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US4585632A
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US
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Process for the removal of nitrogen oxides from exhaust gases
Assignee: Sued Chemie AG
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Filing: 1984-12-14
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Granted: 1986-04-29
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Expires: 2004-12-14
Abstract
Abstract Process for the removal of nitrogen oxides from exhaust gases, in particular from exhaust gases containing sulfur oxides, by catalytic reduction. As a reduction agent a gas mixture obtained by catalytic conversion of methanol either by catalytic dissociation or by steam reforming is mixed with the exhaust gases and passed over a catalyst, wherein the nitrogen oxides are reduced to nitrogen. According to the first variant, one operates with conventional catalysts above 300° C., according to the second variant, with new catalysts below 300° C.
Inventors
- 👤 Michael Schneider
- 👤 Karel Kochloefl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 23:50
CPC Classifications
B; B01; B01J; B01J37/00; B01J37/02; B01J37/024; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9413; B01D53/9418; B01J23/00; B01J23/38; B01J23/40; B01J23/54; B01J23/56; B01J23/63; B01D2251/00; B01D2251/20; B01D2251/21; B01D2255/00; B01D2255/10; B01D2255/102; B01D2255/20; B01D2255/206; B01D2255/2063; B01D2255/2065; B01D2255/207; B01D2255/20707; B01D2255/20715; B01D2255/20761
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
93 words
Process for the removal of nitrogen oxides from exhaust gases, which comprises the steps of: A. passing methanol over a methanol conversion catalyst selected from the group consisting of catalytic noble metals supported on carriers comprising titanium dioxide, zirconium dioxide or cerium dioxide and a catalytic metal comprising copper oxide and producing a hydrogen-rich gas substantially free of methanol; B. passing said hydrogen-rich gas and exhaust gases containing nitrogen oxide over a supported noble metal nitrogen oxide reduction catalyst under conditions conductive to the reduction of nitrogen oxides to nitrogen and water vapor.
Claim 2
Dependent Claim
93 words
Process for the removal of nitrogen oxides from exhaust gases, which comprises the steps of: A. passing methanol over a methanol conversion catalyst selected from the group consisting of catalytic noble metals supported on carriers comprising titanium dioxide, zirconium dioxide or cerium dioxide and a catalytic metal comprising copper oxide and producing a hydrogen-rich gas substantially free of methanol; B. passing said hydrogen-rich gas and exhaust gases containing nitrogen oxide over a supported noble metal nitrogen oxide reduction catalyst under conditions conductive to the reduction of nitrogen oxides to nitrogen and water vapor.
Claim 3
Dependent Claim
60 words
Process according to claim 1, wherein said methanol conversion catalysts contain: a metal component from one or more elements of Group VIII of the periodic table on a support material comprising A TiO 2 or CeO 2 or B TiO 2 , which is applied on the surface of a preformed refractory material of Al 2 O 3 or ceramic.
Claim 4
Dependent Claim
22 words
Process according to claim 1, comprising the further step of adding steam to the methanol in a molar ratio of between 5-1:1.
Claim 5
Dependent Claim
25 words
Process according to claim 1, in which the conversion of methanol is carried out at temperatures in the range of about 400° to 600° C.
Claim 6
Dependent Claim
28 words
Process according to claim 1, in which the reduction of the nitrogen oxides is carried out at temperatures in the range of from about 300° to 500° C.
Claim 7
Dependent Claim
27 words
Process according to claim 1, wherein the noble metal of the nitrogen oxide reduction catalyst is selected from the group consisting of ruthenium, rhodium, platinum and palladium.
Claim 8
Dependent Claim
21 words
Process according to claim 6, wherein the noble metal is selected from the group consisting of ruthenium, rhodium, platinum and palladium.
Claim 9
Dependent Claim
46 words
Process according to claim 1, in which the nitrogen oxide reduction catalyst comprises: A. a noble metal selected from the group consisting of ruthenium, rhodium, palladium and platinum; B. a low surface area inert carrier substrate coated with a higher surface area layer of carrier material.
Claim 10
Dependent Claim
15 words
Process according to claim 8, in which said high surface area layer is gamma alumina.
Claim 11
Dependent Claim
14 words
Process according to claim 8, in which said high surface area layer is silica.
Claim 12
Dependent Claim
16 words
Process according to claim 8, in which said higher surface area layer is an aluminum silicate.
Claim 13
Dependent Claim
24 words
Process according to claim 8, in which said higher surface area layer also contains an oxide of the lanthanoide group of the Periodic Table.
Claim 14
Dependent Claim
31 words
Process according to claim 8, in which the low surface inert carrier substrate is selected from the group consisting of alpha aluminum oxide, titanium oxide, a ceramic material and aluminum-magnesium silicate.
Claim 15
Dependent Claim
39 words
Process according to claim 8, in which the inert carrier substrate has a specific surface of less than 50 m 2 /g and the proportion of pores of a diameter of more than 25 nm is more than 50%.
Claim 16
Dependent Claim
28 words
Process according to claim 8, in which the proportion of intermediate layer of higher surface area material in the total catalyst is about 0.1 to 15% by weight.
Claim 17
Dependent Claim
28 words
Process according to claim 8, in which the noble metal concentration of the catalyst is about 0.01 to 1 percent by weight, by reference to the total catalyst.
Claim 18
Dependent Claim
19 words
Process according to claim 8, in which the temperature for reduction of the nitrogen oxides is below 300° C.
Claim 19
Dependent Claim
28 words
Process according to claim 17, in which the reduction of the nitrogen oxides is carried out at a temperature in the range of from 180° to 300° C.
Claim 20
Dependent Claim
20 words
Process according to claim 1, in which the molar ratio of hydrogen and nitrogen oxides is about 10 to 2:1.
Claim 21
Dependent Claim
22 words
Process according to claim 2, wherein TiO 2 or CeO 2 of component A 1 are in admixture with a hydraulic binder.
Claim 22
Dependent Claim
23 words
Process according to claim 12, in which said oxide of the lanthanoide group of the periodic table is an oxide of a lanthanum.
References Cited (Backward Citations)
JPS5220971A
Cited
JPS5379762A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-04-28 | 1989-10-28 | 1990-04-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-04-28 | 1993-10-28 | 1994-04-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-04-28 | 1997-10-28 | 1998-04-29 | $7700.00 | Window Closed / Lapsed |