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Phenolic resin-containing aqueous compositions

Assignee: Dow Silicones Corp
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Filing: 1984-11-05
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Granted: 1986-04-22
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Expires: 2004-11-05
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Abstract

Abstract What is disclosed are aqueous compositions which are useful for coating solid substrates such as glass, plastic and metal. The aqueous compositions comprise colloidal silica, a phenolic resin, water and at least one hydrolyzable silane. An example of such a composition is colloidal silica, phenolic resin, water and CH3SiO3/2 obtained from CH3Si(OCH3)3.

Inventors

  • 👤 Frank K. Chi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 10:58
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K3/36; C09; C09D; C09D183/00; C09D183/04

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 103 words
An aqueous composition comprising (A) 100 parts by weight phenolic resin; (B) 1 to 100 parts by weight of colloidal silica; (C) 1 to 100 parts by weight of a partial condensate, or a mixture of partial condensates, from silanes having the general formula RSi(OR') 3 wherein R' is methyl or ethyl and R is independently selected from a group consisting of (i) alkyl radicals having 1 to 3 inclusive carbon atoms; (ii) the CH 2 ═CH-- radical; (iii) the C 6 H 5 -- radical; (iv) substituted alkyl radicals having the formulae ##STR14## (D) 450 to 1900 parts by weight of water.
Claim 2
Dependent Claim 103 words
An aqueous composition comprising (A) 100 parts by weight phenolic resin; (B) 1 to 100 parts by weight of colloidal silica; (C) 1 to 100 parts by weight of a partial condensate, or a mixture of partial condensates, from silanes having the general formula RSi(OR') 3 wherein R' is methyl or ethyl and R is independently selected from a group consisting of (i) alkyl radicals having 1 to 3 inclusive carbon atoms; (ii) the CH 2 ═CH-- radical; (iii) the C 6 H 5 -- radical; (iv) substituted alkyl radicals having the formulae ##STR14## (D) 450 to 1900 parts by weight of water.
Claim 3
Dependent Claim 20 words
An aqueous composition as claimed in claim 1 wherein the partial condensate has the formula CH 3 SiO 3/2 .
Claim 4
Dependent Claim 22 words
An aqueous composition as claimed in claim 1 wherein the partial condensate has the formula C 6 H 5 SiO 3/2 .
Claim 5
Dependent Claim 20 words
An aqueous composition as claimed in claim 1 wherein the partial condensate has the formula CH 2 ═CHSiO 3/2 .
Claim 6
Dependent Claim 25 words
An aqueous composition as claimed in claim 1 wherein the partial condensate has the general formula R'"SiO 3/2 wherein R'" is a substituted alkyl radical.
Claim 7
Dependent Claim 20 words
An aqueous composition as claimed in claim 5 wherein R'" is --CH 2 CH 2 CH 2 NH 2 .
Claim 8
Dependent Claim 24 words
An aqueous composition as claimed in claim 5 wherein R'" is --CH 2 CH 2 CH 2 NHCH 2 CH 2 NH 2 .
Claim 9
Dependent Claim 18 words
An aqueous composition as claimed in claim 5 wherein R'" is --CH 2 CH 2 CH 2 SH.
Claim 10
Dependent Claim 18 words
An aqueous composition as claimed in claim 5 wherein R'" is --CH 2 CH 2 CH 2 Cl.
Claim 11
Dependent Claim 12 words
An aqueous composition as claimed in claim 5 wherein R'" is ##STR15##
Claim 12
Dependent Claim 12 words
An aqueous composition as claimed in claim 5 wherein R'" is ##STR16##
Claim 13
Dependent Claim 18 words
An aqueous composition as claimed in claim 5 wherein R'" is --CH 2 CH 2 CF 3 .
Claim 14
Dependent Claim 21 words
An aqueous composition as claimed in claim 2 wherein the partial condensate is a mixture and the mixture consists of ##STR17##
Claim 15
Dependent Claim 17 words
An aqueous composition as claimed in claim 13 wherein the ratio of ##STR18## is 1:4 to 1:0.063.
Claim 16
Dependent Claim 40 words
An aqueous composition as claimed in claim 2 wherein the partial condensate is a mixture and the mixture consists of CH 3 SiO 3/2 and H 2 NCH 2 CH 2 NHCH 2 CH 2 CH 2 SiO 3/2 .
Claim 17
Dependent Claim 33 words
An aqueous composition as claimed in claim 15 wherein the ratio of CH 3 SiO 3/2 to H 2 N(CH 2 ) 2 NH(CH 2 ) 3 SiO 3/2 is 1:11 to 1:0.015.
Claim 18
Dependent Claim 14 words
An aqueous composition as claimed in claim 1 wherein there is present a catalyst.
Claim 19
Dependent Claim 15 words
An aqueous composition as claimed in claim 17 wherein the catalyst is a condensation catalyst.
Claim 20
Dependent Claim 15 words
A solid substrate coated with the composition of claim 17 and the composition is cured.
Claim 21
Dependent Claim 14 words
An article coated with the composition of claim 17 and the composition is cured.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-21 1989-10-21 1990-04-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-21 1993-10-21 1994-04-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-21 1997-10-21 1998-04-22 $7700.00 Window Closed / Lapsed

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