Polymer for contact lens and contact lens made thereof

Claim 2

A polymerization product consisting essentially of: (a) 30% to 95% of an organosiloxane monomer having the following general formula: ##STR19## wherein: n is an integer of 1 to 3; X is --(CH 2 ) p --O] q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of a hydrophobic methacrylic acid alkyl ester monomer, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b).

Claim 3

The polymerization product of claim 1, wherein said organosiloxane monomer is a compound having the following general formula (II): ##STR20## wherein n is an integer of 1 to 3, and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 .

Claim 4

The polymerization product of claim 1, wherein said organosiloxane monomer is a compound having the following general formula (III): ##STR21## wherein n is an integer of 1 to 3, p is an integer of 2 to 4, and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 .

Claim 5

The polymerization product of claim 1, wherein said organosiloxane monomer is a compound having the following general formula (IV): ##STR22## wherein n is an integer of 1 to 3, p is an integer of 2 to 4, q' is 2 or 3, and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 .

Claim 6

The polymerization product of claim 1, having an oxygen permeability of 2.5×10 -10 to 43×10 -10 ml.cm./cm. 2 sec.cmHg, a refractive index of n D 25 =1.40 to 1.50, a specific gravity of d 4 20 =1.01 to 1.21, a visible ray percent transmission of not less than 90% and a Vickers hardness number of 1.5 to 19.0.

Claim 7

A polymerization product prepared by a process consisting essentially of polymerizing, in the presence of 0.5 to 25 parts of a cross-linking agent: (a) 30% to 95% of an organosiloxane monomer having the following general formula (I): ##STR23## wherein: n is an integer of 1 to 3; X is --(CH 2 ) p --O-- q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of a hydrophobic methacrylic acid alkyl ester monomer, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b), said parts of the cross-linking agent being parts by weight per 100 parts by weight of component (a) plus component (b).

Claim 8

A polymerization product prepared by a process consisting essentially of polymerizing, in the presence of 0.5 to 25 parts of a cross-linking agent: (a) 30% to 95% of an organosiloxane monomer having the following general formula (I): ##STR23## wherein: n is an integer of 1 to 3; X is --(CH 2 ) p --O-- q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of a hydrophobic methacrylic acid alkyl ester monomer, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b), said parts of the cross-linking agent being parts by weight per 100 parts by weight of component (a) plus component (b).

Claim 9

The polymerization product of claim 6 wherein said cross-linking agent is employed in an amount of 1 to 20 parts by weight per 100 parts by weight of the components (a) and (b).

Claim 10

The polymerization product of claim 6, wherein said cross-linking agent is at least one polyfunctional monomer selected from the group consisting of ethylene glycol diacrylate, ethylene glycol dimethacrylate, diethylene glycol diacrylate, diethyl glycol dimethacrylate, triethylene glycol diacrylate, triethylene glycol dimethacrylate, allyl methacrylate, trimethylolpropane trimethacrylate, divinyl benzene, diallyl phthalate, compounds having the following general formula (V): ##STR24## wherein n and n' are an integer of 1 to 3, m is 1 or 2, and R 1 and R 2 are hydrogen or methyl, and compounds having the following general formula (VI): ##STR25## wherein n and n' are an integer of 1 to 3, m is 1 or 2, and R 1 and R 2 are hydrogen or methyl.

Claim 11

A contact lens made of a copolymer consisting essentially of: (a) 30% to 95% of organosiloxane monomer units having the following general formula (I): ##STR26## wherein: n is an integer of 1 to 3; X is --(CH 2 ) p --O-- q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of hydrophobic methacrylic acid alkyl ester monomer units, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b).

Claim 12

A contact lens made of a copolymer consisting essentially of: (a) 30% to 95% of organosiloxane monomer units having the following general formula (I): ##STR26## wherein: n is an integer of 1 to 3; X is --(CH 2 ) p --O-- q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of hydrophobic methacrylic acid alkyl ester monomer units, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b).

Claim 13

A contact lens made of a copolymer consisting essentially of: (a) 30% to 95% of organosiloxane monomer units having the following general formula (I): ##STR27## wherein: n is an integer of 1 to 3; X is [(CH 2 ) p --O] q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of hydrophobic methacrylic acid alkyl ester monomer units, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b), wherein said copolymer further contains units of a cross-linking agent in a weight ratio of 0.5 to 25 against 100 of the components (a) and (b), said cross-linking agent being at least one polyfunctional monomer selected from the group consisting of ethylene glycol diacrylate, ethylene glycol dimethacrylate, diethylene glycol diacrylate, diethylene glycol dimethacrylate, triethylene glycol diacrylate, triethylene glycol dimethacrylate, allyl methacrylate, trimethylolpropane trimethacrylate, divinyl benzene, diallyl phthalate, compounds having the following general formula (V): ##STR28## wherein: n and n' are an integer of 1 to 3; m is 1 or 2; and R 2 and R 2 are hydrogen or methyl, and compounds having the following general formula (VI): ##STR29## wherein: n and n' are an integer of 1 to 3; m is 1 or 2; and R 1 and R 2 are hydrogen or methyl.

Claim 14

A contact lens made of a copolymer consisting essentially of: (a) 30% to 95% of organosiloxane monomer units having the following general formula (I): ##STR27## wherein: n is an integer of 1 to 3; X is [(CH 2 ) p --O] q in which p is an integer of 2 to 4 and q is 0 or an integer of 1 to 3; and Y 1 , Y 2 and Y 3 are methyl or --O--Si--(CH 3 ) 3 ; and (b) 70% to 5% of hydrophobic methacrylic acid alkyl ester monomer units, wherein said hydrophobic methacrylic acid alkyl ester monomer is at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate and cyclohexyl methacrylate, said % of (a) and (b) being % by weight based on the total weight of (a) and (b), wherein said copolymer further contains units of a cross-linking agent in a weight ratio of 0.5 to 25 against 100 of the components (a) and (b), said cross-linking agent being at least one polyfunctional monomer selected from the group consisting of ethylene glycol diacrylate, ethylene glycol dimethacrylate, diethylene glycol diacrylate, diethylene glycol dimethacrylate, triethylene glycol diacrylate, triethylene glycol dimethacrylate, allyl methacrylate, trimethylolpropane trimethacrylate, divinyl benzene, diallyl phthalate, compounds having the following general formula (V): ##STR28## wherein: n and n' are an integer of 1 to 3; m is 1 or 2; and R 2 and R 2 are hydrogen or methyl, and compounds having the following general formula (VI): ##STR29## wherein: n and n' are an integer of 1 to 3; m is 1 or 2; and R 1 and R 2 are hydrogen or methyl.

Claim 15

The contact lens of claim 9 or 10, wherein said copolymer has an oxygen permeability of 2.5×10 -10 to 43×10 -10 ml.cm./cm. 2 sec.cmHg, a refractive index of n D 25 =1.40 to 1.50, a specific gravity of d 4 20 =1.01 to 1.21, a visible ray percent transmission of not less than 90% and a Vickers hardness number of 1.5 to 19.0.