for use in microfabrication processes, said pattern and etching process comprising the steps of (A) selectively exposing an article comprising a substrate and an overlying radiation sensitive layer consisting essentially of a polymeric material to radiation to form a pattern in which the ease of removal of the irradiated portions of said overlying layer by a developing agent is decreased; (B) treating said overlying layer with said developing agent to selectively remove the unexposed portions thereof; and (C) dry etching the article with etching gases whereby said article surface corresponding to the removed portions of the patterned overlying layer are preferentially etched; characterized in that said polymeric material consists of a polymer which contains at least 50 percent by monomeric unit ratio of one or a combination of monomeric units selected from the group of: ##STR3## wherein said polymer has a weight average molecular weight M w within the range of 10,000 to 1,000,000 and wherein the polydispersivity of said polymer M w /M n , wherein M n is number average molecular weight, is less than 5.
Claim 2
Dependent Claim
184 words
A pattern forming and etching process for use in microfabrication processes, said pattern and etching process comprising the steps of (A) selectively exposing an article comprising a substrate and an overlying radiation sensitive layer consisting essentially of a polymeric material to radiation to form a pattern in which the ease of removal of the irradiated portions of said overlying layer by a developing agent is decreased; (B) treating said overlying layer with said developing agent to selectively remove the unexposed portions thereof; and (C) dry etching the article with etching gases whereby said article surface corresponding to the removed portions of the patterned overlying layer are preferentially etched; characterized in that said polymeric material consists of a polymer which contains at least 50 percent by monomeric unit ratio of one or a combination of monomeric units selected from the group of: ##STR3## wherein said polymer has a weight average molecular weight M w within the range of 10,000 to 1,000,000 and wherein the polydispersivity of said polymer M w /M n , wherein M n is number average molecular weight, is less than 5.
Claim 3
Dependent Claim
12 words
A process as claimed in claim 1, wherein the polymer comprises poly-2-vinylnaphthalene.
Claim 4
Dependent Claim
13 words
A process as claimed in claim 1, wherein the polymer comprises chloromethylated poly-2-vinylnaphthalene.
Claim 5
Dependent Claim
18 words
A process as claimed in claim 1, wherein the polymer comprises a copolymer of vinylnaphthalene and chloromethyl styrene.
Claim 6
Dependent Claim
17 words
A process as claimed in claim 1, wherein the polymer comprises a copolymer of vinylnaphthalene and chlorostyrene.
Claim 7
Dependent Claim
18 words
A process as claimed in claim 1, wherein the polymer comprises a copolymer of vinylnaphthalene and glycidyl methacrylate.
Claim 8
Dependent Claim
29 words
A process as claimed in claim 5 or 6 wherein the moiety of said vinylnaphthalene is equal to or greater than 50 percent in terms of monomeric unit ratio.
Claim 9
Dependent Claim
44 words
A process as claimed in claim 1, wherein the polydispersivity of the polymer M w /M n (M w /M n where M w denotes a weight average molecular weight; and M n , a number average molecular weight) is preferably less than 3.
Claim 10
Dependent Claim
25 words
A process as claimed in claim 4 wherein the moiety of said vinylnaphthalene is greater than about 80 percent in terms of monomeric unit ratio.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-06-02 | 1989-12-02 | 1990-06-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-06-02 | 1993-12-02 | 1994-06-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-06-02 | 1997-12-02 | 1998-06-03 | $7700.00 | Window Closed / Lapsed |