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US4592993A Expired / Lapsed US ⏱️ 0.0 years remaining

Pattern forming and etching process using radiation sensitive negative resist

Assignee: NEC Corp
•
Filing: 1985-10-15
•
Granted: 1986-06-03
•
Expires: 2005-10-15
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Abstract

Abstract A process for fabrication of resist comprising a substrate and an overlying radiation sensitive layer, said overlying layer consisting essentially of a specific polymer or copolymer of vinylnaphthalene.

Inventors

  • 👤 Yoshitake Ohnishi
  • 👤 Takeshi Endo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:35
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/038

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 184 words
A pattern forming and etching process for use in microfabrication processes, said pattern and etching process comprising the steps of (A) selectively exposing an article comprising a substrate and an overlying radiation sensitive layer consisting essentially of a polymeric material to radiation to form a pattern in which the ease of removal of the irradiated portions of said overlying layer by a developing agent is decreased; (B) treating said overlying layer with said developing agent to selectively remove the unexposed portions thereof; and (C) dry etching the article with etching gases whereby said article surface corresponding to the removed portions of the patterned overlying layer are preferentially etched; characterized in that said polymeric material consists of a polymer which contains at least 50 percent by monomeric unit ratio of one or a combination of monomeric units selected from the group of: ##STR3## wherein said polymer has a weight average molecular weight M w within the range of 10,000 to 1,000,000 and wherein the polydispersivity of said polymer M w /M n , wherein M n is number average molecular weight, is less than 5.
Claim 2
Dependent Claim 184 words
A pattern forming and etching process for use in microfabrication processes, said pattern and etching process comprising the steps of (A) selectively exposing an article comprising a substrate and an overlying radiation sensitive layer consisting essentially of a polymeric material to radiation to form a pattern in which the ease of removal of the irradiated portions of said overlying layer by a developing agent is decreased; (B) treating said overlying layer with said developing agent to selectively remove the unexposed portions thereof; and (C) dry etching the article with etching gases whereby said article surface corresponding to the removed portions of the patterned overlying layer are preferentially etched; characterized in that said polymeric material consists of a polymer which contains at least 50 percent by monomeric unit ratio of one or a combination of monomeric units selected from the group of: ##STR3## wherein said polymer has a weight average molecular weight M w within the range of 10,000 to 1,000,000 and wherein the polydispersivity of said polymer M w /M n , wherein M n is number average molecular weight, is less than 5.
Claim 3
Dependent Claim 12 words
A process as claimed in claim 1, wherein the polymer comprises poly-2-vinylnaphthalene.
Claim 4
Dependent Claim 13 words
A process as claimed in claim 1, wherein the polymer comprises chloromethylated poly-2-vinylnaphthalene.
Claim 5
Dependent Claim 18 words
A process as claimed in claim 1, wherein the polymer comprises a copolymer of vinylnaphthalene and chloromethyl styrene.
Claim 6
Dependent Claim 17 words
A process as claimed in claim 1, wherein the polymer comprises a copolymer of vinylnaphthalene and chlorostyrene.
Claim 7
Dependent Claim 18 words
A process as claimed in claim 1, wherein the polymer comprises a copolymer of vinylnaphthalene and glycidyl methacrylate.
Claim 8
Dependent Claim 29 words
A process as claimed in claim 5 or 6 wherein the moiety of said vinylnaphthalene is equal to or greater than 50 percent in terms of monomeric unit ratio.
Claim 9
Dependent Claim 44 words
A process as claimed in claim 1, wherein the polydispersivity of the polymer M w /M n (M w /M n where M w denotes a weight average molecular weight; and M n , a number average molecular weight) is preferably less than 3.
Claim 10
Dependent Claim 25 words
A process as claimed in claim 4 wherein the moiety of said vinylnaphthalene is greater than about 80 percent in terms of monomeric unit ratio.

References Cited (Backward Citations)

US3164575A Cited
US3162532A Cited
US3817957A Cited
US4208211A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-06-02 1989-12-02 1990-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-06-02 1993-12-02 1994-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-06-02 1997-12-02 1998-06-03 $7700.00 Window Closed / Lapsed

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