Patent US4588642A successfully refreshed from Google Patents.
US4588642A
Expired / Lapsed
US
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Thermoplastic fluorine-containing resin laminate
Assignee: Mitsubishi Chemical Corp
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Filing: 1984-05-09
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Granted: 1986-05-13
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Expires: 2004-05-09
Abstract
Abstract A laminate comprising a layer of a modified resin selected from the group consisting of (a) a resinous modified ethylene or vinyl acetate polymer or a polymer composition thereof containing a specific proportion of the vinyl acetate and (b) a resinous modified ethylene or alkyl acrylate polymer or a polymer composition thereof containing a specific proportion of the alkyl acrylate, and a layer of a thermoplastic fluorine-containing resin is disclosed. The laminate exhibits a high interfacial adhesion strength, while maintaining the advantages of the fluorine-containing resin.
Inventors
- 👤 Masahide Ochiumi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 04:33
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/30; B32B27/304; B32B27/306; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31855; Y10T428/31909; Y10T428/31928; Y10T428/31935
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
173 words
A laminate comprising a layer of the following modified resin(a) or (b) and a layer of a thermoplastic fluorine-containing resin, wherein: (a) is a resinous modified copolymer comprising an ethylene-vinyl acetate copolymer having vinyl acetate graft-copolymerized onto at least a part of the copolymer in an amount of at least 5 percent by weight based on the modified copolymer, wherein the total vinyl acetate content is 20 to 80 percent by weight based on the weight of the modified copolymer; (b) is a resinous modified copolymer comprising a copolymer selected from the group consisting of ethylene-lower alkyl acrylate copolymer, ethylene-lower alkyl methacrylate copolymer and the combination thereof, said copolymer having lower alkyl acrylate, lower alkyl methacrylate or a combination thereof graft-copolymerized onto at least a part of said copolymer in an amount of at least 5 percent by weight based on the weight of the modified copolymer, wherein the total lower alkyl acrylate and lower alkyl methacrylate content is 20 to 80 percent by weight based on the weight of the modified copolymer.
Claim 2
Dependent Claim
173 words
A laminate comprising a layer of the following modified resin(a) or (b) and a layer of a thermoplastic fluorine-containing resin, wherein: (a) is a resinous modified copolymer comprising an ethylene-vinyl acetate copolymer having vinyl acetate graft-copolymerized onto at least a part of the copolymer in an amount of at least 5 percent by weight based on the modified copolymer, wherein the total vinyl acetate content is 20 to 80 percent by weight based on the weight of the modified copolymer; (b) is a resinous modified copolymer comprising a copolymer selected from the group consisting of ethylene-lower alkyl acrylate copolymer, ethylene-lower alkyl methacrylate copolymer and the combination thereof, said copolymer having lower alkyl acrylate, lower alkyl methacrylate or a combination thereof graft-copolymerized onto at least a part of said copolymer in an amount of at least 5 percent by weight based on the weight of the modified copolymer, wherein the total lower alkyl acrylate and lower alkyl methacrylate content is 20 to 80 percent by weight based on the weight of the modified copolymer.
Claim 3
Dependent Claim
25 words
The laminate as claimed in claim 1, wherein the polymer is an ethylene-vinyl acetate copolymer which contains at least 15% by weight of vinyl acetate.
Claim 4
Dependent Claim
49 words
The laminate as claimed in claim 1 wherein the copolymer is selected from the group consisting of ethylene-lower alkyl acrylate copolymer, ethylene-lower alkyl methacrylate copolymer or the combination thereof, wherein the copolymer contains at least 15% by weight of lower alkyl acrylate, lower alkyl methacrylate or a combination thereof.
Claim 5
Dependent Claim
31 words
The laminate as claimed in claim 1, wherein the total vinyl acetate content in modified copolymer (a) is 25 to 65% by weight based on the weight of modified copolymer (a).
Claim 6
Dependent Claim
36 words
The laminate as claimed in claim 1, wherein the total lower alkyl acrylate and lower alkyl methacrylate content in modified copolymer (b) is 25 to 65% by weight based on the weight of modified copolymer (b).
Claim 7
Dependent Claim
29 words
The laminate as claimed in claim 1 wherein the lower alkyl acrylate and lower alkyl methacrylate are the methyl or ethyl esters of acrylic acid and methacrylic acid respectively.
Claim 8
Dependent Claim
22 words
The laminate as claimed in claim 1, wherein the modified copolymer (a) is further diluted with ethylene polymer or vinyl acetate polymer.
Claim 9
Dependent Claim
27 words
The laminate as claimed in claim 1, wherein the modified resin (b) is further diluted with ethylene polymer or lower alkyl acrylate or lower alkyl methacrylate polymer.
Claim 10
Dependent Claim
18 words
The laminate as claimed in claim 1, wherein the graft copolymerization is carved out by aqueous suspension grafting.
Claim 11
Dependent Claim
23 words
The laminate as claimed in claim 1, wherein the fluorine-containing resin is selected from the group consisting of polyvinyl fluoride and polyvinylidene fluoride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-05-12 | 1989-11-11 | 1990-05-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-05-12 | 1993-11-11 | 1994-05-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-05-12 | 1997-11-11 | 1998-05-13 | $7700.00 | Window Closed / Lapsed |