US4582884A
Expired / Lapsed
US
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Lens composition, article and method of manufacture
Assignee: Barnes Hind Inc
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Filing: 1984-08-31
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Granted: 1986-04-15
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Expires: 2004-08-31
Abstract
Abstract A copolymer composition, especially suited for fabricating optical lenses comprising a copolymer of copolymerized comonomers which include about one to about 25 percent by weight of an acryloxyalkylsilanol; about 0.5 to about 15 percent by weight of a polyacryloxyalkylpolysiloxane; about 5 to about 60 percent by weight of an siloxy substituted ester of acrylic or methacrylic acid; and from about 35 to about 90 percent by weight of an acrylic or methacrylic ester of an alkanol having from one to twenty carbon atoms. Contact lenses and contact lens buttons are formed of such copolymer of copolymerized comonomers by conventional techniques, by injection molding, and by compression molding.
Inventors
- 👤 Donald J. Ratkowski
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 16:05
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
190 words
A copolymer composition, especially suited for fabricating optical lenses, comprising a copolymer of copolymerized comonomers containing: (a) about one to about twenty-five percent by weight of an acryloxyalkylsilanol having the structure ##STR7## wherein R=CH 3 -- or H--; X, Y=C 1 -C 6 alkyl; phenyl or Z ##STR8## n=1-5; m=1-3 R1=C 1 -C 6 alkyl, or phenyl R2=C 1 -C 6 alkyl, or phenyl R3=C 1 -C 6 alkyl, or phenyl (b) about 0.5 to about fifteen percent by weight of a polyacryloxyalkylpolysiloxane having the structure ##STR9## Wherein: R=CH 3 -- or H--; m=0-3 n=1-5 ##STR10## R1=C 1 -C 6 alkyl, or phenyl; R2=C 1 -C 6 alkyl, or phenyl; and R3=C 1 -C 6 alkyl, or phenyl; (c) about 5 to about 60 percent by weight of a siloxy substituted ester of acrylic or methacrylic acid having the structure: ##STR11## Wherein R=CH 3 -- or H--; X=C 1 -C 6 alkyl, phenyl or Z Y=C 1 -C 6 alkyl, phenyl or Z ##STR12## and (d) about 35 to about 90 percent by weight of an acrylic or methacrylic ester of an alkanol having from one to 20 carbon atoms.
Claim 2
Dependent Claim
190 words
A copolymer composition, especially suited for fabricating optical lenses, comprising a copolymer of copolymerized comonomers containing: (a) about one to about twenty-five percent by weight of an acryloxyalkylsilanol having the structure ##STR7## wherein R=CH 3 -- or H--; X, Y=C 1 -C 6 alkyl; phenyl or Z ##STR8## n=1-5; m=1-3 R1=C 1 -C 6 alkyl, or phenyl R2=C 1 -C 6 alkyl, or phenyl R3=C 1 -C 6 alkyl, or phenyl (b) about 0.5 to about fifteen percent by weight of a polyacryloxyalkylpolysiloxane having the structure ##STR9## Wherein: R=CH 3 -- or H--; m=0-3 n=1-5 ##STR10## R1=C 1 -C 6 alkyl, or phenyl; R2=C 1 -C 6 alkyl, or phenyl; and R3=C 1 -C 6 alkyl, or phenyl; (c) about 5 to about 60 percent by weight of a siloxy substituted ester of acrylic or methacrylic acid having the structure: ##STR11## Wherein R=CH 3 -- or H--; X=C 1 -C 6 alkyl, phenyl or Z Y=C 1 -C 6 alkyl, phenyl or Z ##STR12## and (d) about 35 to about 90 percent by weight of an acrylic or methacrylic ester of an alkanol having from one to 20 carbon atoms.
Claim 3
Dependent Claim
20 words
A composition according to claim 1 in which an additional crosslinking monomer is incorporated into said copolymer of copolymerized comonomers.
Claim 4
Dependent Claim
24 words
A composition according to claim 2 in which said additional crosslinking monomer is an acrylic ester of a C 1 -C 20 alkyl polyol.
Claim 5
Dependent Claim
31 words
The composition according to claim 3 in which said additional crosslinking monomer is present in an amount equal to about one percent to about twelve percent by weight of said copolymer.
Claim 6
Dependent Claim
23 words
The composition according to claim 4 in which said crosslinking monomer is selected from the group consisting of ethylene glycoldimethacrylate and butylene glycoldimethacrylate.
Claim 7
Dependent Claim
18 words
A composition according to claim 2 in which a hydrophilic monomer is incorporated into said copolymer of comonomers.
Claim 8
Dependent Claim
30 words
A composition according to claim 6 in which said hydrophilic monomer is present in an amount equal to about two percent to about fourteen percent by weight of said copolymer.
Claim 9
Dependent Claim
51 words
A composition according to claim 2 in which a hydrophilic monomer is incorporated into said copolymer of comonomers in an amount equal to about two percent to about fourteen percent by weight of said copolymer, said hydrophilic monomer being selected from the group consisting of methacrylic acid, acrylic acid and acrylamide.
Claim 10
Dependent Claim
19 words
A composition according to claim 1 in which a hydrophilic monomer is incorporated into said copolymer of copolymerized comonomers.
Claim 11
Dependent Claim
30 words
A composition according to claim 9 in which said hydrophilic monomer is present in an amount equal to about two percent to about twelve percent by weight of said copolymer.
Claim 12
Dependent Claim
52 words
A composition according to claim 1 in which a hydrophilic monomer is incorporated into said copolymer of copolymerized comonomers in an amount equal to about two percent to about twelve percent by weight of said copolymer, said hydrophilic monomer being selected from the group consisting of methacrylic acid, acrylic acid and acrylamide.
Claim 13
Dependent Claim
19 words
A composition according to claim 2 in which an initiator is incorporated into said comonomer mixture prior to polymerization.
Claim 14
Dependent Claim
29 words
A composition according to claim 12 in which said initiator is present in an amount equal to about 0.1 to about 1.0 percent by weight of said comonomer mixture.
Claim 15
Dependent Claim
31 words
A composition according to claim 13 in which said initiator is selected from the group consisting of di(2-phenyloxyethyl)peroxy dicarbonate, α,α'-azobisiso-butyronitrile, and a mixture of methyl ethyl ketone peroxide and cobalt naphthenate.
Claim 16
Dependent Claim
19 words
A composition according to claim 9 in which an initiator is incorporated into said comonomer mixture prior to polymerization.
Claim 17
Dependent Claim
29 words
A composition according to claim 15 in which said initiator is present in an amount equal to about 0.1 to about 1.0 percent by weight of said comonomer mixture.
Claim 18
Dependent Claim
31 words
A composition according to claim 16 in which said initiator is selected from the group consisting of di(2-phenyloxyethyl)peroxy dicarbonate, α,α'-azobisiso-butyronitrile, and a mixture of methyl ethyl ketone peroxide and cobalt naphthenate.
Claim 19
Dependent Claim
94 words
A composition according to claim 1 containing as comonomers prior to polymerization from about 2 to about 8 percent by weight of a hydrophilic monomer selected from the group consisting of methacrylic acid, acrylic acid and acrylamide; from about 3 to about 8 percent by weight of a crosslinker selected from the group consisting of ethylene glycol dimethacrylate and butylene glycol dimethacrylate; and from 0.1 to about 0.5 percent by weight of an initiator selected from the group consisting of di(2-phenyloxyethyl)-peroxy dicarbonate; α,α'-azobisisobutyronitrile, and a mixture of methyl ethyl ketone peroxide and cobalt naphthenate.
Claim 20
Dependent Claim
21 words
A composition according to claim 18 in which said initiator is a mixture of methyl ethyl ketone peroxide and cobalt naphthenate.
Claim 21
Dependent Claim
12 words
A composition according to claim 18 in which said initiator is α,α'-azobisisobutyronitrile.
Claim 22
Dependent Claim
14 words
A composition according to claim 18 in which said crosslinker is ethylene glycol dimethacrylate.
Claim 23
Dependent Claim
19 words
As a new article of manufacture, an optical lens fabricated from the copolymer of copolymerized comonomers of claim 1.
Claim 24
Dependent Claim
12 words
An article of manufacture according to claim 22 comprising a contact lens.
Claim 25
Dependent Claim
20 words
As a new article of manufacture, a contact lens button fabricated from the copolymer of copolymerized comonomers of claim 1.
Claim 26
Dependent Claim
16 words
As a new article of manufacture, a contact lens formed from the button of claim 24.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-04-14 | 1989-10-14 | 1990-04-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-04-14 | 1993-10-14 | 1994-04-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-04-14 | 1997-10-14 | 1998-04-15 | $7700.00 | Window Closed / Lapsed |