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US4584151A
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Method of producing a polycrystalline transparent spinel sintered body
Assignee: NGK Insulators Ltd
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Filing: 1985-07-15
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Granted: 1986-04-22
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Expires: 2005-07-15
Abstract
Abstract The disclosed polycrystalline transparent sintered body contains Al 2 O 3 and MgO at a molar ratio of (0.54:0.46) to (0.58:0.42) and has in-line transmittance of more than 77% for 1 mm thickness at a light wavelength of 0.6 μm, which sintered body is produced by preparing fine spinel powder through hydrolysis of an isopropanol solution of aluminum isopropoxide and magnesium isopropoxide, forming a shaped body from the powder, and sintering the shaped body.
Inventors
- 👤 Minoru Matsui
- 👤 Tomonori Takahashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 14:15
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/44; C04B35/443; C01; C01F; C01F7/00; C01F7/02; C01F7/34; C01F7/36; C04B35/622; C04B35/626; C04B35/62605; C04B35/6261; C04B35/6262; C04B2235/00; C04B2235/02; C04B2235/30; C04B2235/32; C04B2235/3201; C04B2235/3203; C04B2235/3205; C04B2235/3208; C04B2235/3217; C04B2235/3222; C04B2235/44; C04B2235/441; C04B2235/444; C04B2235/445; C04B2235/50; C04B2235/54; C04B2235/5409; C04B2235/65; C04B2235/656; C04B2235/6562; C04B2235/6567; C04B2235/658; C04B2235/6582; C04B2235/70; C04B2235/74; C04B2235/79; C04B2235/80; C04B2235/96; C04B2235/9646; C04B2235/9653; Y; Y10; Y10S; Y10S264/00; Y10S264/91
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
83 words
A method of producing a polycrystalline transparent spinel sintered body, comprising the steps of preparing an isopropanol solution of aluminum isopropoxide and magnesium isopropoxide, generating precipitates by hydrolysis of the isopropanol solution, heating the precipitates so as to form fine spinel powder consisting essentially of Al 2 O 3 and MgO in a molar ratio of (0.502:0.498) to (0.524:0.476), forming a shaped body from the spinel powder, and firing the shaped body at a temperature higher than 1,700° C. in a hydrogen atmosphere.
Claim 2
Independent Claim
83 words
A method of producing a polycrystalline transparent spinel sintered body, comprising the steps of preparing an isopropanol solution of aluminum isopropoxide and magnesium isopropoxide, generating precipitates by hydrolysis of the isopropanol solution, heating the precipitates so as to form fine spinel powder consisting essentially of Al 2 O 3 and MgO in a molar ratio of (0.502:0.498) to (0.524:0.476), forming a shaped body from the spinel powder, and firing the shaped body at a temperature higher than 1,700° C. in a hydrogen atmosphere.
Claim 3
Dependent Claim
32 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said hydrolysis occurs at a temperature which is close to the boiling point of isopropanol.
Claim 4
Dependent Claim
32 words
A method of producing a polycrystalline transparent spinel sintered sintered body as set forth in claim 1, wherein lithium fluoride (LiF) is added to said fine spinel powder as a sintering aid.
Claim 5
Dependent Claim
43 words
A method of producing a polycrystalline transparent spinel body as set forth in claim 3, wherein lithium fluoride (LiF) is dissolved in water and an aqueous solution of lithium fluoride (LiF) thus prepared is added to said isopropanol solution for effecting the hydrolysis.
Claim 6
Dependent Claim
35 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 3, wherein 0.05-15% by weight of said lithium fluoride (LiF) is added to said spinel powder as a sintering aid.
Claim 7
Dependent Claim
26 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said hydrolysis is effected while refluxing said isopropanol solution.
Claim 8
Dependent Claim
27 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said heating of the precipitates is effected at 900°-1,100° C.
Claim 9
Dependent Claim
29 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said firing of the shaped body occurs for more than ten hours.
Claim 10
Dependent Claim
44 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said firing of the shaped body is effected by raising temperature thereof at a rate of less than 50° C./hour in a temperature range of 800°-1,400° C.
Claim 11
Dependent Claim
33 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said precipitates formed by the hydrolysis are dried by heating at a temperature below 120° C.
Claim 12
Dependent Claim
36 words
A method of producing a polycrystalline transparent spinel sintered body as set forth in claim 1, wherein said precipitates formed by the hydrolysis are heated in an oxidizing atmosphere at 900°-1,100° C. to effect crystallization thereof.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-04-21 | 1989-10-21 | 1990-04-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-04-21 | 1993-10-21 | 1994-04-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-04-21 | 1997-10-21 | 1998-04-22 | $7700.00 | Window Closed / Lapsed |