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US4582556A Expired / Lapsed US ⏱️ 0.0 years remaining

Adhesion primers for encapsulating epoxies

Assignee: Olin Corp
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Filing: 1984-05-31
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Granted: 1986-04-15
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Expires: 2004-05-31
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Abstract

Abstract A copper plastic laminate is provided having a high bond strength. The copper is selected from the group consisting of copper and copper alloys and has on its surface a uniform glassy-like, substantially pore-free coating of copper phosphate. A plastic encapsulating material containing a mold release agent is adhesively bonded to the copper.

Inventors

  • 👤 Sheldon H. Butt
  • 👤 Edward F. Smith, III
  • 👤 F. Dennis Gyurina

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:02
CPC Classifications
H; H10; H10W; H10W74/00; H10W74/40; H10W74/47; H05; H05K; H05K3/00; H05K3/38; H05K3/382; H05K3/385; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49117; Y10T29/49121; Y10T428/00; Y10T428/31504; Y10T428/31511

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 81 words
A process of forming a metal plastic composite, comprising the steps of: a. selecting said metal from the group consisting of copper and copper alloys; b. coating the surface of said metal with an adhesion primer comprising a substantially glassy-like, pore-free phosphate coating; c. rinsing said metal; d. drying said metal; and e. adhesively bonding a plastic material comprising an epoxide resin and a mold release agent to the surface of the copper or copper alloy metal having said adhesion primer.
Claim 2
Dependent Claim 81 words
A process of forming a metal plastic composite, comprising the steps of: a. selecting said metal from the group consisting of copper and copper alloys; b. coating the surface of said metal with an adhesion primer comprising a substantially glassy-like, pore-free phosphate coating; c. rinsing said metal; d. drying said metal; and e. adhesively bonding a plastic material comprising an epoxide resin and a mold release agent to the surface of the copper or copper alloy metal having said adhesion primer.
Claim 3
Dependent Claim 24 words
The process as in claim 1 including the step of selecting said plastic material from an epoxide resin formulated as a thermosetting encapsulating epoxy.
Claim 4
Dependent Claim 21 words
The process as in claim 1 including the step of adding inert fillers to said plastic material to provide dimensional stability.
Claim 5
Dependent Claim 23 words
The process as in claim 3 including the step of selecting said mold release agent from a group of low melting temperature organics.
Claim 6
Dependent Claim 25 words
The process as in claim 4 including the step of selecting said mold release agent from the group consisting of silicones, stearates and fatty acids.
Claim 7
Dependent Claim 17 words
The process as in claim 2 further including the step of forming said metal into a leadframe.
Claim 8
Dependent Claim 29 words
The process as in claim 6 further including the step of connecting an electrical or electronic component to said leadframe, whereby said component is encapsulated by said epoxide resin.
Claim 9
Dependent Claim 91 words
The process as in claim 1 wherein said step of coating the surface of said metal includes immersing said metal in a phosphoric acid solution of at least 8 percent concentration and containing from 3.5 grams per liter up to the solubility limit of a material selected from the group consisting of sodium dichromate and potassium dichromate and mixtures thereof for at least 2 seconds to form a substantially pore-free coating of copper phosphate, provided that when the concentration of phosphoric acid is increased, the minimum dichromate concentration is proportionately increased.
Claim 10
Dependent Claim 46 words
The process as in claim 1 wherein the coating step includes immersing said metal in a solution containing an organophosphonic acid and a chromate free oxidizing agent for at least 4 seconds to coat the surface of said metal with a compound of said organophosphonic acid.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-14 1989-10-14 1990-04-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-14 1993-10-14 1994-04-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-14 1997-10-14 1998-04-15 $7700.00 Window Closed / Lapsed

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