Zeolite EU-7

Claim 2

A crystalline zeolite material, EU-7, having a molar composition (in terms of mole ratios of oxides) expressed by the formula: 0.5 to 2.5 R.sub.2 O:Y.sub.2 O.sub.3 :at least 20 XO.sub.2 :0 to 600 H.sub.2 O wherein R is a monovalent cation or 1/n of a cation of valency n, X is silicon and/or germanium, Y is one or more aluminum, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium or boron, and H 2 O is water of hydration additional to water notionally present when R is H, and having an X-ray powder diffraction pattern as set out in Table 1 (as determined by standard technique using copper Kα-radiation) and as shown in FIG. 1.

Claim 3

A crystalline zeolite material, EU-7, as claimed in claim 1 wherein the molar composition is expressed by the formula: 0.5 to 2.5 R.sub.2 O:Y.sub.2 O.sub.3 :20 to 5000 XO.sub.2 :0 to 600 H.sub.2 O.

Claim 4

A crystalline zeolite material, EU-7, as claimed in claim 1 wherein R is or includes an alkali metal cation, ammonium, hydrogen or a nitrogen-containing organic cation.

Claim 5

A crystalline zeolite material, EU-7, as claimed in claim 1 having, as freshly made, a molar composition expressed by the formula 0.5 to 2.5 M.sub.2 O:0 to 150A:Y.sub.2 O.sub.3 :20 to 5000 XO.sub.2 :0 to 300 H.sub.2 O where M is an alkali metal, selected from caesium and rubidium ammonium or hydrogen and A is nitrogen-containing organic cation.

Claim 6

A method of making the crystalline zeolite material, EU-7 as defined in claim 1, which comprises forming an aqueous mixture containing sources of at least one oxide XO 2 , at least one oxide Y 2 O 3 and optionally at least one organic compound selected from (a) cyclic amines with 1 to 3 nitrogen atoms in the molecule and with a total of 1 to 10 carbon atoms per nitrogen atom; (b) α-ω alkane diamines having 1 to 4 carbon atoms per nitrogen atom; (c) α-ω alkane diols having 1 to 4 carbon atoms per hydroxyl group; and (d) mixtures of compounds selected from groups (a), (b) and/or (c), the reaction mixture having the molar composition: XO 2 /Y 2 O 3 in the range 20 to 5000 M 1 OH/XO 2 in the range 0.08 to 0.7 H 2 O/XO 2 in the range 5 to 170 A/XO 2 in the range 0 to 1 M 2 Z/XO 2 in the range 0 to 1 wherein each of M 1 and M 2 represents an alkali metal selected from caesium and rubidium, ammonium or hydrogen, A represents the organic compound, X is selected from silicon and germanium, and Y is one or more of aluminum, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium or boron, and Z is an acid radical; maintaining the mixture at a temperature of 80°-250° C. until crystals of EU-7 form; and recovering EU-7 zeolite material.

Claim 7

A method as claimed in claim 5 wherein the reaction mixture has a molar composition in which XO 2 /Y 2 O 3 is in the range 30 to 120 M 1 OH/XO 2 is in the range 0.15 to 0.50 H 2 O/XO 2 is in the range 15 to 85 A/XO 2 is in the range 0.08 to 0.5 M 2 Z/XO 2 is in the range 0.08 to 0.33.

Claim 8

A method as claimed in claim 5 in which the organic compound is selected from hexane-1,6-diamine, butane-1,4-diamine, ethylene diamine, hexane-1,6-diol and ethylene glycol.

Claim 9

A method as claimed in claim 5 in which M 1 and M 2 are caesium.

Claim 10

A catalyst comprising zeolite EU-7 as defined in claim 1.

Claim 11

A method of making crystalline zeolite material, EU-7, as defined in claim 1 which comprises forming an aqueous mixture containing sources of at least one oxide XO 2 , at least one oxide Y 2 O 3 , optionally a diamine selected from butane-1,4-diamine; ethylene-diamine; octane-1, 8-diamine; dodecane-1, 2-diamine; and hexane-1, 6-diamine, the reaction mixture having the molar composition: XO 2 /Y 2 O 3 in the range 20 to 5000, preferably 30 to 120 M 1 OH/XO 2 in the range 0.08 to 0.7, preferably 0.15 to 0.50 H 2 O/XO 2 in the range 5 to 170, preferably 15 to 85 A/XO 2 in the range 0 to 1 M 2 Z/XO 2 in the range 0 to 1, preferably 0.08 to 0.33 wherein M 1 and M 2 is an alkali metal selected from caesium or rubidium, A represents the diamine, X is one or more of silicon and germanium, and Y is one or more of aluminum, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium and boron, and Z is an acid radical; maintaining the mixture at a temperature of 80°-250° C. until crystals of EU-7 form; and recovering EU-7 zeolite material.

Claim 12

A method of making crystalline zeolite material, EU-7, as defined in claim 1, which comprises reacting at 150° to 180° C., an aqueous mixture containing sources of SiO 2 and Al 2 O 3 , a diamine selected from butane-1, 4-diamine; ethylene-diamine; octane-1, 8-diamine; dodecane-1, 2-diamine; and hexane-1, 6-diamine, the reaction mixture having the molar composition: SiO 2 /Al 2 O 3 from 30 to 80 H 2 O/SiO 2 of about 50:1 A/SiO 2 from 0.16 to 0.33 M 2 O/SiO 2 0.14 to 0.18 wherein M 2 is caesium and/or rubidium and A is the diamine whereby crystals of zeolite EU-7 are formed and, recovering EU-7 zeolite material.