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US4587028A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-silicate antifreeze formulations

Assignee: Texaco Inc
•
Filing: 1984-10-15
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Granted: 1986-05-06
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Expires: 2004-10-15
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Abstract

Abstract Non-silicate, non-gelling corrosion inhibited antifreeze compositions containing a water-soluble liquid alcohol freezing point depressant and an inhibitor combination comprising an alkali metal salt of benzoic acid, an alkali metal salt of a dicarboxylic acid and an alkali metal nitrate are described. These formulations work just as well or better than silicate-based formulations in all regards and have the advantage of not having to contain expensive organo silane gellation inhibitors as do silicate-containing antifreezes. The dicarboxylic acid used preferably has eight to twelve carbon atoms.

Inventors

  • 👤 Jerome W. Darden

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 21:42
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/20

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 75 words
A non-silicate, non-gelling corrosion inhibited antifreeze composition comprising a water-soluble liquid alcohol freezing point depressant comprising ethylene glycol and an inhibitor combination comprising. a. about 2 to 5 percent of an alkali metal salt of benzoic acid, b. about 0.5 to 1.5 percent of an alkali metal salt of a dicarboxylic acid having eight to twelve carbon atoms, and c. about 0.1 to 0.5 percent of an alkali metal nitrate in the absence of silicates.
Claim 2
Dependent Claim 75 words
A non-silicate, non-gelling corrosion inhibited antifreeze composition comprising a water-soluble liquid alcohol freezing point depressant comprising ethylene glycol and an inhibitor combination comprising. a. about 2 to 5 percent of an alkali metal salt of benzoic acid, b. about 0.5 to 1.5 percent of an alkali metal salt of a dicarboxylic acid having eight to twelve carbon atoms, and c. about 0.1 to 0.5 percent of an alkali metal nitrate in the absence of silicates.
Claim 3
Dependent Claim 18 words
The antifreeze composition of claim 1 in which the alkali metal salt of benzoic acid is sodium benzoate.
Claim 4
Dependent Claim 18 words
The antifreeze composition of claim 1 in which the alkali metal salt of dicarboxylic acid is sodium sebacate.
Claim 5
Dependent Claim 15 words
The antifreeze composition of claim 1 in which the alkali metal nitrate is sodium nitrate.
Claim 6
Dependent Claim 32 words
The antifreeze composition of claim 1 in which at least one additional ingredient is present which is selected from the group consisting of alkali metal hydroxides, alkali metal nitrites and aromatic azoles.
Claim 7
Dependent Claim 36 words
A process for inhibiting the corrosion of metals which come in contact with an antifreeze composition, which comprises contacting the surface of the metal to be inhibited against corrosion with the antifreeze composition of claim 1.
Claim 8
Dependent Claim 55 words
A non-silicate corrosion inhibited antifreeze composition comprising a water-soluble liquid alcohol freezing point depressant comprising ethylene glycol and an inhibitor combination comprising: a. about 2 to 5 percent of sodium benzoate, b. about 0.5 to 1.5 percent of sodium sebacate, and c. about 0.1 to 0.5 percent of sodium nitrate in the absence of silicates.
Claim 9
Dependent Claim 55 words
A non-silicate corrosion inhibited antifreeze composition comprising a water-soluble liquid alcohol freezing point depressant comprising ethylene glycol and an inhibitor combination comprising: a. about 2 to 5 percent of sodium benzoate, b. about 0.5 to 1.5 percent of sodium sebacate, and c. about 0.1 to 0.5 percent of sodium nitrate in the absence of silicates.
Claim 10
Dependent Claim 32 words
The antifreeze composition of claim 7 in which at least one additional ingredient is present which is selected from the group consisting of alkali metal hydroxides, alkali metal nitrites and aromatic azoles.
Claim 11
Dependent Claim 36 words
A process for inhibiting the corrosion of metals which come in contact with an antifreeze composition, which comprises contacting the surface of the metal to be inhibited against corrosion with the antifreeze composition of claim 7.

References Cited (Backward Citations)

US4338209A Cited
US4242214A Cited
US4382008A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-05-05 1989-11-04 1990-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-05-05 1993-11-04 1994-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-05-05 1997-11-04 1998-05-06 $7700.00 Window Closed / Lapsed

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